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191.
Laser driven shocks can lead to a dynamic failure, called film spallation. Here, we use a modified laser spallation set-up
to measure the dynamic adhesion of thin films and we propose a novel diagnostic technology. Based on correlation theory, new
spallation criteria for characterizing the progressive damage at the interface between the film and the substrate are established,
such as interface delamination, film spallation and film expulsion. With the help of the theory, the degree of damage and
the dimension of damage (i.e. fracture), such as the minimum width of delamination radius, the thickness of the film etc.,
are estimated. Experiments are carried out on epoxy/stainless steel and epoxy/Al, and the experimental results show that their
dynamic bonding strengths are about 25 MPa and 20 MPa, respectively. The detailed results, analyses and discussions are presented
in this paper.
Received: 6 February 2001 / Accepted: 3 December 2001 / Published online: 11 February 2002 相似文献
192.
条件愈苦,意志愈坚 --记王淦昌早年的科研活动 总被引:1,自引:0,他引:1
文章介绍了中国物理学家王淦昌早期的科研工作,特别是在抗日战争时期的科研成绩.王淦昌早期的科研贡献并不是在先进的实验仪器上,在条件优裕的实验室内完成的,而是在实验设备缺乏,科学文献不足等极端困难的环境中完成的.从王淦昌身上,可以看到那个时代中国优秀科学家脚踏实地、执志若金的奋斗精神. 相似文献
193.
194.
在原子、分子和纳米材料中的高次谐波为非线性光学开辟了一个崭新的研究领域.其响应时间之短、能量之高,引起了人们的高度重视.目前的研究达到了白热化的程度.还有很多问题没有解决.文章首先简要地介绍了这一个新的领域.然后用一个简单的例子引出有名的辐射截断方程,最后用C60作为一个例子说明如何详细地计算辐射能量谱. 相似文献
195.
A.R. Phani M. PassacantandoS. Santucci 《Journal of Physics and Chemistry of Solids》2002,63(3):383-392
Crack free, dense and transparent CdTiO3 thin films have been prepared by sol-gel technique using titanium butoxide and cadmium acetate. The formation of the CdTiO3 phase started from 500°C annealing temperature onwards. The complete orthorhombic structure of CdTiO3 was formed on Silicon (100) substrate at an annealing temperature of 600°C for 5 h. As the annealing temperature increased from 600 to 700°C, we have observed the cadmium silicate phase at the interface of Si and CdTiO3 phase. Structural, morphological and elemental evolution of these CdTiO3 thin films produced by sol-gel synthesis were characterised by grazing incidence X-ray diffraction (GIXRD), tapping mode atomic force microscopy (TMAFM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) respectively. 相似文献
196.
Jianjun Liu Chun-gang DuanM.M Ossowski W.N MeiR.W Smith J.R Hardy 《Journal of Physics and Chemistry of Solids》2002,63(3):409-414
Structural phase transition in AgNO3 at high temperature is simulated by molecular dynamics. The simulations are based on the potentials calculated from the Gordon-Kim modified electron-gas formalism extended to molecular ionic crystals. AgNO3 transforms into rhombohedral structure at high temperature and the phase transition is associated with the rotations of the NO3 ions and displacements of the NO3 and Ag ions. 相似文献
197.
Delong Zhang Xiaojun ChenYufang Wang Dengsong ZhuBo Wu Guoxiang Lan 《Journal of Physics and Chemistry of Solids》2002,63(2):345-358
Raman spectra of as-grown and vapor transport equilibration (VTE) treated Er:LiNbO3 crystals, which have different cut orientations (X-cut and Z-cut), different Er-doping levels (Er:(0.2, 0.4 and 2.0 mol%)LiNbO3) and different VTE durations (80, 120, 150 and 180 h), were recorded at room temperature in the wavenumber range 50-1000 cm−1 by using backward scattering geometry. The spectra were attributed on the basis of their spectral features and the previous experimental work and the most recent theoretical progress in lattice dynamics on pure LiNbO3. In comparison with the pure crystal the most remarkable effect of Er-doping on the Raman spectrum is observed for the E(TO9) mode. It does not appear at 610 cm−1 as the pure crystal, but locates at 633 cm−1. In addition, the doping also results in the lowering of the Raman phonon frequency, the broadening of the Raman linewidth and the changes of the relative Raman intensity of some peaks. The VTE treatment results in the narrowing of the linewidth, the recovery of the lowered phonon frequency and the further changes of relative Raman intensity. The narrowing of Raman linewidth indicates that the VTE processing has brought these crystals closer to stoichiometric composition. The VTE treatment has induced the formation of a precipitate ErNbO4 in the high-doped Er(2.0%):LiNbO3 crystals whether X- or Z-cut. For these precipitated crystals, besides above linewidth and phonon frequency features, they also display more significant Raman intensity changes compared with those not precipitated crystals. In addition, a slight mixing between A1(TO) and E(TO) spectra is also observed for these precipitated crystals. Above doping and VTE effects on Raman spectra were quantitatively or qualitatively correlated with the characteristics of the crystal structure and phonon vibrational system. 相似文献
198.
Eriko Ohshima Keiji KusabaSinji Onodera Masae Kikuchi 《Journal of Physics and Chemistry of Solids》2002,63(3):419-423
High-pressure phase transition of Ta2NiO6 with the trirutile-type structure was investigated from the viewpoint of crystal chemistry. A new quenchable high-pressure phase was found in the pressure range higher than 7 GPa and 900°C. The high-pressure phase has an orthorhombic cell (a=4.797(1) Å, b=5.153(2) Å and c=14.85(1) Å and space group; Abm2), and it is more dense by 9.6% than the trirutile-structured phase. Infrared spectra of the trirutile-type phase and the high-pressure phase show that Ni2+ ions in the high-pressure phase are still in octahedral sites. The crystal structure of the high-pressure phase is considered as a cation-ordering trifluorite-type structure, which can be stabilized by a crystal field effect of Ni2+ ions. 相似文献
199.
We report successful fabrication of Ag doped Hg:1223 films by reacting Ba2Ca2.3Cu3.3Oz(Agy): y=0, 0.02, 0.025, 0.05, 0.1 and 0.2 precursors deposited by spray pyrolysis on SrTiO3 (100) substrates, in controlled Hg+Pb ambient, in an evacuated sealed quartz tube at 820 °C for 4 h. The effects of AgNO3 addition on the superconducting properties of Hg/(Pb):1223 films are studied. The addition of low concentration of silver e.g. y≈0.025 results in a slight increase in Tc (R=0) from 125 to 126 K and the dc critical current density (Jc) decreases with the increasing Ag in Hg(Pb):1223 (Agy) films. The microstructural details exhibit the curious characteristics of spiral like features for lower concentrations of silver i.e. up to y=0.05. These improvements are believed to be due to the liberation of oxygen through the dissociation of AgNO3 at higher temperature and passivation of weak link effects through the segregation of silver at these grain boundaries. The addition of silver content y≥0.05 resulted in the decrease in transition temperature. The Jc is observed to decrease steadily with increasing Ag content. The microstructural features, e.g. spiral are also found to deteriorate with increasing silver content. The deterioration in superconducting properties at high Ag content is believed to be mainly due to the formation of Ag-Hg amalgam. 相似文献
200.
H.S RagabA Shehap M.S Abo EllilW.H Osman F.H Abd El-Kader 《Journal of Physics and Chemistry of Solids》2002,63(10):1839-1847
Ternary-phase ceramic system of Li2O Al2O3 4SiO2 doped with CuO, FeO and TiO2 has been prepared and subjected to dc electrical conductivity and thermally stimulated depolarization current (TSDC) measurements as a function of temperature (30-250 °C) and field strength. The electrical conductivity results are explained by assuming both ionic and electronic conduction mechanisms coexist with different contributions over the whole temperature range of experiments. TSDC spectra have been found to be characterized by a broad intense relaxation peak, which can be attributed to an ionic charge polarization. The broad relaxation transitions are apparently a result of the nonuniform nature of this process. Activation energies are calculated for both dc electrical conductivity and TSDC according to Arrhenius equation and initial rise method, respectively. 相似文献