全文获取类型
收费全文 | 1644篇 |
免费 | 562篇 |
国内免费 | 139篇 |
专业分类
化学 | 253篇 |
晶体学 | 5篇 |
力学 | 64篇 |
综合类 | 105篇 |
数学 | 531篇 |
物理学 | 1387篇 |
出版年
2024年 | 3篇 |
2023年 | 13篇 |
2022年 | 56篇 |
2021年 | 43篇 |
2020年 | 45篇 |
2019年 | 49篇 |
2018年 | 58篇 |
2017年 | 79篇 |
2016年 | 105篇 |
2015年 | 67篇 |
2014年 | 136篇 |
2013年 | 178篇 |
2012年 | 126篇 |
2011年 | 129篇 |
2010年 | 113篇 |
2009年 | 105篇 |
2008年 | 123篇 |
2007年 | 114篇 |
2006年 | 109篇 |
2005年 | 98篇 |
2004年 | 72篇 |
2003年 | 82篇 |
2002年 | 85篇 |
2001年 | 81篇 |
2000年 | 45篇 |
1999年 | 40篇 |
1998年 | 40篇 |
1997年 | 22篇 |
1996年 | 21篇 |
1995年 | 18篇 |
1994年 | 16篇 |
1993年 | 10篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1982年 | 1篇 |
1967年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有2345条查询结果,搜索用时 15 毫秒
71.
The dissolution behavior of carbon steel in ammonium chloride (NH4Cl) solution containing sodium thiosulfate (Na2S2O3) of various concentrations (0.01 and 0.1 M) was investigated using electrochemical impedance spectroscopy (EIS) and other nonelectrochemical techniques. The weight loss and polarization measurements indicate a significant increase in the NH4Cl corrosion rate of carbon steel on addition of Na2S2O3. The EIS measurements exhibited two capacitive loops at multiple direct current (dc) potentials for both the concentrations. Electrical equivalent circuit (EEC) and reaction mechanism analysis (RMA) were employed to analyze the impedance data. A four-step mechanism with two intermediate adsorbate species of same charge was proposed to explain the dissolution behavior of carbon steel in the given system. The surface coverage values enumerated that the surface was entirely covered with adsorbed species unlike in the pure NH4Cl system. Charge transfer resistance and polarization resistance values estimated from RMA parameters indicate the increase in a dissolution rate with dc potential. The surface morphology was inspected via field emission scanning electron microscopy, and the corrosion products including surface state of carbon steel electrode were analyzed using energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. 相似文献
72.
73.
Hasan M. El Ghanem Saa’Di Abdul Jawad Yazan A. Hussain Adnan S. Abu-Surrah 《Journal of Macromolecular Science: Physics》2014,53(5):878-892
Impedance spectroscopy was utilized to investigate the dielectric properties, ac conductivity and charge transport mechanisms in propylene-alt-CO/ethylene-alt-CO (EPEC) random terpolymer filled with multi-walled carbon nanotubes (MWCNT) as a function of nanofiller content, frequency, and temperature. Equivalent resistor-capacitor (RC) circuit models were proposed to describe the impedance characteristics of the unfilled terpolymer and the nanocomposite at different temperatures. For the nanocomposites, the ac conductivity tended to be frequency independent at low frequencies. At high frequencies, the ac conductivity increased with frequency. The dc conductivity (i.e., plateau of the ac conductivity at low frequencies) at room temperature increased from 10?9 (Ω·m)?1 for the unfilled polymer to l0?3 (Ω·m)?1 for the 6 wt% MWCNT/EPEC nanocomposite. At low temperatures, the equivalent RC model for EPEC-0 and EPEC-2 was found to consist of a parallel RC circuit. However, for 6 wt% MWCNT/EPEC nanocomposite, an RC model consisting of an R/constant phase element (CPE) circuit and a resistor in series was required to describe the impedance behavior of the nanocomposite. 相似文献
74.
Characterizations of ( m,n )-Jordan Derivations and ( m,n )-Jordan Derivable Mappings on Some Algebras
下载免费PDF全文
![点击此处可从《数学学报(英文版)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Let R be a ring, M be a R-bimodule and m, n be two fixed nonnegative integers with m + n = 0. An additive mapping δ from R into M is called an(m, n)-Jordan derivation if(m +n)δ(A~2) = 2 mAδ(A) + 2nδ(A)A for every A in R. In this paper, we prove that every(m, n)-Jordan derivation with m = n from a C*-algebra into its Banach bimodule is zero. An additive mappingδ from R into M is called a(m, n)-Jordan derivable mapping at W in R if(m + n)δ(AB + BA) =2mδ(A)B + 2 mδ(B)A + 2 nAδ(B) + 2 nBδ(A) for each A and B in R with AB = BA = W. We prove that if M is a unital A-bimodule with a left(right) separating set generated algebraically by all idempotents in A, then every(m, n)-Jordan derivable mapping at zero from A into M is identical with zero. We also show that if A and B are two unital algebras, M is a faithful unital(A, B)-bimodule and U = [A M N B] is a generalized matrix algebra, then every(m, n)-Jordan derivable mapping at zero from U into itself is equal to zero. 相似文献
75.
The trench on a printed circuit board was reconstructed to fabricate a microfluidic framework that allows low-cost production for small quantities and integration with multifunctional elements. An on-chip electrolyte regulator was thus proposed on this platform to analyze diffusion properties in laminar flow. A numerical model was developed, highlighting the interplay between the electrolyte migration and hydrodynamic properties. Solutions with dissolved sodium chloride were simulated and experimentally tested for the regulation of electrical conductivity under the guidance of the normalized Nernst-Planck equation. The diffusion mechanism and the resulting concentration field were demonstrated in detail. This approach provides a satisfactory manufacturing method and a useful tool for integrated microfluidic systems. 相似文献
76.
In this article, we deal with the notion of the envelopes of homotopies which is the generalized version of functional envelopes in discrete dynamical systems. We prove the stability for envelopes of homotopies in complete normed algebra and we get the stabilities of the derivation and the extended derivation for the notion in the spaces. 相似文献
77.
《Optimization》2012,61(3):413-427
The hypergraph minimum bisection (HMB) problem is the problem of partitioning the vertices of a hypergraph into two sets of equal size so that the total weight of hyperedges crossing the sets is minimized. HMB is an NP-hard problem that arises in numerous applications – for example, in digital circuit design. Although many heuristics have been proposed for HMB, there has been no known mathematical program that is equivalent to HMB. As a means of shedding light on HMB, we study the equivalent, complement problem of HMB (called CHMB), which attempts to maximize the total weight of non-crossing hyperedges. We formulate CHMB as a quadratically constrained quadratic program, considering its semidefinite programming relaxation and providing computational results on digital circuit partitioning benchmark problems. We also provide results towards an approximation guarantee for CHMB. 相似文献
78.
We propose a new scheme for generating the superposition and entanglement of the coherent states and squeezed states by considering N superconducting charge qubits (or artificial two-level atoms) interacting with photons in a high finesse cavity on a chip, assisted by a strong driving field. By virtue of the parameters of this system, we can generate novel quantum states, for example, multiparty entangled states and Schro¨dinger cat states among the superconducting qubits, coherent states and squeezed state... 相似文献
79.
《Optimization》2012,61(3):405-412
In the paper exponential bounds for the instationary and stationary waiting time d.f.'s in GI/GI/1/∞, derived by several authors partly using martingale theory arguments, are improved with the help of monotonicity properties. Further it is shown that Ne?eptjrenko's bound for the rate of convergence of the mean waiting time in single server queues Is also valid for many server queues with ρ < 1. 相似文献
80.
电子回旋共振(ECR)中和器是微型ECR离子推力器的重要组成部分,其引出的电子用于中和ECR离子源的离子束流,避免了航天器表面电荷堆积,并且电子引出性能对推力器的整体性能起着重要作用.为了分析影响微型ECR中和器电子引出的因素,本文建立了二维轴对称PIC/MCC计算模型,通过数值模拟研究不同磁路结构对中和器的电子引出,及不同腔体长度对壁面电流损失的影响.计算结果表明, ECR区位置和引出孔附近磁场构型对中和器的电子引出性能至关重要.当ECR区位于天线上游,电子在迁移扩散中易损失,并且电子跨过引出孔前电势阱所需的能量更高.如果更多磁力线平行通过引出孔,中和器引出相同电子电流所需电压较小.当ECR区被天线切割或位于下游时,电子更易沿磁力线迁移到引出孔附近,从而降低了收集板电压.研究了同一磁路结构下不同腔体长度对电子引出的影响,发现增加腔体长度,使得更多平行轴线的磁力线通过引出孔从而避免电子损失在引出板表面,增加了引出电子电流.研究结果有助于设计合理的中和器磁路和腔体尺寸. 相似文献