碰撞池-电感耦合等离子体质谱法测定芝麻中痕量的锗

建立了碰撞池-电感耦合等离子体质谱法测定芝麻中痕量的锗元素(germanium , Ge)。采用微波消解,碰撞池(KED模式)-电感耦合等离子体质谱检测,在线引入内标元素铑(Rh),同时消解液中加入3%正戊醇增敏。结果 3 % 正戊醇可使_⁷⁴Ge的上机检测信号强度提高2.85倍,_⁷⁴Ge校正曲线线性相关系数为1.00000,检出限为0.0555 μg/kg,加标回收率为92.0%~106%,相对标准偏差(relative standard deviation, RSD%)为2.6%~4.3%。采用建立的方法测定7种国家标准物质,检测结果均在认定值范围内,RSD%为2.5%~8.8%。结论 该方法灵敏度高、准确,可实现批量检测,适用于芝麻中痕量锗的检测。     

Quantum Chemical Calculations and Experimental Studies on 2,3-Diphenyl-tetrazole-5-thione

1 INTRODUCTION Many substituted tetrazoles show a variety of interesting properties. For instance, they exhibit certain types of physiological activity by affecting the nervous system in a number of ways[1]. They are commonly used as good weed killers in…     

A frequency accurate spatial derivative finite difference approximation

We present a method for designing spatial derivative approximations that achieves a priori accuracy in the spatial frequency domain. We use a general, average value approximation with undetermined coefficients together with a set of constraints that ensure convergence and consistency to formulate a constrained optimal fitting problem. These constraints lead to a linear matrix formulation. We apply the method to the design of spatial approximations for simulating equations with wavelike solutions using both an explicit central difference approximation (which has no phase error) and an upwind design where the level of dissipation can be specified by the designer. © 1997 John Wiley & Sons, Inc. Numer Methods Partial Differential Eq 13: 549–560, 1997     

Regular low frequency cardiac output oscillations observed in critically ill surgical patients

A serendipitous finding during development of an automated “electronic flow chart” system to gather data on ICU patients [1] was the observation of low frequency oscillations in blood pressure that were not explained by systematic variability in the environment. [2] This finding has since been confirmed by others. [3,4] In the present report, hemodynamic data for critically ill surgical patients was continuously collected and visualized on a computer workstation to search for patterns not noted by standard monitoring. With this system, we observed low-frequency periodic oscillations in the cardiac output of ten patients, with regular periodicities of 4 to 280 minutes (average = 34 minutes). The mortality rate in these patients was 40%, while the mortality was only 10.8% in 83 similarly monitored intensive care unit (ICU) patients who did not develop regular oscillations in cardiac output. Interestingly, these oscillatory patterns appear to be associated with inadequate resuscitation of increased metabolic rates. The mathematical definition of “chaos” refers to irregular behavior that appears to be random but is actually deterministic. [5] A surprising finding concerning transitions between states of apparent randomness and order in nonlinear systems is that many systems become more organized after being disturbed. Chaotic behavior in biological systems may represent a normal physiologic state, while the loss of chaotic behavior may herald a pathophysiologic state. [6] The mechanism of the regular low frequency oscillations in cardiac output remains to be determined, but the high mortality rate suggests that it is a pathophysiologic marker, perhaps due to inadequate oxygen delivery in under-resuscitated shock. © 1997 John Wiley & Sons, Inc.     

Nd:Ca4ReO(BO3)3(Re=Gd,Y)晶体最佳激光、最佳倍频及最佳自倍频方向的确定

介绍了Nd:Ca4ReO(BO3)3(Re=Gd,Y)晶体最佳激光方向、最佳倍频方向的确定.综合考虑激光受激发射截面、抽运光吸收系数、有效非线性系数的各向异性,分析了自倍频性质的空间分布,并就此确定出最佳自倍频方向 关键词： Nd:Ca4ReO(BO3)3(Re=Gd Y)晶体 激光发射 倍频 自倍频     

激光准直Cr原子束的实验研究

利用多普勒原理对Cr原子束进行横向准直.应用激光感生荧光技术稳定激光器的频率，把激光器的中心频率稳定在偏离Cr原子共振中心频率-5±0.26MHz的位置.根据理论计算出准直激光束的最小尺寸为13.7mm.根据实验数据选择合适的参数，实现利用多普勒原理横向准直Cr原子束，使原子束的横向分布缩小到原来的1/3. 关键词： 激光准直 激光感生荧光稳频 多普勒冷却     

Harmonic IR spectra from empirical force fields and ab initio dipole-moment derivatives

Infrared spectra simulations require ab initio techniques to get reliable intensities. On the other hand, recent force fields can provide accurate molecular geometries and frequencies. Therefore, it is suggested that these new force fields could be used to simulate infrared spectra, dipole-moment surfaces being described at high levels of theory in order to get satisfactory intensities. As pointed out, for a system with N atoms, the cost of such a simulation would be reduced N-fold with respect to standard quantum approaches. Preliminary calculations based on this scheme are reported here. Encouraging results are obtained since no significant lost of accuracy is noted on going from the ab initio to the molecular mechanics potential energy surface. © 1998 John Wiley & Sons, Inc. Int J Quant Chem 69: 705–711, 1998     

一种创新型感应电机调速系统的设计与实现

鉴于传统电力电子相关课程实验既无法直观了解电路内部构造,也不能有效提升实际动手能力的情况,设计了一种基于实验室环境的开放式创新型感应电机变频调速系统,改造了主电路和控制电路的电源,在适应实验室用电环境的同时,能实现主电路低压可测量和提升学生实验的安全性;并设计了采样电路和保护电路,能加深学生对电路的了解,增强实际动手能力.经实验验证,该系统能完成多段速运动控制、模拟量与数字量给定调速等相关实验.     

Influence of oxycycloaliphatic groups in the relaxation behavior of acrylic polymers

A comparative study on the mechanical and dielectric relaxation behavior of poly(5‐acryloxymethyl‐5‐methyl‐1,3‐dioxacyclohexane) (PAMMD), poly(5‐acryloxymethyl‐5‐ethyl‐1,3‐dioxacyclohexane) (PAMED), and poly(5‐methacryloxymethyl‐5‐ethyl‐1,3‐dioxacyclohexane) (PMAMED) is reported. The isochrones representing the mechanical and dielectric losses present prominent mechanical and dielectric β relaxations located at nearly the same temperature, approximately −80°C at 1 Hz, followed by ostensible glass–rubber or α relaxations centered in the neighborhood of 27, 30, and 125°C for PAMMD, PAMED, and PMAMED, respectively, at the same frequency. The values of the activation energy of the β dielectric relaxations of these polymers lie in the vicinity of 10 kcal mol⁻¹, ∼ 2 kcal mol⁻¹ lower than those corresponding to the mechanical relaxations. As usual, the temperature dependence of the mean‐relaxation times associated with both the dielectric and mechanical α relaxations is described by the Vogel–Fulcher–Tammann–Hesse (VFTH) equation. The dielectric relaxation spectra of PAMED and PAMMD present in the frequency domain, at temperatures slightly higher than T_g, the α and β relaxations at low and high frequencies, respectively. The high conductive contributions to the α relaxation of PMAMED preclude the possibility of isolating the dipolar component of this relaxation in this polymer. Attempts are made to estimate the temperature at which the α and β absorptions merge together to form the αβ relaxation in PAMMD and PAMED. Molecular Dynamics (MD) results, together with a comparative analysis of the spectra of several polymers, lead to the conclusion that flipping motions of the 1,3‐dioxacyclohexane ring may not be exclusively responsible for the β‐prominent relaxations that polymers containing dioxane and cyclohexane pendant groups in their structure present, as it is often assumed. The diffusion coefficient of ionic species, responsible for the high conductivity exhibited by these polymers in the α relaxation, is semiquantitatively calculated using a theory that assumes that this process arises from MWS effects, taking place in the bulk, combined with Nernst–Planckian electrodynamic effects, due to interfacial polarization in the films. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 2486–2498, 1999     

HIRFL新B1聚束器频率微调系统的设计及稳定性分析

 频率自动调谐系统是聚束器的重要组成部分之一。频率调谐系统成功的研制和投入使用达到了使谐振腔体的固有谐振频率在22～54 MHz的范围内自动稳定在输入信号频率上的目的,频率自动微调系统达到了±5×10^-6的频率稳定度,解决了由于腔体失谐所造成的高频电压滑落的问题,由此在腔体的加速缝隙间得到稳定的高频电压,保证了聚束器系统的高质量可靠运行。