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71.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献
72.
采用显微Raman光谱方法对红外目标模拟器中重掺杂Si微电阻桥单元的热传导特性进行研究,根据Si桥的实际特性建立相应的Raman散射模型,通过测量Raman峰位的移动得到高功率激光辐照下测量点的温度.对Si桥桥面分别进行了沿某些特殊线段的逐点线扫描和覆盖全部桥面的面扫描,得到各点的温升及其分布.用基于有限元分析的软件结合Si桥结构参数对各测量点的温升进行了模拟计算,其结果在热导分布的基本趋势上与实验相一致.实验细致地揭示了热导分布的局域起伏,反映出实际器件的不均匀性,为改进器件设计、优化器件性能提供了实验依据.
关键词:
Raman光谱
Si桥
温度分布
热导 相似文献
73.
Karla J. Moreno Miroslaw Maczka Ulises Amador 《Journal of solid state chemistry》2006,179(12):3805-3813
The structural and microstructural characteristics of metastable Gd2(Ti1−yZry)2O7 powders prepared by mechanical milling have been studied by a combination of XRD and Raman spectroscopy. Irrespective of their Zr content, as-prepared powder phases present an anion-deficient fluorite-type of structure as opposed to the pyrochlore equilibrium configuration obtained for the same solid solution by other synthetic routes. These fluorites are stable versus thermal activation, at least up to temperatures of 800 °C. For the Ti-rich compositions, thermal treatments at higher temperatures facilitate the rearrangement of the cation and anion substructures and the relaxation of mechanochemically induced defects whereas for compositions with high Zr content, the fluorite crystal structure is retained even at temperatures as high as 1200 °C. Interestingly enough, transient pyrochlores showing a very unusual cation distribution were observed during the thermally induced defect-recovery process. 相似文献
75.
S. A. Kirillov A. Morresi M. Paolantoni P. Sassi 《Journal of Physical Organic Chemistry》2007,20(8):568-573
The most obvious consequence of the concept of aromaticity is the common confidence that in aromatic compounds, bond lengths do not alternate and are between typical to the single and double ones. However, in 1994, performing crystal structure investigations of substituted pyridines and their salts, Krygowski and co‐workers have discovered a very surprising angular group induced bond alteration (AGIBA) effect: It appears that some angular substituents, like methoxy or nitrozo groups, can induce bond alternation in aromatic rings. Crystal studies do not allow one to operate with liquids that are more common in organic chemistry. This paper presents the first possible evidence of spectroscopic manifestations of the AGIBA effect. Raman spectra of the liquid toluene are analyzed. It is found that instead of being single, the line corresponding to the ring breathing vibrations is clearly split by 1.0–1.4 cm?1, thus indicating the presence of two (cis‐ and trans‐) AGIBA isomers. The energy difference between these isomers estimated in temperature dependent Raman studies is found equal to 6.68 kJ mol?1. The low‐wavenumber line therefore corresponds to the cis‐AGIBA isomer and the high‐wavenumber line to the trans‐AGIBA isomer stabilized by the AGIBA effect. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
76.
N. Nishi J. Nishijo K. Judai C. Okabe O. Oishi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,43(1-3):287-290
UV photoexcitation of (t-butylethynyl copper)24
cluster films induces segregation of the crystals into metallic and organic
phases and leads to evolve the metallic sheets sandwiched by organic
polymers. The growth of the metallic crystals in the plane of the
photo-electromagnetic field is attributed due to plasmon-plasmon interaction
among nanoparticles embedded in dielectric polymer matrices. The surface
enhanced photochemical reaction of residual cluster molecules on the photon
incident direction is expected to take an important role for joining the
metal particles to produce a metallic sheet. We can apply this phenomenon
for photolithographic copper pattern generation on a flexible base plate. 相似文献
77.
78.
Thin films of polystyrene (PS), poly(methyl methacrylate) (PMMA) and polystyrene-polyacrylonitrile copolymer (PS-AN), containing various embedded transition-metal complexes, have been studied by FTIR microscopy. The spatial distributions of the transition-metal carbonyl complexes throughout the thin organic polymer films have been determined by a two-dimensional IR mapping procedure. The spectral variations observed in the distribution of the metal carbonyls throughout the different polymer films are discussed. The IR data show that the technique used to prepare the organometallic-embedded thin films (viz. freeze-drying of solutions followed by hot mechanical pressing of the residues) does in general lead to homogeneous films which may eventually find industrial application, e.g. as membrane sensors for small molecules. 相似文献
79.
A. E. Chmel’ 《Journal of Applied Spectroscopy》1997,64(4):566-568
Using Raman spectroscopy, a quantitative analysis of the distribution of OH− ions on the boundary between a bearing pipe and a glass layer deposited from chlorides in billets for quartz fiber light
guides is carried out. Water penetrated into the light-reflecting shell to a depth of several tenths of a millimeter, depending
on the composition of the doping layer (i.e., ultimately on the temperature of the depsoition process).
A. F. Ioffe Physical-Technical Institute, Academy of Sciences of Russia, 26, Politekhnicheskaya St., St. Petersburg, 194021,
Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 4, pp. 548–550, July–August, 1997. 相似文献
80.
转动喇曼散射截面的群论计算 总被引:1,自引:1,他引:0
本文利用群链U(4)U(3)O(3)描述双原子分子N_2和O_2振转谱的对称性质,并利用群论方法计算了N_2和O_2分子转动喇曼散射的跃迁矩阵元,给出了它们的转动喇曼散射的截面。结果与实验较好地符合。 相似文献