首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6152篇
  免费   553篇
  国内免费   927篇
化学   3708篇
晶体学   82篇
力学   519篇
综合类   82篇
数学   1110篇
物理学   2131篇
  2024年   5篇
  2023年   48篇
  2022年   95篇
  2021年   104篇
  2020年   132篇
  2019年   145篇
  2018年   169篇
  2017年   174篇
  2016年   218篇
  2015年   148篇
  2014年   248篇
  2013年   473篇
  2012年   347篇
  2011年   357篇
  2010年   281篇
  2009年   393篇
  2008年   383篇
  2007年   418篇
  2006年   350篇
  2005年   354篇
  2004年   315篇
  2003年   275篇
  2002年   221篇
  2001年   239篇
  2000年   192篇
  1999年   191篇
  1998年   166篇
  1997年   138篇
  1996年   142篇
  1995年   126篇
  1994年   109篇
  1993年   67篇
  1992年   96篇
  1991年   72篇
  1990年   63篇
  1989年   56篇
  1988年   53篇
  1987年   45篇
  1986年   37篇
  1985年   26篇
  1984年   24篇
  1983年   12篇
  1982年   27篇
  1981年   23篇
  1980年   15篇
  1979年   16篇
  1978年   8篇
  1977年   6篇
  1976年   9篇
  1973年   8篇
排序方式: 共有7632条查询结果,搜索用时 218 毫秒
1.
We investigate the possibility of phantom crossing in the dark energy sector and the solution for the Hubble tension between early and late universe observations. We use robust combinations of different cosmological observations, namely the Cosmic Microwave Background (CMB), local measurement of Hubble constant (H0), Baryon Acoustic Oscillation (BAO) and SnIa for this purpose. For a combination of CMB+BAO data that is related to early universe physics, phantom crossing in the dark energy sector was confirmed at a 95% confidence level and we obtained the constraint H0=71.03.8+2.9 km/s/Mpc at a 68% confidence level, which is in perfect agreement with the local measurement by Riess et al. We show that constraints from different combinations of data are consistent with each other and all of them are consistent with phantom crossing in the dark energy sector. For the combination of all data considered, we obtained the constraint H0=70.25±0.78 km/s/Mpc at a 68% confidence level and the phantom crossing happening at the scale factor am=0.8510.031+0.048 at a 68% confidence level.  相似文献   
2.
This minireview describes the strategies for synthesis of fiuorinated surfactants potentially nonbioaccumulable.Various strategies have been focused on(Ⅰ) reducing the length of the perfluorocarbon chain,(Ⅱ) introducing hetero atoms into the fluorocarbon chain,(Ⅲ) introducing branch(herein and after branch means the fluoro-carbon chain section is not straight).In most cases,the surface tensions versus the surfactant concentrations have been assessed.These above strategies led to various highly fiuorinated(perfluorinated or not perfluorinated) surfactants whose chemical changes enabled to obtain novel alternatives to perfluorooctanoic acid(PFOA) and perfluorooctane sulphonate(PFOS).  相似文献   
3.
ABSTRACT

By applying the geometric models and the theoretical equation, the surface tension, the molar volume and the density were studied. The empirical calculations were carried out in temperature range 623?K?≤?T?≤?1123?K. Only few thermophysical properties were estimated for eight quinary alloys: Sn3.55Ag0.5Cu3Bi3Sb, Sn3.48Ag0.5Cu3Bi5Sb, Sn3.48 Ag0.5Cu5Bi3Sb, Sn3.40 Ag0.5Cu5Bi5Sb, Sn3.53Ag1Cu3Bi3Sb, Sn3.46Ag1Cu3Bi5Sb, Sn3.46Ag1Cu5Bi3Sb, Sn3.38Ag1Cu5Bi5Sb. The results show that surface tension and density have a linear appearance for all temperatures. We have also studied the influence of the composition and temperature in the studied alloys. The obtained theoretical results are compared with the experimental ones and with the conventional Pb–Sn welds.  相似文献   
4.
Self-assembly is a versatile bottom-up approach for fabricating novel supramolecular materials with well-defined nano- or micro-structures associated with functionalities. The oil-water interface provides an ideal venue for molecular and colloidal self-assembly. This paper gives an overview of various self-assembled materials, including nanoparticles, polymers, proteins, and lipids, at the oil-water interface. Focus has been given to fundamental principles and strategies for engineering the self-assembly process, such as control of pH, ionic strength and use of external fields, to achieve complex soft materials with desired functionalities, such as nanoparticle surfactants, structured liquids, and proteinosomes. It has been shown that self-assembly at the oil-water interface holds great promise for developing well-structured complex materials useful for many research and industrial applications.  相似文献   
5.
In this paper we consider a wavelet algorithm for the piecewise constant collocation method applied to the boundary element solution of a first kind integral equation arising in acoustic scattering. The conventional stiffness matrix is transformed into the corresponding matrix with respect to wavelet bases, and it is approximated by a compressed matrix. Finally, the stiffness matrix is multiplied by diagonal preconditioners such that the resulting matrix of the system of linear equations is well conditioned and sparse. Using this matrix, the boundary integral equation can be solved effectively.  相似文献   
6.
Kinetics of vapor phase hydrogenation of phenol to cyclohexanone over Pd/MgO system has been studied in a flow microreactor under normal atmospheric pressure. The reaction rate is found to be negative order with respect to the partial pressure of phenol and has increased from −0.5 to 0.5 with increasing temperature (473 to 563 K). The apparent activation energy (Ea) of the process is found to be close to 65 kJ per mol. On the basis of kinetic results a surface mechanism is proposed.  相似文献   
7.
In this paper we study constant mean curvature compact surfaces with two Jordan curves in parallel planes as boundary and we investigate the point at which the surface inherits the symmetries of its boundary.  相似文献   
8.
一类潜热型功能液固两相流体的定压比热研究   总被引:4,自引:0,他引:4  
应用两相流与热物理理论,严格推导出一类潜热型功能液固两相流体的定压比热计算公式.  相似文献   
9.
关于AOR迭代法的研究   总被引:5,自引:0,他引:5  
本文论证了严格对角占优矩阵之AOR法的误差估计式中的误差估计常数hγ,ω(0≤γ≤ω0)的最小值是h1,1.  相似文献   
10.
烷基硫酸盐表面张力的量子化学研究   总被引:1,自引:0,他引:1  
用AMl量子化学计算法优化了十三烷基硫酸根阴离子和——CH3在不同取代位的十二烷基硫酸根阴离子的几何构型,得到最优构型时最高占据分子轨道能级EHOMO、最低空轨道能级ELUMO、电子能量Eele和偶极矩μ等数据.将这些电子结构数据分别与表面张力相拟合,得到很好的相关性。文中讨论了——CH3在不同位置取代对表面张力的影响。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号