Heat capacity and thermodynamic functions of LuPO4 in the range 0-320 K

The heat capacity of LuPO₄ was measured in the temperature range 6.51-318.03 K. Smoothed experimental values of the heat capacity were used to calculate the entropy, enthalpy and Gibbs free energy from 0 to 320 K. Under standard conditions these thermodynamic values are: (298.15 K) = 100.0 ± 0.1 J K⁻¹ mol⁻¹, S⁰(298.15 K) = 99.74 ± 0.32 J K⁻¹ mol⁻¹, H⁰(298.15 K) − H⁰(0) = 16.43 ± 0.02 kJ mol⁻¹, −[G⁰(298.15 K) − H⁰(0)]/T = 44.62 ± 0.33 J K⁻¹ mol⁻¹. The standard Gibbs free energy of formation of LuPO₄ from elements Δ_fG⁰(298.15 K) = −1835.4 ± 4.2 kJ mol⁻¹ was calculated based on obtained and literature data.     

Thermodynamics of BaNd2Fe2O7(s) and BaNdFeO4(s) in the system BaNdFeO

Two compounds, BaNd₂Fe₂O₇(s) and BaNdFeO₄(s) in the quaternary system BaNdFeO were prepared by citrate-nitrate gel combustion route and characterized by X-ray diffraction analysis. Heat capacities of these two oxides were measured in two different temperature ranges: (i) 130-325 K and (ii) 310-845 K, using a heat flux type differential scanning calorimeter. Two different types of solid-state electrochemical cells with CaF₂(s) as the solid electrolyte were employed to measure the e.m.f. as a function of temperature. The standard molar Gibbs energies of formation of these quaternary oxides were calculated as a function of temperature from the e.m.f. data. The standard molar enthalpies of formation from elements at 298.15 K, ΔfHm° (298.15 K) and the standard entropies, Sm° (298.15 K) of these oxides were calculated by the second law method. The values of ΔfHm° (298.15 K) and Sm° (298.15 K) obtained for BaNd₂Fe₂O₇(s) are: −2756.9 kJ mol⁻¹ and 234.0 J K⁻¹ mol⁻¹ whereas those for BaNdFeO₄(s) are: −2061.5 kJ mol⁻¹ and 91.6 J K⁻¹ mol⁻¹, respectively.     

Binding of cetylpyridinum chloride to glucose oxidase

The binding of cetylpyridinum chloride (CPC) with glucose oxidase (GOD) has been extensively studied at various experimental conditions such as ionic strength, urea concentration and pH at 25 °C, using ion-selective membrane electrodes, UV–vis absorption spectroscopy and enzyme activity assay method. The accurate binding isotherms have been obtained and analyzed in terms of Scatchard plot and binding capacity concept. The results represent two binding set system for most of studied conditions. The values of Hill equation parameters have been estimated and used for calculation of intrinsic Gibbs free energy of binding. The results have been interpreted in terms of structural viewpoint of GOD and nature of interactions in the solution. The interpretations are in good agreement with denaturation experiment. Activity measurements represent the significant activation of enzyme due to binding of first CPC molecules. However, the binding of subsequent CPC diminished the activity of enzyme which may be due to the binding of second CPC to enzyme active site. The complete deactivation of enzyme is reached due to binding of about five CPC ions.     

GFRP加固RC双向板抗爆性能试验研究

为探讨化爆条件下玻璃纤维对钢筋混凝土结构的加固效果,对粘贴玻璃纤维条带钢筋混凝土复合板以及普通钢筋混凝土板同时进行了抗爆性能试验,并将两者的结果进行了对比分析。结果表明,玻璃纤维能够有效阻止混凝土裂缝的发展,提高钢筋混凝土板的抗爆能力,研究结果可为玻璃纤维加固机理研究及复合结构的抗爆设计提供依据和参考。     

考虑仓库容量扩张的多周期随机存贮模型——折扣准则

研究了仓库容量可以控制的、基于折扣准则的多周期随机存贮模型.利用马氏决策过程(MDP)的方法,建立了最小折现成本所满足的最优方程,在此基础上,得到了一个(Ut*,yt*(b))结构的最优策略:当仓库容量小于Ut*时将容量扩充到Ut*,并订货至Ut*;否则保持仓库容量不变,且当存贮量小于yt*(b)时订货到yt*(b),反之不订货.     

Removable singularities for weighted Bergman spaces

We develop a theory of removable singularities for the weighted Bergman space , where μ is a Radon measure on ℂ. The set A is weakly removable for , and strongly removable for . The general theory developed is in many ways similar to the theory of removable singularities for Hardy H ^p spaces, BMO and locally Lipschitz spaces of analytic functions, including the existence of counterexamples to many plausible properties, e.g. the union of two compact removable singularities needs not be removable. In the case when weak and strong removability are the same for all sets, in particular if μ is absolutely continuous with respect to the Lebesgue measure m, we are able to say more than in the general case. In this case we obtain a Dolzhenko type result saying that a countable union of compact removable singularities is removable. When dμ = wdm and w is a Muckenhoupt A _p weight, 1 < p < ∞, the removable singularities are characterized as the null sets of the weighted Sobolev space capacity with respect to the dual exponent p′ = p/(p − 1) and the dual weight w′ = w ^{1/(1 − p)}.     

High-capacity purification of hen egg-white proteins by ion-exchange electrochromatography with an oscillatory transverse electric field

The ion-exchange electrochromatography with an oscillatory electric field perpendicular to the mobile-phase flow driven by pressure (pIEEC) was used to separate hen egg-white (HEW) proteins. The results were compared with those of normal ion-exchange chromatography (IEC). The column was designed as three-compartment rectangular column of 2-mL with dimensions (length x width x depth) of 40 x 10 x 5 mm(3) and the electric field was applied across the direction of column width. Q Sepharose FF was packed into the central compartment as the chromatographic bed. It was confirmed that the dynamic binding capacity (DBC) of different proteins (ovotransferrin and ovalbumin) in the HEW solution increased 2.3 times when an oscillatory electric current of 30 mA at 1/20 Hz was applied in the transverse column direction. Then, the HEW proteins were separated by the pIEEC at loading amounts 2.3-fold higher than those by the IEC. When the feedstock of about one-third of the DBC was applied to the columns (i.e., 7 mL for the pIEEC and 3 mL for the IEC), similar separation efficiencies of the two chromatographic modes were achieved. Both the recovery yield and purity reached 73% to over 90%. The results indicate that the pIEEC is promising for high-capacity purification of proteins.     

基于收益管理理论的门诊预约存量控制研究

门诊预约机制能够帮助医疗服务系统实现合理的资源组织与顺畅的服务流程,目前是医疗系统管理中的热点问题。论文分析了收益管理的适用性条件,提出其在医院门诊预约调度问题中应用的可行性,然后构建了门诊预约存量控制的Littlewood基础模型,并考虑患者爽约的情况,建立了超订策略下的门诊预约存量控制模型,最终用实例验证了所提出方法的实用性和有效性。     

新能源移动充电车路径优化问题研究

在绿色城市背景下,新能源汽车的数量快速增长,现有公共充电设施的不完善使得移动充电服务应运而生。投入运营成本较高而利润低成为阻碍移动充电业务运营的瓶颈之一,如何通过科学合理的调度提高平台利润成为重要问题。本文研究了移动充电车队的调度和路径优化问题,以平台最大收益为目标,综合考虑顾客软时间窗、移动电池容量以及充电车续航里程等约束,建立数学规划模型;设计了一种最大最小蚁群算法,并通过数值实验验证了模型的合理性和算法的有效性,为移动充电企业运营提供决策参考。