Spectral properties and microstructure of sputtered WOx films for solar conversion applications

Tungsten oxides (WO_x) films have gained promising attention in terms of selective solar absorption due to its high intrinsic absorption properties. We fabricated a series of single-layer WO_x films on aluminum substrates by a magnetron sputtering system. The optical absorption properties of the film were investigated by spectrophotometer and ellipsometry. We found that the optical properties of the film were very sensitive to the change of the thickness. The result showed the highest α value can reach up 0.82 with the thickness of 26 nm at 0.6 Pa or 70 nm at 1.5 Pa, and both ε values was around 0.05, indicating the high spectral selectivity properties. The different reflectance evolutions presented a wide range of color appearances, such as yellow, reddish, cyan, and blue. Moreover, the surface morphologies and phase structures of single-layer WO_x films were investigated by SEM, XRD, and Raman. A WO_x/SiO₂ solar selective absorber coating indicated that the as-obtained WO_x film was a promising application in solar-thermal conversion.     

Circularly Polarized Luminescence and Tuning Chromaticity of Eu(III)‐Grafting Chiral Polymer Based on Variable Position of the Substitution

The novel chiral conjugated polymers P‐1 and P‐3 are prepared from the monomers S‐M‐2 and S‐M‐3 with (R,R)‐1,2‐aminocyclohexane ( M‐1 ) via a nucleophilic addition–elimination reaction, respectively. The Eu(III)‐grafting chiral polymers P‐2 and P‐4 could be obtained by direct coordination reaction of Eu(TTA)₃·2H₂O with P‐1 and P‐3 , respectively. Photoexcitation of P‐2 produces pink color emission as a result of the combination of partial blue self‐emission chromophore of P‐1 along with the red color from the Eu(TTA)₃ moiety, whereas P‐4 shows the exclusively red color emission from the Eu(III) (⁵D₀→⁷F₂) transition due to almost complete excitation energy transfer from the macromolecular chain to the Eu(TTA)₃ moiety. The choice substitution of phenyl derivative of the polymer plays a crucial role on the efficient energy transfer from the polymer chain to Eu(III) ion center. Meanwhile, the g_lum value of the dissymmetry factor of circularly polarized luminescence (CPL) for the ⁵D₀→⁷F₂ transition of Eu(III) for P‐4 reaches as high as +0.0207, whereas P‐2 exhibits the largest g_lum value about +0.0464 centered at 434 nm.

     

BEPCⅡ中电子云不稳定性模拟研究

正电子储存环在多束团运行时有可能发生电子云不稳定性(ECI)?.本文针对北京正负电子对撞机二期工程(BEPCⅡ)的具体条件,编写发展了模拟计算程序,以不同电子云密度抑制措施下的计算结果为基础,研究了耦合束团不稳定性和单束团不稳定性,给出了电子云不稳定性增长率和阈值密度以及色品对束团尺寸增长的抑制作用,为储存环中电子云不稳定性的前沿科学研究和BEPCⅡ工程设计提供了有意义的结果.     

冷阴极荧光灯色度测量的实验设计

本文介绍了将冷阴极荧光灯彩色光源引入色度测量物理实验教学,并给出了测量该光源色度的实验方法．     

Chromaticity-stable organic white light-emitting devices based on mixed pyridine–phenol boron complex

We demonstrate molecular organic white light-emitting devices (LEDs), using vacuum-deposited thin films of N,N-diphenyl-N,N-bis(1-naphthyl)-(1,1-biphenyl)-4,4-diamine (NPB) as the hole-transporting layer, 1,6-bis(2-hydroxyphenyl)pyridine boron complex ((dppy)BF) as the emitting layer, tris-(8-hydroxyquinoline)aluminum (Alq) doped with 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) as the red-emitting layer. The white light comes from three components: exciplex emission at the interface between NPB and (dppy)BF, which covers the wide range from 500 to 700 nm, blue emission from bulk NPB and (dppy)BF and red emission from DCJTB. The chromaticity of the devices can be tuned by varying the thickness of (dppy)BF and doped Alq layers. The Commission Internationale De L'Eclairage (CIE) coordinates of emitted light vary from (0.31, 0.335) to (0.32, 0.345) when forward voltages change from 10 to 20 V, which are just adjacent to the white-light equi-energy point (0.33, 0.33). The brightness and luminous efficiency are 150 cd/m² and 0.3l m/W at 12 V, respectively.     

Tm3+单掺杂及Tm3+, Dy3+共掺杂YP1-xVxO4荧光粉的光谱性质

采用共沉淀法制备了Tm³⁺单掺杂及Tm³⁺,Dy³⁺共掺杂的YP_1-xV_xO₄荧光粉材料。给出了样品的XRD谱,获得了样品的SEM照片,对其发射和激发光谱也进行了测量。结果发现,随着钒酸根含量的增加,样品的激发带发生红移,这样的激发带能够满足白光LED用荧光粉的激发要求。在Tm³⁺,Dy³⁺共掺杂的样品中观测到了全色的发射,并且红、绿、蓝三个发射组分的比例也可以调整。我们计算了不同样品的色坐标,发现均在白光范围内,可见该体系样品有希望成为一种全色发射的白光LED用荧光粉。     

Enhance luminescence by introducing alkali metal ions (R+ = Li+, Na+ and K+) in SrAl2O4:Eu3+ phosphor by solid-state reaction method

In the present article, the role of charge compensator ions (R⁺?=?Li⁺, Na⁺ and K⁺) in europium-doped strontium aluminate (SrAl₂O₄:Eu³⁺) phosphors was synthesized by the high-temperature, solid-state reaction method. The crystal structures of sintered phosphors were in a monoclinic phase with space group P2₁. The trap parameters which are mainly activation energy (E), frequency factor (s) and order of the kinetics (b) were evaluated by using the peak shape method. The calculated trap depths are in the range from 0.76 to 0.84?eV. Photoluminescence measurements showed that the phosphor exhibited emission peak with good intensity at 595?nm, corresponding to ⁵D₀–⁷F₁ (514?nm) orange emission and weak ⁵D₀–⁷F₂ (614?nm) red emission. The excitation spectra monitored at 595?nm show a broad band from 220 to 320?nm ascribed to O–Eu charge-transfer state transition and the other peaks in the range of 350–500?nm originated from f–f transitions of Eu³⁺ ions. The strongest band at 394?nm can be assigned to ⁷F₀–⁵L₆ transition of Eu³⁺ ions due to the typical f–f transitions within Eu³⁺ of 4f⁶ configuration. The latter lies in near ultraviolet (350–500?nm) emission of UV LED. CIE color chromaticity diagram and thermoluminescence spectra confirm that the synthesized phosphors would emit an orange-red color. Incorporating R⁺?=?Li⁺, Na⁺ and K⁺ as the compensator charge, the emission intensity of SrAl₂O₄:Eu³⁺ phosphor can be obviously enhanced and the emission intensity of SrAl₂O₄:Eu³⁺ doping Li⁺ is higher than that of Na⁺ or K⁺ ions.     

不同环境光下液晶显示器人眼辨色阈值的研究

为了研究在不同环境光下人眼辨色水平上的颜色视觉特性,通过在液晶显示器上显示颜色刺激,使用心理物理学中的恒常刺激法进行主观实验,获取了CIE1976a*-b*平面上3名标准观察者在暗室、A光源和D50三种环境光下的5个基本颜色中心的主观实验数据。采用性能因子PF/3评价标准观察者的测试重复性和准确性,根据主观实验拟合得到色度椭圆来表示辨色阈值实验的结果。实验结果表明:CIE1976a*-b*平面是视觉非均匀的;在整体上,人眼的辨色灵敏度随着外界光源色温的变大而变小;人眼在三种环境光下的5个颜色中心区域,红绿方向的视觉色差尺度均小于黄蓝方向。实验结果可以为均匀颜色空间和色差公式的改进提供原始数据。     

白光LED光斑均匀性的改进

用于照明领域的白光LED,其出射光斑的色度均匀性对于产品性能有着更加重要的意义.介绍了目前工业上制作白光LED主要采用的荧光粉灌封点胶工艺.并在目前主流灌封点胶工艺的基础上通过改善荧光粉层结构形状,以提高白光LED器件的出射光斑均匀性.并通过九点法对不同工艺结构下LED出射光斑的空间色度分布进行了测量和分析.通过分析,虽然采用不同的粉层结构,能够一定程度上改善白光光斑的色度均匀性.但总体上,采用这种传统的点胶工艺制作的器件的白光光斑性能不好,现有的荧光粉层灌封点胶工艺存在很大的弊端.荧光粉层的可控性是影响色度均匀性(即光斑均匀性)的主要因素,包括单个器件内的光斑和器件之间的颜色一致性都不理想.     

基于阈上小色差的色差公式权重函数研究

利用心理物理实验的恒常刺激法,测得了在CIELAB颜色空间中a*b*平面上16个颜色中心的阈上小色差(约3ΔE*ab单位)色度椭圆.基于本实验和RIT-Dupont各16个非中性色颜色中心的彩度差和色调差数据分别拟合得到相应的彩度权重函数SC_ZJU07和色调权重函数SH_ZJU07.应用获得的视觉实验数据对六个基于CIELAB的典型色差公式的彩度和色调权重函数以及SC_ZJU07和SH_ZJU07的色差预测性能进行评价,结果表明所提出的SC_ZJU07和SH_ZJU07的预测性能均为最佳.对于彩度差数据,六个色差公式彩度权重函数的预测性能表现不佳;而对于色调差数据,CIEDE2000色调权重函数的预测性能明显优于其他公式.