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181.
An on-line Hg reduction technique using stannous chloride as the reductant was applied for accurate and precise mercury isotope ratio determinations by multi-collector (MC)-ICP/MS. Special attention has been paid to ensure optimal conditions (such as acquisition time and mercury concentration) allowing precision measurements good enough to be able to significantly detect the anticipated small differences in Hg isotope ratios in nature. Typically, internal precision was better than 0.002% (1 RSE) on all Hg ratios investigated as long as approximately 20 ng of Hg was measured with a 10-min acquisition time. Introducing higher amounts of mercury (50 ng Hg) improved the internal precision to <0.001%. Instrumental mass bias was corrected using 205Tl/203Tl correction coupled to a standard-sample bracketing approach. The large number of data acquired allowed us to validate the consistency of our measurements over a one-year period. On average, the short-term uncertainty determined by repeated runs of NIST SRM 1641d Hg standard during a single day was <0.006% (1 RSD) for all isotope pairs investigated (202Hg/198Hg, 202Hg/199Hg, 202Hg/200Hg, and 202Hg/201Hg). The precision fell to <0.01% if the long-term reproducibility, taken over 11 months (over 100 measurements), was considered. The extent of fractionation has been investigated in a series of sediments subject to various Hg sources from different locations worldwide. The ratio 202Hg/198Hg expressed as δ values (per mil deviations relative to NIST SRM 1641d Hg standard solution) displayed differences from +0.74 to −4.00‰. The magnitude of the Hg fractionation per amu was constant within one type of sample and did not exceed 1.00‰. Considering all results (the reproducibility of Hg standard solutions, reference sediment samples, and the examination of natural samples), the analytical error of our δ values for the overall method was within ±0.28‰ (1 SD), which was an order of magnitude lower than the extent of fractionation (4.74‰) observed in sediments. This study confirmed that analytical techniques have reached a level of long-term precision and accuracy that is sufficiently sensitive to detect even small differences in Hg isotope ratios that occur within one type of samples (e.g., between different sediments) and so far have unequivocally shown that Hg isotope ratios in sediments vary within approximately 5‰. 相似文献
182.
I. S. Molchan G. E. Thompson P. Skeldon N. Trigoulet A. Tempez P. Chapon N. Tuccitto A. Licciardello 《Surface and interface analysis : SIA》2010,42(4):211-214
The performance of glow discharge time‐of‐flight mass spectrometry in isotopic differentiation is revealed using the distribution of oxygen isotopes 16O and 18O in barrier‐type anodic alumina films as a focus. Anodic alumina films comprising 18O‐rich layers of controlled thickness were formed by the appropriate combination of anodising of superpure aluminium in electrolytes enriched with 18O isotopes and of natural abundance of 18O isotopes. Analysis of the elemental depth profiles of selected ionic species, i.e. 16O18O, allowed determination of the locations of the 18O‐rich layers and the 18O/16O interface. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
183.
固相微萃取-气相色谱/同位素质谱法测定水中挥发性有机物单体碳同位素 总被引:1,自引:0,他引:1
建立了采用75μm碳分子筛/聚二甲基硅氧烷(CAR-PDMS)纤维的固相微萃取-气相色谱/同位素质谱联用方法测定水中挥发性有机污染物碳同位素。使用浸入式固相微萃取和顶空固相微萃取方法进行实验确定在低浓度条件下最佳δ13C测试方法。通过使用顶空固相微萃取前处理技术进行单体同位素分析分析灵敏度更高,应用CSIA技术对1,2-二氯乙烯,三氯乙烯,四氯化碳进行单体同位素分析,方法的检出限为70μg/L,与样本的标准偏差小于0.3‰。该法适用于水体中微量挥发性有机污染物的同位素组成测定。 相似文献
184.
端三吡啶基聚异丙基丙烯酰胺的合成及其金属配合物 总被引:1,自引:1,他引:0
合成出三吡啶官能化的二硫代酯并以其作为链转移剂进行了异丙基丙烯酰胺(NIPAAm)的可逆加成断裂链转移(RAFT)聚合,得到分子量可控和窄分子量分布的端三吡啶基聚异丙基丙烯酰胺(tpy-PNIPAAm),聚合反应为对单体浓度的一级动力学关系.Tpy-PNIPAAm在水中既保持了与聚异丙基丙烯酰胺类似的相转变行为,又拥有三吡啶(tpy)的强络合能力.将tpy-PNIPAAm与金属核素模型进行络合得到金属配合物,所得金属配合物在水中拥有与PNIPAAm类似的相转变行为,同时tpy-PNIPAAm的金属配合物由于其两亲性,在水中可以形成纳米粒子,由于纳米粒子间的静电排斥作用,这种纳米粒子即使在高于相转变温度时,仍能稳定于水中. 相似文献
185.
J. Dilling G. Audi D. Beck G. Bollen F. Herfurth A. Kellerbauer H.-J. Kluge D. Lunney R.B. Moore C. Scheidenberger S. Schwarz G. Sikler J. Szerypo 《Hyperfine Interactions》2001,132(1-4):329-333
The masses of the xenon isotopes with 114≤A≤123 were directly measured for the first time. The experiments were carried out at the ISOLTRAP triple trap spectrometer
at the on-line mass separator ISOLDE/CERN. A mass resolving power of the Penning trap spectrometer of m/Δm≈500 000 was chosen and an accuracy of δm≈12keV for all investigated Xe isotopes was achieved. An atomic mass evaluation was performed and the results of this adjustment
are compared with theoretical predictions. The new results for the xenon isotopes and their effects on neighboring nuclides
are discussed within the two-neutron separation energy picture.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
186.
S. C. Zerbetto E. C. C. Vasconcellos 《International Journal of Infrared and Millimeter Waves》1994,15(5):889-933
Methanol (CH3OH) is considered today one of the most important active media for the generation of laser radiation in the far-infrared (FIR) spectral region. Together with ten of its other isotopic species, it is responsible for the major part of the laser lines generated by the optical pumping technique. Due to the extreme importance of those molecules as laser generators, we understood that there was a necessity of a comprehensive work which would include as much pratical information as possible about each line.Chang et al(1) early recognized methanol as a source of strong FIR laser lines. Since then, more than 100 papers were published containing information about new laser emission. Recently, Moruzzi et al(114) presented a review of 575 lines produced by12CH3OH. In the present paper, we have extended the review to the various isotopic modifications of this molecule (namely13CH3OH, CD3OH,13CD3OH, CD3OD,13CD3OD, CH3OD, CH
3
18
OH, CH2DOH, CH2DOD and CHD2OH), a total of nearly 2000 lines with wavelengths ranging from 19µm to 3030µm. 相似文献
187.
Despite the large number of successful applications of laser ablation, elemental and isotopic fractionation coupled to inductively coupled plasma mass spectrometry (ICP-MS) remain as the main limitations for many applications of this technique in the fields of analytical chemistry and Earth Sciences. A substantial effort has been made to control such fractionations, which are well-established features of nanosecond laser ablation systems. Technological advancements made over the past decade now allow the ablation of solids by femtosecond laser pulses in the deep ultraviolet (UV) region at wavelengths less than 200 nm. Here the use of femtosecond laser ablation and its effects on elemental and isotopic fractionation is investigated. The Pb/U system is used to illustrate elemental fractionation and stable Fe isotopes are used to illustrate isotopic fractionation. No elemental fractionation is observed beyond the precision of the multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) measurements. Without a matrix match between standard and sample, elemental fractionation is absent even when using different laser ablation protocols for standardization and samples (spot versus raster). Furthermore, we found that laser ablation-induced isotope ratio drifts, commonly observed during nanosecond laser ablation, are undetectable during ultraviolet femtosecond laser ablation. So far the precision obtained for Fe isotope ratio determinations is 0.1‰ (2 standard deviation) for the 56Fe/54Fe ratio. This is close to that obtainable by solution multiple-collector inductively coupled plasma mass spectrometry. The accuracy of the results appears to be independent of the matrix used for standardization. The resulting smaller particle sizes reduce fractionation processes. Femtosecond laser ablation carries the potential to solve some of the difficulties encountered during the two prior decades since the introduction of laser ablation. 相似文献
188.
Cs5[Na{W4N10}] was prepared from a mixture of NaNH2, CsNH2 and tungsten powder (molar ration 1 : 10 : 4) at 700°C in autoclaves. After the reaction is finished the nitride is embedded in an alkali metal matrix. Dark red crystals were isolated by washing out the alkali metal with liquid ammonia at room temperature. The structure of Cs5[Na{W4N10}] was solved by X-ray single crystal data: I41 (No. 80), Z = 4, a = 13.926(3) Å, c = 8.723(3) Å, Z(F) ≥ 3σ(F) = 1535, Z(Variables) = 63, R/Rw = 0.040/0.052. The compound is highly sensitive against moisture giving oxotungstates and ammonia. It contains a framework of tetrahedra [WNN3/21.5?]. Sodium shares four terminal nitrogen ligands. Including sodium a distorted, β-cristobalite type arrangement [Na{W4N10}5?] results. It contains caesium in all interstices formed by twelve nitrogen ligands in so-called Friauf polyhedra. 相似文献
189.
质子滴线区新核素25P的鉴别 总被引:1,自引:1,他引:0
在兰州放射性束流装置RIBLL上 ,利用磁刚度Bρ、飞行时间tTOF和多重望远镜ΔE- E联合探测方法测量了69Me V/u 36Ar轰击Be靶产生的 P同位素碎片的同位素分布,并与 EPAX经验公式的计算结果进行了比较 ,在质子滴线区首次鉴别出了新核素25PThe mass distribution of the phosphor fragments induced by projectile fragmentation reaction of 69 MeV/u 36Ar + 9Be was measured at the projectile fragment separator RIBLL at IMP. The fragment products were identified by determining the magnetic rigidity Bρ , the time of flight tTOF and their energy loss ΔE . The experimental isotope distribution was compared to the result of the empirical parameterization EPAX. Three events for the new nuclide 25P in the... 相似文献
190.