全文获取类型
收费全文 | 85434篇 |
免费 | 6629篇 |
国内免费 | 7825篇 |
专业分类
化学 | 28983篇 |
晶体学 | 364篇 |
力学 | 7749篇 |
综合类 | 1615篇 |
数学 | 36113篇 |
物理学 | 25064篇 |
出版年
2024年 | 115篇 |
2023年 | 726篇 |
2022年 | 1411篇 |
2021年 | 1614篇 |
2020年 | 1788篇 |
2019年 | 2075篇 |
2018年 | 1708篇 |
2017年 | 2033篇 |
2016年 | 2353篇 |
2015年 | 1989篇 |
2014年 | 3099篇 |
2013年 | 5688篇 |
2012年 | 3418篇 |
2011年 | 4010篇 |
2010年 | 3450篇 |
2009年 | 4686篇 |
2008年 | 5122篇 |
2007年 | 5397篇 |
2006年 | 5005篇 |
2005年 | 4308篇 |
2004年 | 3937篇 |
2003年 | 3947篇 |
2002年 | 3658篇 |
2001年 | 3089篇 |
2000年 | 3008篇 |
1999年 | 2668篇 |
1998年 | 2495篇 |
1997年 | 2047篇 |
1996年 | 1829篇 |
1995年 | 1614篇 |
1994年 | 1460篇 |
1993年 | 1262篇 |
1992年 | 1192篇 |
1991年 | 955篇 |
1990年 | 780篇 |
1989年 | 665篇 |
1988年 | 606篇 |
1987年 | 479篇 |
1986年 | 425篇 |
1985年 | 494篇 |
1984年 | 471篇 |
1983年 | 231篇 |
1982年 | 381篇 |
1981年 | 442篇 |
1980年 | 332篇 |
1979年 | 321篇 |
1978年 | 250篇 |
1977年 | 233篇 |
1976年 | 168篇 |
1974年 | 117篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
Yirang Yuan 《Numerical Methods for Partial Differential Equations》2003,19(5):665-681
For the coupled system of multilayer fluid dynamics in porous media, the modified characteristic finite difference fractional steps method applicable to parallel arithmetic is put forward and two‐dimensional and three‐dimensional schemes are used to form a complete set. Some techniques, such as calculus of variations, energy method, piecewise biquadratic interpolation, multiplicative commutation rule of difference operators, decomposition of high order difference operators and prior estimates are adopted. Optimal order estimates in L2 norm are derived to determine the error in the approximate solution. This method has already been applied to the numerical simulation of multilayer fluid dynamics in porous media. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 665–681, 2003. 相似文献
52.
Ioan Tomescu 《Journal of Graph Theory》2003,43(3):210-222
In the set of graphs of order n and chromatic number k the following partial order relation is defined. One says that a graph G is less than a graph H if ci(G) ≤ ci(H) holds for every i, k ≤ i ≤ n and at least one inequality is strict, where ci(G) denotes the number of i‐color partitions of G. In this paper the first ? n/2 ? levels of the diagram of the partially ordered set of connected 3‐chromatic graphs of order n are described. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 210–222, 2003 相似文献
53.
Finite element analysis of fluid flow with moving free surface has been performed in 2‐D and 3‐D. The new VOF‐based numerical algorithm that has been proposed by the present authors (Int. J. Numer. Meth. Fluids, submitted) was applied to several 2‐D and 3‐D free surface flow problems. The proposed free surface tracking scheme is based on two numerical tools; the orientation vector to represent the free surface orientation in each cell and the baby‐cell to determine the fluid volume flux at each cell boundary. The proposed numerical algorithm has been applied to 2‐D and 3‐D cavity filling and sloshing problems in order to demonstrate the versatility and effectiveness of the scheme. The proposed numerical algorithm resolved successfully the free surfaces interacting with each other. The simulated results demonstrated applicability of the proposed numerical algorithm to the practical problems of large free surface motion. It has been also demonstrated that the proposed free surface tracking scheme can be easily implemented in any irregular non‐uniform grid systems and can be extended to 3‐D free surface flow problems without additional efforts. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
54.
J. M. Cuevas J. M. Laza M. Correa J. L. Vilas M. Rodríguez L. M. Len 《Journal of Polymer Science.Polymer Physics》2003,41(17):1965-1977
The reticulation process of an epoxy resin using an amine as a cure agent was studied at different temperatures and concentrations of the cure agent with dynamic mechanical thermal analysis. The study was performed under both isothermal and nonisothermal conditions, and a temperature–time–transformation diagram was obtained. The measurements from the two modes gave similar results, although the nonisothermal mode required fewer experiments. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1965–1977, 2003 相似文献
55.
S. A. Patlazhan 《Journal of Polymer Science.Polymer Physics》1993,31(12):1649-1665
A statistical theory of light scattering from deformed isotropic and textured heterogeneous polymer materials is formulated. Two types of textured structures are analyzed: assemblies of optically isotropic and anisotropic rods and a spatially anisotropic distribution of isotropic spherical inclusion centers. The small-angle Hv light-scattering patterns are calculated. The appearance of scattering from isotropic rods and spheres in deformed materials has been demonstrated. The changes of the Hv scattering patterns as a function of elongation and strucuture parameters are discussed. © 1993 John Wiley & Sons, Inc. 相似文献
56.
Vipul Dav Wolfgang G. Glasser Garth L. Wilkes 《Journal of Polymer Science.Polymer Physics》1993,31(9):1145-1161
Fibers were spun from isotropic and anisotropic dimethylacetamide solutions of cellulose esters. Take-up speeds of the dry jet/wet spinning process varied. Water served as the coagulant. The mechanical properties of the fibers increased as spinning progressed from the isotropic to the anisotropic state of the solution. A trade-off in solubility and fiber properties was noted as the butyryl acetyl ratio decreased. Whereas high butyryl content enhances both overall solubility and the formation of liquid–crystalline solutions at lower concentration, it results in lower fiber modulus and strength. Morphology of the fibers depended on the coagulation rate which was influenced by the concentration of the sppinning solution. The level of orientation and crystallinity of the fibers increased somewhat when they were spun from liquid-crystalline solutions. © 1993 John Wiley & Sons, Inc. 相似文献
57.
We prove the following. Let G be an undirected graph. Every partially specified symmetric matrix, the graph of whose specified entries is G and each of whose fully specified submatrices is completely positive (equal to BBT for some entrywise nonnegative matrix B), may be completed to a completely positive matrix if and only if G is a block-clique graph (a chordal graph in which distinct maximal cliques overlap in at most one vertex). The same result holds for matrices that are doubly nonnegative (entrywise nonnegative and positive semidefinite). 相似文献
58.
Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007 相似文献
59.
60.
The solvent extraction of cobalt(II), nickel(II) and copper(II) using 2,4-pent-dione (Hacac) and 4-phenyl-2, 4-but-dione (Hbzac)
is carried out by varying the reagent concentration and pH of the aqueous phase. Each of these metals is quantitatively separated
(≈ 98%) from their binary mixtures with monovalent (Ag), divalent (Mn, Zn, Cd, Hg, Mg, Sn, Pb) and trivalent (Cr, Fe) metals.
The extraction constants are calculated from the metal distribution data using linear regression analysis. The extracted species
is MA2 in each case. A most significant result is separation of copper(II) from iron(III) which otherwise interferes when extracted
from the acidic medium. 相似文献