Plant protein-based feeds and commercial feed enable isotopic tracking of aquaculture emissions into marine macrozoobenthic bioindicator species

Brittle stars (Ophiura spp.) and other benthic macrofauna were collected in a prospective mariculture area in the North Sea to determine if these taxa could be used as indicator species to track nutrients released from future offshore aquaculture sites. We analysed natural carbon and nitrogen stable isotopic signatures in tissues from macrofauna and compared these to six feed ingredients and four experimental diets made thereof, as well as to a commercial feed with and without lipid and carbonate removal. Our data suggest practicability of using isotopic signatures of Ophiura spp. to track aquaculture-derived organic material if plant-based fish diet ingredients and commercial feed were used for fish farming in the German Exclusive Economic Zone. Diets with high fish meal content would not be detected in Ophiura spp. using isotopic measures due to the similarity with the marine background. Our data provide valuable baseline information for studies on the impact of offshore aquaculture on the marine environment.     

Multi-scale defect interactions in high-rate brittle material failure. Part I: Model formulation and application to ALON

Within this two part series we develop a new material model for ceramic protection materials to provide an interface between microstructural parameters and bulk continuum behavior to provide guidance for materials design activities. Part I of this series focuses on the model formulation that captures the strength variability and strain rate sensitivity of brittle materials and presents a statistical approach to assigning the local flaw distribution within a specimen. The material model incorporates a Mie–Grüneisen equation of state, micromechanics based damage growth, granular flow and dilatation of the highly damaged material, and pore compaction for the porosity introduced by granular flow. To provide initial qualitative validation and illustrate the usefulness of the model, we use the model to investigate Edge on Impact experiments (Strassburger, 2004) on Aluminum Oxynitride (AlON), and discuss the interactions of multiple mechanisms during such an impact event. Part II of this series is focused on additional qualitative validation and using the model to suggest material design directions for boron carbide.     

缺陷介质切槽爆破断裂行为的动焦散线实验

利用数字激光动态焦散线实验系统,对含缺陷介质在切槽爆破和普通炮孔爆破中爆生裂纹的断裂行为进行对比研究。结果表明,切槽爆破中沿切槽方向起裂的主裂纹比非切槽方向早10 μs,有利于能量优先沿切槽方向释放;切槽方向主裂纹的起裂韧度为0.58 MN/m3/2,其裂纹扩展的平均速度为277 m/s,分别是普通爆破时主裂纹相应值的54%和86%;当切槽方向主裂纹与缺陷介质贯通后,为爆生气体提供了足够的膨胀空间,诱导爆生气体向预制裂纹两端释放,翼裂纹起裂以Ⅰ型拉伸破坏为主,并在裂纹扩展的60~250 μs内,Ⅰ型动态应力强度因子保持在0.6~0.8 MN/m3/2,形成了明显的平台,延缓了翼裂纹扩展速度的衰减,最终较普通炮孔翼裂纹扩展时间和扩展长度分别增加了22.7%和17.8%。     

平面碰撞与强激光加载下金属铝的层裂行为

在轻气炮和神光Ⅱ强激光装置上开展了金属铝的层裂实验。针对激光打靶层裂实验中样品自由面速度剖面后期振荡容易丢失问题,改进靶设计,获得很好效果。利用轻气炮加载和强激光加载层裂实验应变率的显著差异,并通过数值模拟,讨论了在建立具有预测能力的理论建模中需要关注的损伤成核、演化与汇合问题中的材料特性与应变率相关特性因素。结果表明,对于我们以前建立的动态损伤与断裂模型,微孔洞成核的平均半径、阈值压力、成核速率相关参数以及微孔洞长大的阈值压力等具有材料特性属性,但微孔洞的表面能以及决定材料发生完全层裂的临界损伤度等具有明显的应变率效应。另外,分析还发现,虽然层裂强度具有明显的应变率效应,但是在样品层裂当地,样品由持续拉伸向收缩转变的临界行为,取决于一个很小的临界损伤,这个临界值很可能是材料常数,与应变率无关。     

冲击载荷下镁铝合金裂纹动态扩展过程的数值模拟

采用基于黏聚裂纹模型的扩展有限元方法,开展了镁铝合金结构冲击破坏过程的数值模拟研究。通过镁铝合金三点弯曲试样冲击实验,获得了不同子弹撞击速度下试样的冲击破坏模式。在此基础上,建立了实验结构的扩展有限元模型,并采用最大主应力准则,以及含损伤型的本构关系模拟材料的冲击断裂行为。对于裂纹尖端附近区域,采用黏聚裂纹模型模拟裂纹的断裂过程。对子弹速度分别为12.2、15.1、26.3 m/s的3种工况下镁铝合金试样的动态破坏过程进行了数值模拟研究,获得了与实验相一致的断裂模式。计算结果表明,试样以Ⅰ型断裂模式为主,裂纹沿初始预制裂纹方向扩展。当裂纹扩展到一定程度后,在试样韧带区域被撞击端附近,由于应力波及边界效应导致该区域处于复杂应力状态,试样出现复合型断裂模式,裂纹偏离原扩展路径,与本文实验结果相吻合。     

内聚力模型的形状对胶接结构断裂过程的影响

内聚力模型被广泛应用于粘接结构的断裂数值模拟过程中,为深入分析不同形状内聚力模型与胶黏剂性质和粘接结构断裂之间的关系,本文分别采用脆性和延展性两种类型胶黏剂,对其粘接的对接试件进行了单轴拉伸、剪切实验,以及其粘接的双臂梁试件进行了断裂实验.3种类型的内聚力模型(抛物线型、双线型和三线型)分别模拟了以上粘接结构的断裂过程,并与实验结果进行对比.结果发现:双线型的内聚力模型适用计算脆性胶黏剂的拉伸与剪切的断裂过程;指数型内聚力模型较适合计算延展性胶黏剂的拉伸和剪切的断裂过程,临界应力、断裂能和模型的形状参数是分析拉伸和剪切的重要参数;双臂梁试件的断裂过程模拟结果发现,断裂曲线与胶黏剂性质有关,内聚力模型形状参数也有影响.通过实验与计算结果分析,双线型内聚力模型更适合脆性胶黏剂粘接的双臂梁断裂计算,而三线型更适合计算延展性胶黏剂粘接的双臂梁断裂过程,此研究结果对胶黏剂的使用和粘接结构的断裂分析有很重要意义.     

Finite size and geometrical non-linear effects during crack pinning by heterogeneities: An analytical and experimental study

Crack pinning by heterogeneities is a central toughening mechanism in the failure of brittle materials. So far, most analytical explorations of the crack front deformation arising from spatial variations of fracture properties have been restricted to weak toughness contrasts using first order approximation and to defects of small dimensions with respect to the sample size. In this work, we investigate the non-linear effects arising from larger toughness contrasts by extending the approximation to the second order, while taking into account the finite sample thickness. Our calculations predict the evolution of a planar crack lying on the mid-plane of a plate as a function of material parameters and loading conditions, especially in the case of a single infinitely elongated obstacle. Peeling experiments are presented which validate the approach and evidence that the second order term broadens its range of validity in terms of toughness contrast values. The work highlights the non-linear response of the crack front to strong defects and the central role played by the thickness of the specimen on the pinning process.     

Modeling crack growth during Li insertion in storage particles using a fracture phase field approach

Fracture of storage particles is considered to be one of the major reasons for capacity fade and increasing power loss in many commercial lithium ion batteries. The appearance of fracture and cracks in the particles is commonly ascribed to mechanical stress, which evolves from inhomogeneous swelling and shrinkage of the material when lithium is inserted or extracted. Here, a coupled model of lithium diffusion, mechanical stress and crack growth using a phase field method is applied to investigate how the formation of cracks depends on the size of the particle and the presence or absence of an initial crack, as well as the applied flux at the boundary. The model shows great versatility in that it is free of constraints with respect to particle geometry, dimension or crack path and allows simultaneous observation of the evolution of lithium diffusion and crack growth. In this work, we focus on the insertion process. In particular, we demonstrate the presence of intricate fracture phenomena, such as, crack branching or complete breakage of storage particles within just a single half cycle of lithium insertion, a phenomenon that was only speculated about before.     

扭转预应变对35CrMo钢低周疲劳性能的影响

自行设计了疲劳和扭转两用的试样,通过对试件预扭转不同的角度,系统研究35CrMo钢在不同扭转预应变下的低周疲劳性能,分析了扭转预应变后35CrMo钢的循环硬化软化特性、滞后回线、塑性应变能及循环弹性模量的变化规律,并对疲劳断口进行扫描电镜分析。结果表明:4种预扭转处理过的试件均表现出明显的循环软化行为,且循环软化规律及衰减的程度基本相同;循环应力范围及疲劳寿命随着预扭转角的增大而降低;应力应变滞后回线中加卸载曲线间的宽度随着预扭转角的增大而减小;塑性应变能都随着循环次数的增大而增加,且随着预扭转角的增大其增大速率下降;循环弹性模量都随着循环次数的增加而逐渐降低,且随着预扭转角的增大其衰减趋势减缓。