羟基磷灰石微球的制备、应用和功能化

羟基磷灰石(HA)是人体和动物骨骼的主要无机矿物成分。近年来,因HA具有特殊的表面特性和理化性能,良好的生物相容性、生物活性和骨传导作用,制备各种形态的HA材料成为从事生物、医学和材料的科研人员的研究重点。本文首先介绍了HA微球的制备方法,重点讨论了以聚合物为软模板以及用各种球形材料作为硬模板合成HA微球的制备方法,列出了不同方法制备HA微球的直径、孔径、比表面等各种性能参数。由于HA微球具有比表面积大、流动性好、质量轻、强度大,注射性能好,团聚能力低等HA块材不具有的特点,其在载体、骨修复材料、环境保护和色谱分离上有广泛的应用。针对HA微球在应用过程中遇到的问题,可采用表面改性或包覆、掺杂和将HA分散在其他基体中等措施对HA微球进行功能化修饰。HA 微球在控释载体、蛋白质分离以及细胞支架等方面具有极大的应用前景。     

Vibration analysis of a new polymer quartz piezoelectric crystal sensor for detecting characteristic materials of volatility liquid

We present a new polymer quartz piezoelectric crystal sensor that takes a quartz piezoelectric crystal as the basal material and a nanometer nonmetallic polymer thin film as the surface coating based on the principle of quartz crystal microbalance (QCM). The new sensor can be used to detect the characteristic materials of a volatile liquid. A mechanical model of the new sensor was built, whose structure was a thin circle plate composing of polytef/quartz piezoelectric/polytef. The mechanical model had a diameter of 8 mm and a thickness of 170 μ. The vibration state of the model was simulated by software ANSYS after the physical parameters and the boundary condition of the new sensor were set. According to the results of experiments, we set up a frequency range from 9.995850 MHz to 9.997225 MHz, 17 kinds of frequencies and modes of vibration were obtained within this range. We found a special frequency f_sp of 9.996358 MHz. When the resonant frequency of the new sensor’s mechanical model reached the special frequency, a special phenomenon occurred. In this case, the amplitude of the center point O on the mechanical model reached the maximum value. At the same time, the minimum absolute difference between the simulated frequency based on the ANSYS software and the experimental measured stable frequency was reached. The research showed that the design of the new polymer quartz piezoelectric crystal sensor perfectly conforms to the principle of QCM. A special frequency value f_sp was found and subsequently became one of the most important parameters in the new sensor design.     

Effect of normalized plasma frequency on electron phase-space orbits in a free-electron laser

Irregular phase-space orbits of the electrons are harmful to the electron-beam transport quality and hence deteriorate the performance of a free-electron laser （FEL）. In previous literature, it was demonstrated that the irregularity of the electron phase-space orbits could be caused in several ways, such as varying the wiggler amplitude and inducing sidebands. Based on a Hamiltonian model with a set of self-consistent differential equations, it is shown in this paper that the electron- beam normalized plasma frequency functions not only couple the electron motion with the FEL wave, which results in the evolution of the FEL wave field and a possible power saturation at a large beam current, but also cause the irregularity of the electron phase-space orbits when the normalized plasma frequency has a sufficiently large value, even if the initial energy of the electron is equal to the synchronous energy or the FEL wave does not reach power saturation.     

F-P腔不同扫频段透射谱锁频精度实验

针对窄线宽激光器输出谱线窄,难以被锁定的情况,利用F-P腔特有极窄线宽、高精细度特性对激光器谱线线宽实施压窄及频率锁定。通过设计实验方案并搭建锁频测试平台,利用F-P腔外部光反馈将窄线宽半导体激光器线宽压窄来提高锁频精度。通过监测正弦波调制下F-P腔对于4种不同直流电压下激光PZT扫频段的透射谱线,并对其分别进行解调和锁频精度测试,得到直流高压放大器电压为73 V时对窄线宽激光器进行扫频,激光器反馈锁频精度最高可达1.5 MHz。     

Pulsed microwave damage trend of bipolar transistor as a function of pulse parameters

In the present paper we conduct a theoretical study of the thermal accumulation effect of a typical bipolar transistor caused by high power pulsed microwave (HPM), and investigate the thermal accumulation effect as a function of pulse repetition frequency (PRF) and duty cycle. A study of the damage mechanism of the device is carried out from the variation analysis of the distribution of the electric field and the current density. The result shows that the accumulation temperature increases with PRF increasing and the threshold for the transistor is about 2 kHz. The response of the peak temperature induced by the injected single pulses indicates that the falling time is much longer than the rising time. Adopting the fitting method, the relationship between the peak temperature and the time during the rising edge and that between the peak temperature and the time during the falling edge are obtained. Moreover, the accumulation temperature decreases with duty cycle increasing for a certain mean power.     

Free vibration and critical speed of moderately thick rotating laminated composite conical shell using generalized differential quadrature method

The generalized differential quadrature method (GDQM) is employed to consider the free vibration and critical speed of moderately thick rotating laminated composite conical shells with different boundary conditions developed from the first-order shear deformation theory (FSDT). The equations of motion are obtained applying Hamilton’s concept, which contain the influence of the centrifugal force, the Coriolis acceleration, and the preliminary hoop stress. In addition, the axial load is applied to the conical shell as a ratio of the global critical buckling load. The governing partial differential equations are given in the expressions of five components of displacement related to the points lying on the reference surface of the shell. Afterward, the governing differential equations are converted into a group of algebraic equations by using the GDQM. The outcomes are achieved considering the effects of stacking sequences, thickness of the shell, rotating velocities, half-vertex cone angle, and boundary conditions. Furthermore, the outcomes indicate that the rate of the convergence of frequencies is swift, and the numerical technique is superior stable. Three comparisons between the selected outcomes and those of other research are accomplished, and excellent agreement is achieved.     

VIBRATION ANALYSIS OF A BEAM WITH EMBEDDED SHAPE MEMORY ALLOY WIRES

In this study, analytical relations for evaluating the exact solution of natural fre- quency and mode shape of beams with embedded shape memory alloy （SMA） wires are presented. Beams are modeled according to Euler-Bernoulli, Timoshenko and third order beam （Reddy） the- ories. A relation is obtained for determining the effect of axial load generated by the recovery action of pre-strained SMA wires. By defining some dimensionless quantities~ the effect of different me- chanical properties on the frequencies and mode shapes of the system are carefully examined. The effect of axial load generated by SMA wires with buckling load and frequency jump is accurately studied.     

基于超高频雷达的流量测量算法研究:以长江武汉段为例

水文站和船载测量的方法测量河流断面的流量受到船舶航行和河流水文条件的限制.本文以UHF雷达探测长江武汉段的试验数据为基础,构建表面流速与断面流速分布的关系模型,进而估算断面流量.把估算的结果与实测数据对比,验证了利用岸基UHF雷达测量河段流量的可行性.     

PPLN晶体差频测量飞秒激光脉冲的载波包络相移

在飞秒激光频率梳系统中，通常采用自参考技术测量飞秒激光脉冲的载波包络相移，但该技术需要采用光子晶体光纤进行光谱扩展从而增加了系统的不稳定性，这种技术已经制约了高稳定度的飞秒激光频率梳的发展.采用PPLN晶体差频法测量了宽谱钛宝石振荡器输出的7fs激光脉冲的载波包络频移，得到了大于30dB的拍频信号，为研制无光纤的新一代高稳定度光学频率梳奠定了基础.     

Structural, electronic and vibrational properties of indium oxide clusters

Geometric, electronic and vibrational properties of the most stable and energetically favourable configurations of indium oxide clusters In_mO_n (1≤m, n≤4) are investigated using density functional theory. The lowest energy geometries prefer the planar arrangement of the constituent atoms with a trend to maximize the number of ionic In-O bonds. Due to the charge transfer from In to O atoms, the electrostatic repulsion occurs between the atoms with the same kind of charge. The minimization of electrostatic repulsion and the maximization of In-O bond number compete between each other and determine the location of the isometric total energy. The most stable linear In-O-In-O structure of In₂O₂ cluster is attributed to the reduced electrostatic repulsive energy at the expense of In-O bond number, while the lowest energy rhombus-like structure of In₂O₃ cluster reflects the maximized number of In-O bonds. Furthermore, the vibrational frequencies of the lowest energy clusters are calculated and compared with the available experimental results. The energy gap and the charge density distribution for clusters with varying oxygen/indium ratio are also discussed.