全文获取类型
收费全文 | 1576篇 |
免费 | 716篇 |
国内免费 | 94篇 |
专业分类
化学 | 536篇 |
晶体学 | 19篇 |
力学 | 91篇 |
综合类 | 18篇 |
数学 | 93篇 |
物理学 | 1629篇 |
出版年
2024年 | 12篇 |
2023年 | 16篇 |
2022年 | 52篇 |
2021年 | 73篇 |
2020年 | 56篇 |
2019年 | 51篇 |
2018年 | 77篇 |
2017年 | 108篇 |
2016年 | 91篇 |
2015年 | 100篇 |
2014年 | 182篇 |
2013年 | 180篇 |
2012年 | 158篇 |
2011年 | 177篇 |
2010年 | 138篇 |
2009年 | 128篇 |
2008年 | 113篇 |
2007年 | 96篇 |
2006年 | 86篇 |
2005年 | 87篇 |
2004年 | 62篇 |
2003年 | 51篇 |
2002年 | 49篇 |
2001年 | 40篇 |
2000年 | 34篇 |
1999年 | 22篇 |
1998年 | 20篇 |
1997年 | 20篇 |
1996年 | 23篇 |
1995年 | 16篇 |
1994年 | 11篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 5篇 |
排序方式: 共有2386条查询结果,搜索用时 15 毫秒
31.
32.
《Surface and interface analysis : SIA》2003,35(5):445-449
Surface states of polydimethylsiloxane (PDMS) treated by plasma were investigated by x‐ray photoelectron spectroscopy and surface voltage decay. X‐ray photoelectron spectroscopy confirmed the formation of a silica‐like (SiOx, x = 3–4) oxidative surface layer. This layer increased in thickness with increasing exposure duration of plasma. Plasma exposure lowers the surface resistivity from 1.78 × 1014 to 1.09 × 1013 Ω □?1 with increasing plasma treatment time. By measuring the decay time constant of surface voltage, the calculated surface resistivity was compared with the value measured directly by a voltage–current method; good agreement between the two methods was obtained. It was observed that plasma treatment led to a decrease in the thermal activation energy of the surface conduction from 31.0 kJ mol?1 for an untreated specimen to 21.8 kJ mol?1 for a plasma‐treated specimen for 1 h. Our results allow the examination of effects of plasma on the electrical properties of PDMS. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
33.
《Arabian Journal of Chemistry》2022,15(7):103933
In this study, a fingerprint-activity relationship modeling between chemical fingerprints and antirheumatic activity was established, and multivariate statistical analysis was used to evaluate the quality of Taxilli Herba (TH) from different hosts. Characteristic fingerprints of 20 batches of TH samples were generated by high-performance liquid chromatography coupled with triple quadrupole-time of flight tandem mass spectrometry (HPLC-Triple TOF-MS/MS), and the similarity analysis was calculated based on thirteen common characteristic peaks by hierarchical clustering analysis (HCA). Subsequently, nine efficacy markers were discovered by combining fingerprints and antirheumatic activity through grey correlation analysis (GCA) and bivariate correlation analysis (BCA). Meanwhile, the content of 5 constituents in 9 markers was determined by high-performance liquid chromatography coupled with triple quadrupole-linear ion trap tandem mass spectrometry (HPLC-QTRAP-MS/MS). The comprehensive quality of TH was assessed using multivariate statistical analysis, including principal components analysis (PCA) and technique for order preference by similarity to ideal solution (TOPSIS). The results showed that a high dose of TH extract could markedly ameliorate arthritis damage compared to other doses, with flavonoids playing an important role in the antirheumatic activity. The comprehensive quality of samples from Morus alba L. (SS) was superior to those from Liquidambar formosana Hance (FXS). The present study will demonstrate the markers associated with efficacy, and provide an applicable strategy for more comprehensive quality control and evaluation of TH. 相似文献
34.
Electron ionization (EI) mass spectra of 46 compounds from several different compound classes were measured. Their molecular ion abundances were compared as obtained with 70‐eV EI, with low eV EI (such as 14 eV), and with EI mass spectra of vibrationally cold molecules in supersonic molecular beams (Cold EI). We further compared these mass spectra in their National Institute of Standards and Technology (NIST) library identification probabilities. We found that
- Low eV EI is not a soft ionization method, and it has little or no influence on the molecular ion relative abundances for large molecules and those with weak or no molecular ions.
- Low eV EI for compounds with abundant or dominant molecular ions in their 70 eV mass spectra results in the reduction of low mass fragment ions abundances thereby reducing their NIST library identification probabilities thus rarely justifies its use in real‐world applications.
- Cold EI significantly enhances the relative abundance of the molecular ions particularly for large compounds; yet, it retains the low mass fragment ions; hence, Cold EI mass spectra can be effectively identified by the NIST library.
- Different standard EI ion sources provide different 70 eV EI mass spectra. Among the Agilent technologies ion sources, the “Extractor” exhibits relatively abundant molecular ions compared with the “Inert” ion source, while the “High efficiency source” (HES) provides mass spectra with depleted molecular ions compared with the “Inert” ion source or NIST library mass spectra.
35.
We study numerically the complex domains of validity for KAM theory in generalized standard mappings. We compare methods based on Padé approximants and methods based on the study of periodic orbits. 相似文献
36.
37.
Frequency and voltage-dependent electrical and dielectric properties of Al/Co-doped PVA/p-Si structures at room temperature
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
In order to investigate of cobalt-doped interracial polyvinyl alcohol (PVA) layer and interface trap (Dit) effects, A1/p- Si Schottky barrier diodes (SBDs) are fabricated, and their electrical and dielectric properties are investigated at room temperature. The forward and reverse admittance measurements are carded out in the frequency and voltage ranges of 30 kHz-300 kHz and -5 V-6 V, respectively. C-V or er-V plots exhibit two distinct peaks corresponding to inversion and accumulation regions. The first peak is attributed to the existence of Dit, the other to the series resistance (Rs), and interfacial layer. Both the real and imaginary parts of dielectric constant (er and err) and electric modulus (Mr and Mrr), loss tangent (tan~), and AC electrical conductivity (aac) are investigated, each as a function of frequency and applied bias voltage. Each of the M~ versus V and Mrr versus V plots shows a peak and the magnitude of peak increases with the increasing of frequency. Especially due to the Dit and interfacial PVA layer, both capacitance (C) and conductance (G/w) values are strongly affected, which consequently contributes to deviation from both the electrical and dielectric properties of A1/Co-doped PVA/p-Si (MPS) type SBD. In addition, the voltage-dependent profile of Dit is obtained from the low-high frequency capacitance (CLF-CHF) method. 相似文献
38.
Charged particles exist widely in variety of technological areas as well as in nature. Even a weak charge on the particles can significantly influence their electric interaction. We investigated the phenomenon of time-dependent electric interaction between two conducting spheres in an electrostatic field. A mirror-image method was developed to analyze this system, and the fundamental role of the charges on the spheres was studied. We concluded that charges conducted to the lower sphere through the alumina tube used in our system play a main role in determining the time-dependent interaction, whereas the influence from air ions is negligible. 相似文献
39.
40.
The laser breakdown time-of-flight mass spectrometry was developed and applied to detect the breakdown patterns of hydrocarbons that are significant to improve the detectability of heavy metals compounded in various mixtures such as particles and hydrocarbons. The laser wavelength dependence of this method was evaluated using 1064, 532, and 266 nm laser outputs. Breakdown processes using 1064 and 532 nm outputs showed less interference of fragmentation for the detection of various heavy metals. The method was applied to various hydrocarbons and it showed the possibility of categorization of hydrocarbon groups using the pattern of breakdown products. 相似文献