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101.
Takuya OkadaKazuhiko Sakaguchi Tetsuro ShinadaYasufumi Ohfune 《Tetrahedron letters》2011,52(44):5744-5746
The stereoselective total synthesis of (−)-funebrine from 2-butyn-1-ol was described. The crucial steps in the synthesis involved the stereoselective enolate Claisen rearrangement of the (S)-α-acyloxy-α-alkynylsilane 8, the Au-catalyzed regio- and stereoselective lactonization of the allenylsilane 7, and the Paal-Knorr pyrrole condensation using an unsymmetrical 1,4-diketone 4b. 相似文献
102.
R.R. Teixeira L.C.A. Barbosa J.W.de M. Carneiro J. Ellena 《Journal of Molecular Structure》2009,917(1):1-9
The synthesis and structural analysis of a set of nostoclide analogues with potential herbicide activity is described. The influence of intra- and intermolecular hydrogen bonding, as well as other interactions on the conformation and packing of the compounds is thoroughly described using DFT calculations and single crystal X-ray diffraction analyses. All lactones exhibited the Z configuration as confirmed by NOESY experiments and by single crystal X-ray diffraction measurements. 相似文献
103.
104.
105.
The present experimental status in the search for neutrinoless double beta decay is reviewed, with emphasis on the first indication for neutrinoless double beta decay found in the HEIDELBERG-MOSCOW experiment, giving first evidence for lepton number violation and a Majorana nature of the neutrinos. Future perspectives of the field are briefly outlined. 相似文献
106.
Current state-of-the-art techniques for CO2 capture are presented and discussed. Post-combustion capture of CO2 by absorption is the technology most easily retrofitted to existing installations, but at present this is not economically viable to install and run. Using ionic liquids instead of aqueous amine solutions overcomes the major thermodynamic issues. By applying SILP technology further advances, in terms of ease of handling and sorption dynamics, are obtained. Initial experimental studies showed that ionic liquids such as tetrahexylammonium prolinate, [N6666][Pro], provide a good candidate for CO2 absorption using SILP technology. Thus a solid SILP absorber comprised of 40 wt% [N6666][Pro] loaded on precalcined silica quantitatively takes up about 1.2 mole CO2 per mole of ionic liquid in consecutive absorption-desorption cycles in a flow-experiment performed with 0.09 bar of CO2 (9% CO2 in He). 相似文献
107.
Summary This paper reports measurements of the current characteristics and of the signal corresponding to a constant concentration of Freon F-11 for an electron-capture detector, supplied with a pulse voltage with a changeable pulse duration, amplitude and repetition time. It was found that an additional voltage applied to the detector cathode increased the detector signal by about 50% and that the maximal signal was observed at 5 V. The influence of the polarized voltage on the electron caputure efficiency coefficient (p) measured with two detectors in series was demonstrated and the reliability of the sample mass calculation by means of (p) is discussed. 相似文献
108.
K.S. Kim Myung Ki Cheoun Yeungun Chung Hyung Joo Nam 《The European Physical Journal A - Hadrons and Nuclei》2001,11(2):147-154
New results for the double beta decay of 76
Ge are presented. They are extracted from data obtained with the HEIDELBERG-MOSCOW experiment, which operates five enriched
76
Ge detectors in an extreme low-level environment in the Gran Sasso underground laboratory. The two-neutrino-accompanied double
beta decay is evaluated for the first time for all five detectors with a statistical significance of 47.7 kg y resulting in
a half-life of T
1/2
2ν = [1.55±0.01(stat)+0.19
-0.15(syst)]×1021 y. The lower limit on the half-life of the 0νββ decay obtained with pulse shape analysis is T
1/2
0ν > 1.9×1025(3.1×1025) y with 90% C.L. (68% C.L.) (with 35.5 kg y). This results in an upper limit of the effective Majorana-neutrino mass of 0.35
eV (0.27 eV) using the matrix elements of A. Staudt et al.'s work (Europhys. Lett. 13, 31 (1990)). This is the most stringent limit at present from double beta decay. No evidence for a majoron-emitting decay
mode is observed.
Received: 22 August 2001 / Accepted: 18 October 2001 相似文献
109.
Gaetan?KerschenEmail author Alexander?F.?Vakakis Young?S.?Lee D.?Michael?Mcfarland Jeffrey?J.?Kowtko Lawrence?A.?Bergman 《Nonlinear dynamics》2005,42(3):283-303
The purpose of this study is to highlight and explain the vigorous energy transfers that may take place in a linear oscillator
weakly coupled to an essentially nonlinear attachment, termed a nonlinear energy sink. Although these energy exchanges are
encountered during the transient dynamics of the damped system, it is shown that the dynamics can be interpreted mainly in
terms of the periodic orbits of the underlying Hamiltonian system. To this end, a frequency-energy plot gathering the periodic
orbits of the system is constructed which demonstrates that, thanks to a 1:1 resonance capture, energy can be irreversibly
and almost completely transferred from the linear oscillator to the nonlinear attachment. Furthermore, it is observed that
this nonlinear energy pumping is triggered by the excitation of transient bridging orbits compatible with the nonlinear attachment being initially at rest, a common feature in most practical applications. A parametric
study of the energy exchanges is also performed to understand the influence of the parameters of the nonlinear energy sink.
Finally, the results of experimental measurements supporting the theoretical developments are discussed.
This study was carried out while the author was a postdoctoral fellow at the National Technical University of Athens and at
the University of Illinois at Urbana-Champaign. 相似文献
110.
Vasile Dinoiu Bernard Tinant Jean-Philippe Bouillon 《Journal of fluorine chemistry》2006,127(1):101-107
The paper presents a one-pot conversion of γ-keto-α-pentafluoroethyl thioester into new pyridazin-3-ones and α,β-unsaturated lactams. The structures of all new compounds were ascribed using 1D (19F, 1H, 13C) and 2D (1H-15N) NMR data, and X-ray diffraction analysis. Two possible competitive reaction mechanisms for the synthesis of pyridazin-3-ones and lactams are presented. 相似文献