全文获取类型
收费全文 | 2667篇 |
免费 | 434篇 |
国内免费 | 299篇 |
专业分类
化学 | 424篇 |
晶体学 | 18篇 |
力学 | 302篇 |
综合类 | 43篇 |
数学 | 1228篇 |
物理学 | 1385篇 |
出版年
2024年 | 3篇 |
2023年 | 21篇 |
2022年 | 58篇 |
2021年 | 53篇 |
2020年 | 56篇 |
2019年 | 78篇 |
2018年 | 79篇 |
2017年 | 76篇 |
2016年 | 98篇 |
2015年 | 87篇 |
2014年 | 157篇 |
2013年 | 220篇 |
2012年 | 132篇 |
2011年 | 139篇 |
2010年 | 128篇 |
2009年 | 184篇 |
2008年 | 174篇 |
2007年 | 169篇 |
2006年 | 160篇 |
2005年 | 191篇 |
2004年 | 125篇 |
2003年 | 141篇 |
2002年 | 117篇 |
2001年 | 106篇 |
2000年 | 109篇 |
1999年 | 93篇 |
1998年 | 74篇 |
1997年 | 72篇 |
1996年 | 59篇 |
1995年 | 37篇 |
1994年 | 32篇 |
1993年 | 25篇 |
1992年 | 15篇 |
1991年 | 24篇 |
1990年 | 17篇 |
1989年 | 8篇 |
1988年 | 12篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 14篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 3篇 |
1978年 | 6篇 |
1976年 | 2篇 |
1974年 | 3篇 |
1957年 | 2篇 |
排序方式: 共有3400条查询结果,搜索用时 31 毫秒
31.
R. Murugesan P. Sami T. Jeyabalan A. Shunmugasundaram 《Journal of Chemical Sciences》1995,107(1):1-10
Bonding and redox properties of mono- and dititanium substituted 12-heteropolytungsto-phosphates and their complexes with
bivalent Mn, Co, Ni and Cu are studied by UV-Vis, ESR and cyclicvoltammetric techniques. The heteropoly blue analogue [TiIIITiIVW10PO40]8− is unstable and its presence in solution is proved by optical and ESR spectroscopy. ESR results reveal that the odd electron
is trapped on the titanium atom at 77 K. The optical electronegativity of Ti(III) in this heteropoly blue is estimated to
be 2.4 from the intervalence charge transfer (IVCT) bands. X-ray powder diffraction results show that the complexes K5MII[Ti2W10PO40].xH2O(MII = Cu or Mn) are isomorphous with K7[Ti2W10PO40].6H2O. Electronic spectroscopy indicates very high symmetry around the bivalent metal ion M in the K5MII[Ti2W10PO40].xH2O complexes. This high symmetry is confirmed in K5Cu[Ti2W10PO40] by the observation of dynamic Jahn-Teller (JT) distortion at 300 K and static JT distortion at 77 K. 相似文献
32.
The main goal of this paper is to prove analytically the existence of strange attractors in a family of vector fields consisting of two Brusselators linearly coupled by diffusion. We will show that such a family contains a generic unfolding of a 4-dimensional nilpotent singularity of codimension 4. On the other hand, we will prove that in any generic unfolding Xμ of an n-dimensional nilpotent singularity of codimension n there are bifurcation curves of (n−1)-dimensional nilpotent singularities of codimension n−1 which are in turn generically unfolded by Xμ. Arguments conclude recalling that any generic unfolding of the 3-dimensional nilpotent singularity of codimension 3 exhibits strange attractors. 相似文献
33.
Hanna Sandler 《Geometriae Dedicata》1998,69(3):317-327
In this paper it is shown that one can choose an arbitrarily large number of inconjugate elements of the group Z/2Z*Z/2Z*Z/2Z which have the property that, under all representations of the group in SU(2,1) as a discrete complex hyperbolic ideal triangle group, the elements are hyperbolic and correspond to closed geodesics of equal length on the associated complex hyperbolic surface. This is an analogue of the geometric fact that the multiplicity of the length spectrum of a Riemann surface is never bounded or the equivalent algebraic phenomenon that an arbitrarily large number of conjugacy classes in a free group can have the same trace under all representations in SL(2,R ). 相似文献
34.
In many-valued logic the decision of functional completeness is a basic and important problem, and the thorough solution to this problem depends on determining all maximal closed sets in the set of many-valued logic functions. It includes three famous problems, i.e., to determine all maximal closed sets in the set of the total, of the partial and of the unary many-valued logic functions, respectively. The first two problems have been completely solved ([1], [2], [8]), and the solution to the third problem boils down to determining all maximal subgroups in the k-degree symmetric group Sk, which is an open problem in the finite group theory. In this paper, all maximal closed sets in the set of unary p-valued logic functions are determined, where p is a prime. Mathematics Subject Classification: 03B50, 20B35. 相似文献
35.
二(邻香草醛缩丙醇胺)异硫氰酸根合锰(Ⅲ)的合成与晶体结构 总被引:2,自引:0,他引:2
本文报道了一个新配合物—二(邻香草醛缩丙醇胺根)异硫氰酸根合锰(Ⅲ)的合成及其晶体结构。配合物属于单斜晶系,空间群为P21/c,晶胞参数为:a=8.565(1), b=21.814(2), c=12.787(2)?, β=92.80(1)°。锰为六配位,在两个邻香草醛缩丙醇胺Schiff碱配体中,一个为三齿配体,另一个为双齿配体。NCS-离子以N在轴向上与锰发生配位,由于Jahn-Teller效应,其键长为2.193?。另外晶胞中存在着罕见的H……S-C≡N氢键。 相似文献
36.
37.
Studies of the vibrational spectra of matrix-isolated M+NO
3
–
ion pairs have been extended to glassy aprotic solvents. The deuterated form of the solvents DMSO, THF, and ACN have windows through the 7- nitrate ionv
3(e) mode infrared region, so it was possible to clearly observe the splitting of the degeneracy of this mode,v
3, produced by the contacting, but solvated, alkali metal cation. Primary attention has been directed to the extent to which this splitting is reduced relative to the argon matrix values. This reduction, which reflects electron-density transfer from the solvating molecules to the ion pairs, is comparable to that observed for H2O and NH3 matrices as the splitting is reduced to 20–35% of the argon-matrix values. The extent of reduction ofv
3 for the different solvents has been related to Gutmann's donicity number scale with the correlation holding well for solvent molecules of comparable size, DMSO, THF and DMF, but breaking down for the smaller linear ACN, apparently because of more molecules in the cation solvation sphere. The matrix data have also been used, through comparison with spectra for saturated liquid solutions of Li+NO
3
–
, to show that the contact ion pair is the dominant species in liquid THF and ACN, whereas the ions are largely solvent separated in DMSO. 相似文献
38.
Transient propagation of weak pressure perturbations in a homogeneous, isotropic, fluid saturated aquifer has been studied. A damped wave equation for the pressure in the aquifer is derived using the macroscopic, volume averaged, mass conservation and momentum equations. The equation is applied to the case of a well in a closed aquifer and analytical solutions are obtained to two different flow cases. It is shown that the radius of influence propagates with a finite velocity. The results show that the effect of fluid inertia could be of importance where transient flow in porous media is studied.List of symbols
b
Thickness of the aquifer, m
-
c
0
Wave velocity, m/s
-
k
Permeability of the porous medium, m2
-
n
Porosity of the porous medium
-
p(
,t)
Pressure, N/m2
-
Q
Volume flux, m3/s
-
r
Radial coordinate, m
-
r
w
Radius of the well, m
-
s
Transform variable
-
S
Storativity of the aquifer
-
S
d(r, t)
Drawdown, m
-
t
Time, s
-
T
Transmissivity of the aquifer, m2/s
-
(
,t)
Velocity of the fluid, m/s
-
Coordinate vector, m
-
z
Vertical coordinate, m
-
Coefficient of compressibility, m2/N
-
Coefficient of fluid compressibility, m2/N
-
Relaxation time, s
-
(r, t)
Hydraulic potential, m
-
Dynamic viscosity of the fluid, Ns/m2
-
Dimensionless radius
-
Density of the fluid, Ns2/m4
-
(, )
Dimensionless drawdown
-
Dimensionless time
-
, x
Dummy variables
-
0,
1
Auxilary functions 相似文献
39.
The hollandite Ba1Cs0.28Fe0.82Al1.46Ti5.72O16, which has been proposed for the cesium-specific conditioning, can be synthesized either by an alcoxyde or a dry route. In both cases, a two-step protocol is applied, i.e., a calcination at 1000 °C followed by a sintering at 1200 °C. After sintering, both synthetic processes lead to a tetragonal form. According to the X-ray diffraction (XRD) patterns collected at the barium and the cesium K absorption edges, the different positions of these two elements have been evidenced with a more centered position in the oxygen cubic site of the tunnel for Ba than for Cs. On the contrary, after calcination, the two synthetic routes yield different products. The alcoxyde route gives rise to a mixture of the aforementioned Cs- and Ba-containing tetragonal I4/m hollandite, a Cs-only-containing monoclinic I2/m hollandite and an unidentified phase with a weak coherence length containing only Ba. The dry route yields a single tetragonal hollandite material containing Ba and Cs slightly different in composition from the targeted compound. 相似文献
40.
The relativistic ground and low-lying excited state potential energy curves of AgH and AuH in the presence of a cylindrical
harmonic confining potential were calculated using the multi-state multi-reference perturbation theory with the spin-free
no-pair Hamiltonian obtained via the third-order Douglas–Kroll transformation, incorporated with the full two-electron Breit–Pauli
spin–orbit operator. The spectroscopic parameters were obtained for both the scalar- and quasi-relativistic potentials. The
spin–orbit coupling constants were calculated for several strengths of the confining potential, and the effects of the applied
potential on the coupling constants were analyzed using configuration interaction.
This paper is dedicated to Serafín Fraga—colleague, mentor, and friend. 相似文献