全文获取类型
收费全文 | 3790篇 |
免费 | 603篇 |
国内免费 | 301篇 |
专业分类
化学 | 1445篇 |
晶体学 | 30篇 |
力学 | 244篇 |
综合类 | 49篇 |
数学 | 744篇 |
物理学 | 2182篇 |
出版年
2024年 | 7篇 |
2023年 | 52篇 |
2022年 | 157篇 |
2021年 | 123篇 |
2020年 | 161篇 |
2019年 | 140篇 |
2018年 | 119篇 |
2017年 | 123篇 |
2016年 | 150篇 |
2015年 | 113篇 |
2014年 | 203篇 |
2013年 | 324篇 |
2012年 | 222篇 |
2011年 | 245篇 |
2010年 | 190篇 |
2009年 | 228篇 |
2008年 | 242篇 |
2007年 | 265篇 |
2006年 | 232篇 |
2005年 | 168篇 |
2004年 | 139篇 |
2003年 | 154篇 |
2002年 | 123篇 |
2001年 | 99篇 |
2000年 | 95篇 |
1999年 | 92篇 |
1998年 | 120篇 |
1997年 | 59篇 |
1996年 | 58篇 |
1995年 | 51篇 |
1994年 | 38篇 |
1993年 | 29篇 |
1992年 | 30篇 |
1991年 | 22篇 |
1990年 | 16篇 |
1989年 | 8篇 |
1988年 | 16篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 5篇 |
1982年 | 12篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有4694条查询结果,搜索用时 15 毫秒
81.
Peter L. Simon Serafim Kalliadasis John H. Merkin Stephen K. Scott 《Journal of mathematical chemistry》2002,31(3):313-332
The steady propagation of a planar laminar premixed flame, with a one-step exothermic reaction and linear heat loss, is studied. The corresponding travelling wave equations are solved numerically. The dependence of the flame velocity on the heat loss parameter is determined and compared with known results obtained by asymptotic expansion and other approximations. Due to the introduction of an ignition temperature the problem can be reduced to a bounded interval (of length L) and the graph of flame speed versus heat loss parameter can be parametrised by L. The numerical method is tested in the case of a step function nonlinearity when the exact solution of the differential equations can also be calculated. 相似文献
82.
Dale Umbach 《Annals of the Institute of Statistical Mathematics》1981,33(1):81-90
Summary It is desired to estimate a parameter
with the loss function of the formL(θ, a)=W(‖θ−a‖), where
is convex, differentiable, and non-decreasing. With this structure a characterization of Bayes estimators is given. Also
it is noted that if the sample space,
, for the observation,X, is a complete separable metric space then a Bayes estimator exists. 相似文献
83.
84.
Kam Yee Yoon Wen Siang Tan Beng Ti Tey Khai Wooi Lee Kok Lian Ho 《Electrophoresis》2013,34(2):244-253
Hepatitis B core antigen (HBcAg) expressed in Escherichia coli is able to self‐assemble into large and small capsids comprising 240 (triangulation number T = 4) and 180 (triangulation number T = 3) subunits, respectively. Conventionally, sucrose density gradient ultracentrifugation and SEC have been used to separate these capsids. However, good separation of the large and small particles with these methods is never achieved. In the present study, we employed a simple, fast, and cost‐effective method to separate the T = 3 and T = 4 HBcAg capsids by using native agarose gel electrophoresis followed by an electroelution method (NAGE‐EE). This is a direct, fast, and economic method for isolating the large and small HBcAg particles homogenously based on the hydrodynamic radius of the spherical particles. Dynamic light scattering analysis demonstrated that the T = 3 and T = 4 HBcAg capsids prepared using the NAGE‐EE method are monodisperse with polydispersity values of ~15% and ~13%, respectively. ELISA proved that the antigenicity of the capsids was not affected in the purification process. Overall, NAGE‐EE produced T = 3 and T = 4 capsids with a purity above 90%, and the recovery was 34% and 50%, respectively (total recovery of HBcAg is ~84%), and the operation time is 15 and 4 times lesser than that of the sucrose density gradient ultracentrifugation and SEC, respectively. 相似文献
85.
针对常见的两种非正态分布———梯形分布和三角分布,研究线性不对称质量损失时其过程均值的优化问题,建立了梯形分布在五种不同情况下线性不对称质量损失的数学模型,基于以上模型给出了线性不对称质量损失时梯形分布最优过程均值的确定方法;研究三角分布在四种不同情况下线性不对称质量损失的数学模型,并给出了线性不对称质量损失时三角分布最优过程均值的确定方法。最后,用实例验证本过程均值优化模型的有效性。实例表明,应用线性不对称损失函数,适当的改变过程均值,可以有效地降低产品的质量损失,通过调整工艺过程将获得最佳经济效益。 相似文献
86.
This article considers a co-reinsurance strategy that (1) protects insurance companies against catastrophic risks; (2) enables insurers to gather sufficient information about the different risk attitudes of reinsurers and diversify their reinsured risks; (3) enables insurers to create better risk-sharing profiles by balancing the risk tolerances of reinsurers; (4) has the benefit of allowing reinsurers to accumulate experience with risks with which they are unfamiliar; (5) reduces the overall direct cost of a reinsurance contract; (6) allows a government to back some insurance products, such as the terrorism insurance programs that were established in many countries after the September 11th terrorist attacks; and (7) reflects the practical reinsurance industry of some countries, such as Iran. Such a co-reinsurance strategy can be fully determined by estimating its parameters whenever three optimal criteria are satisfied and prior information about the unknown parameters is available. Two simulation-based studies have been conducted to demonstrate (1) the practical applications of our findings and (2) the possible impact of any type of dependency between the co-reinsurance’s parameters and the evaluated optimal co-reinsurance strategy. 相似文献
87.
88.
89.
Multiaxial mechanical behavior of aramid fibers and identification of skin/core structure from single fiber transverse compression testing
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Judith Wollbrett‐Blitz Sébastien Joannès Rémi Bruant Christophe Le Clerc Marc Romero De La Osa Anthony Bunsell Alba Marcellan 《Journal of Polymer Science.Polymer Physics》2016,54(3):374-384
The transverse and longitudinal mechanical properties of aramid fibers like Kevlar? 29 (K29) fibers are strongly linked to their highly oriented structure. Mechanical characterization at the single fiber scale is challenging especially when the diameter is as small as 15 µm. Longitudinal tensile tests on single K29 fibers and single fiber transverse compression test (SFTCT) have been developed. Our approach consists of coupling morphological observations and mechanical experiments with SFTCT analysis by comparing analytical solutions and finite element modeling. New insights on the analysis of the transverse direction response are highlighted. Systematic loading/unloading compression tests enable to experimentally determine a transverse elastic limit. Taking account of the strong anisotropy of the fiber, the transverse mechanical response sheds light on a skin/core architecture. More importantly, results suggest that the skin of the fiber, typically representing a shell of one micrometer in thickness, has a transverse apparent modulus of 0.2 GPa. That is around more than fifteen times lower than the transverse modulus of 3.0 GPa in the core. By comparison, the measured longitudinal modulus is about 84 GPa. The stress distribution in the fiber is explored and the critical areas for damage initiation are discussed. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 374–384 相似文献
90.
Redox‐responsive core cross‐linked micelles of poly(ethylene oxide)‐b‐poly(furfuryl methacrylate) by Diels‐Alder reaction for doxorubicin release
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Cuong M. Q. Le Hai Ha Pham Thi Xuan Thang Cao Gun‐Do Kim Chul‐Woong Oh Kwon Taek Lim 《Journal of polymer science. Part A, Polymer chemistry》2016,54(23):3741-3750
Redox‐responsive core cross‐linked (CCL) micelles of poly(ethylene oxide)‐b‐poly(furfuryl methacrylate) (PEO‐b‐PFMA) block copolymers were prepared by the Diels‐Alder click‐type reaction. First, the PEO‐b‐PFMA amphiphilic block copolymer was synthesized by the reversible addition‐fragmentation chain transfer polymerization. The hydrophobic blocks of PFMA were employed to encapsulate the doxorubicin (DOX) drug, and they were cross‐linked using dithiobismaleimidoethane at 60 °C without any catalyst. Under physiological circumstance, the CCL micelles demonstrated the enhanced structural stability of the micelles, whereas dissociation of the micelles took place rapidly through the breaking of disulfide bonds in the cross‐linking linkages under reduction environment. The core‐cross‐linked micelles showed fine spherical distribution with hydrodynamic diameter of 68 ± 2.9 nm. The in vitro drug release profiles presented a slight release of DOX at pH 7.4, while a significant release of DOX was observed at pH 5.0 in the presence of 1,4‐dithiothreitol. MTT assays demonstrated that the block copolymer did not have any practically cytotoxicity against the normal HEK293 cell line while DOX‐loaded CCL micelles exhibited a high antitumor activity towards HepG2 cells. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3741–3750 相似文献