小间隙高放大多丝室及其放电机制

对以强猝灭气体工作的小间隙多丝室及其放电机制进行了研究,实验表明,因为工作在饱和模式区,这种室同时具有很高的气体放大和相当快的时间特性.文中探讨了放电机制,雪崩中空间电荷效应以及电离光子的产生和作用是重要的因素,而其中后一因素又受到强猝灭气体的抑制.     

Investigation on ultrafast thrid—order optical nonlinearity of metal（dmit）2／mnt）2 Charge transfer complexes

We have investigated the transient third-order optical nonlinearity of the solutions of Metal(dmit)2/(mnt)2 salts in acetone by employing femtosecond optical Kerr gate measurement at 830nm wavelength.An order of enhancement on the second-order hyperppolarizability is found for the above salts with central atoms of Cu and Ni.We have suggested an explanation for the enhancement based on the extension of electronic conjugation by the entring Cu or Ni atom.     

Synthesis and characterization of wholly aromatic poly(azomethine)s containing donor–acceptor triphenylamine moieties

N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl₃), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (T_gs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (Φ_F) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007     

Thermal Analysis in Examination of Reduction of Blast Furnace Pellets

This paper presents applications of thermal analysis to observe the course of reduction of acidic pellets, metallurgical substances whose reducibility and strength are basic parameters of use in blast furnace processes. Both parameters depend on the mineral composition of the samples. The investigations included determination of the chemical and phase compositions of the initial samples and reduction products. Research was conducted on acidic pellets from Połtawa (Poland), applied in the T. Sendzimir Steelworks (Poland), in comparison with pellets from Brazil, Canada and Lebedyn (Russia). This revised version was published online in August 2006 with corrections to the Cover Date.     

光致折射效应中空间电荷场建立过程的研究

本文推导了包含自衍射及非线性吸收影响、用以描述空间电荷场建立过程的微分方程组,阐明了周期性的空间电荷场与光强干涉条纹之间的相位差在建立过程中所起的作用,并推导了描述条纹倾斜和弯曲的微分方程。通过数值计算找到了硅酸铋(BSO)晶体中能量转移的规律,讨论了材料特性对过程快慢的影响,提出了用CW激光来探讨瞬态过程快慢的可能性。     

Isospin symmetry violation, meson production and η-nucleus interaction studies

We have studied isospin symmetry violation in nuclear reactions by measuring simultaneously the cross-section of the following two reactionsp +d →³H π⁺ andp +d →³He π⁰. The experiment was perfomed at the cooler synchrotron accelerator COSY, Jülich at several beam energies close to the correspondingη production threshold. We also have ongoing programmes onη-nucleus final-state interaction studies viap+⁶ Li →⁷ Be +η reactions, high resolution search for dibaryonic resonances and lambda-proton final state interaction studies. The experimental details and results obtained so far are presented here     

Study on the Photophysical Process in N-Phenyl Phenothiazine and N-(2-Pyridine) Phenothiazine

By the measurements of the solvent and temperature effects of the fluorescence emission spectra and lifetime of N-phenyl phenothiazine (PHZ) and N-(2-pyridine) phenothiazine (PYZ),the existence of strongly twisted intramolecular charge transfer (TICT) state in PYZ emission spectra is proved.The exciplex formed by PHZ, PYZ and dimethyl terephthalate (DMTP) is investigated, and moreover, the transient absorption spectra of positive and negative ions as the results of the dissociation of the exciplex in the polar solvents is observed through the flash photolysis.     

Multinuclear magnetic resonance study of some mesoionic oxatriazoles containing nitrogenous exocyclic groups

¹H,¹³C,¹⁴N and¹⁵N NMR measurements are reported for four mesoionic 1-oxa-2, 3, 4-triazoles containing exocyclic nitrogenous groups. The NMR signal assignments are discussed and compared with those previously published for some corresponding oxatriazoles. The results obtained support the proposed cyclic mesoionic structures for the compounds studied. The questions of possible charge delocalization and valence tautomerism are addressed. Compound with N^– H as a exocyclic group (Fig. 1) is found to be relatively unstable, this is attributed to proton migration in the corresponding non-cyclic form of this molecule.Published in Khimiya Geterotsikiicheskikh Soedinenii, No. 9, pp. 1260–1263, September, 1995.