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41.
The ionic transport process in polymer electrolytes (such as polyethylene oxide) wassimulated numerically on a two dimensional square lattice where charge carriers areaccommodated by the lattice sites connected randomly with available bonds to represent theamorphous chain configuration. Following the dynamic bond percolation theory(DBPT),the chainmotion contribution to the ionic conduction was incorporated via periodical renewal of the randombond configuration. To check and extend the prediction made by DBPT employing global abruptbond renewal,spatial correlation of the bond reassignment was introduced to the system by: 1)regional bond renewal and 2) organized bond motion. It is found that the difference between thediffusivities simulated involving regional bond renewal and those of DBPT becomes negligiblewhen the bond renewal rate approaches the carrier hopping rate. 相似文献
42.
Orthorhombic inclusion compounds of cyclohexaamylose with methanol,n-propanol, acetic acid and water as guest molecules were studied using13C and2H NMR techniques.13C chemical shifts were correlated with structural data, whereas2H NMR lineshapes were used to derive information on guest molecule motions.Issued as NRCC No. 25568. Presented in part at the 2nd International Symposium on Clathrate Compounds and Molecular Inclusion Phenomena, Parma, Italy, 30 Aug.–3 Sept. 1982 相似文献
43.
Heat capacities C
p
and volumes V have been obtained at 25°C for the transfer of cholesteryl oleyl carbonate (ChOC) from a reference solvent, the highly-branched alkane 2,2,4,4,6,8,8-heptamethylnonane into various solvents. These include normal, branched, and cyclic alkanes as well as the pure cholesteric ChOC. V and most C
p
are associated with the change of environmental free volume during the transfer process and are predicted by the Prigogine-Flory theory. However, for n-alkane solvents with more than twelve carbons, C
p
is large, positive, and unattributable to free volume changes. It is consistent with a restriction of alkane segmental motion by the ChOC. The same mechanism has been proposed to explain an antiplasticization effect of ChOC on transitions in polymers. 相似文献
44.
M. A. Desando Y. P. Handa R. E. Hawkins C. I. Ratcliffe J. A. Ripmeester 《Journal of inclusion phenomena and macrocyclic chemistry》1990,8(1-2):3-16
The structure I clathrate hydrate of carbon monoxide has been studied using dielectric measurements and13C NMR spectroscopy. Broad, weak dielectric absorption curves with maxima at 2.2–3.8 K yieldE
a
= 0.14 kJ mol–1 for the average Arrhenius activation energy associated with the reorientation of the low polarity guest. Except for H2S this represents the fastest reorienting polar guest known among the clathrate hydrates. The low temperature dielectric absorption curves can best be fitted with a Cole-Davidson asymmetric distribution of relaxation times and activation energies (with = 0.06 at 4 × 106 Hz), which at 107 Hz has been resolved into a double symmetric distribution of discrete relaxation times for CO in the small and large cages. The cross-polarization magic angle spinning13C NMR spectra indicate identical chemical shifts for CO in the small and large cages, in contrast to other hydrates. The static spectra show that the CO molecules undergo anisotropic reorientation in the large cages and that there is still considerable mobility at 77 K. One possible model for the anisotropic motion has the CO rapidly moving among sites over each of the 14 faces of the cage with the CO axis orientated towards the cage centre. The cage occupancy ratio at 220 K,
s/
L = 1.11, indicates slightly greater preference of CO for the small cage.Dedicated to Dr D. W. Davidson in honor of his great contributions to the sciences of inclusion phenomena. 相似文献
45.
In spite of Sinai's result that the decay of the velocity autocorrelation function for a random walk on
d
(d=2) can drastically change if local impurities are present, it is shown that local impurities can not abolish weak convergence to the Brownian motion if d2. 相似文献
46.
47.
扁球面网壳的混沌运动研究 总被引:3,自引:0,他引:3
在圆形三向网架非线性动力学基本方程的基础上,用拟壳法给出了圆底扁球面三向网壳的非线性动力学基本方程.在固定边界条件下,引入了异于等厚度壳的无量纲量,对基本方程和边界条件进行无量纲化,通过Galerkin作用得到了一个含二次、三次的非线性动力学方程.为求Melnikov函数,对一类非线性动力系统的自由振动方程进行了求解,得到了此类问题的准确解.在无激励情况下,讨论了稳定性问题.在外激励情况下,通过求Melnikov函数,给出了可能发生混沌运动的条件.通过数字仿真绘出了平面相图,证实了混沌运动的存在. 相似文献
48.
在第25卷第5期的《大学物理》上,一篇文章对"广义芝诺悖论"进行了探讨,但他们分析的并不是"悖论"中的匀速率的理想运动,而且还存在推导错误.本文通过对"广义芝诺悖论"物理情境的分析,抽象建立起VPV模型,并由此得出:从运动学角度考虑,"广义芝诺悖论"正过程的初态和末态是"多对一"的关系,"广义芝诺悖论"并不为悖论. 相似文献
49.
The stability of the rolling motion of near space hypersonic vehicles with rudder control is studied using method of qualitative analysis of nonlinear differential equations, and the stability criteria of the deflected rolling motions are improved. The outcomes can serve as the basis for further study regarding the influence of pitching and lateral motion on the stability of rolling motion. To validate the theoretical results, numerical simulations were done for the rolling motion of two hypersonic vehicles with typical configurations. Also, wind tunnel experiments for four aircraft models with typical configurations have been done. The results show that: 1) there exist two dynamic patterns of the rolling motion under statically stable condition. The first one is point attractor, for which the motion of aircraft returns to the original state. The second is periodic attractor, for which the aircraft rolls periodically. 2) Under statically unstable condition, there exist three dynamic patterns of rolling motion, namely, the point attractor, periodic attractor around deflected state of rolling motion, and double periodic attractors or chaotic attractors. 相似文献
50.