Environmental and economic comparison of waste solvent treatment options

The sustainable development and consumption need more efficient use of natural resources. As a consequence, the use of industrial solvents demands their recovery instead of end-of-pipe treatment. It is not always clear, however, which treatment alternative should be applied. Based on an industrial case study, the environmental and economic evaluation and comparison of the treatment alternatives of a non-ideal solvent mixture containing azeotropes is investigated for determining the preferable option. For the recovery of the industrial solvent mixture, two different separation alternatives are evaluated: a less effective alternative and a novel design based on hybrid separation tools. An end-of-pipe treatment alternative, incineration, is also considered and the split of the solvent mixtures between recovery and incineration is investigated. The environmental evaluation of the alternatives is carried out using ‘Eco-indicator 99 life-cycle impact assessment methodology’. Economic investigation is also accomplished. The economic features clearly favour the total recovery, however, the environmental evaluation detects that if a recovery process of low efficiency is applied, its environmental burden can be similar or even higher than that of the incineration. This motivates engineers to design more effective recovery processes and reconsider the evaluation of process alternatives at environmental decision making.     

Hamilton cycles in line graphs of 3-hypergraphs

We prove that every 52-connected line graph of a rank 3 hypergraph is Hamiltonian. This is the first result of this type for hypergraphs of bounded rank other than ordinary graphs.     

第II类双边拆卸线平衡问题建模与优化

报废汽车体积大,废弃物污染大,拆卸过程复杂,将作业任务均衡分配难。为此,本文对工作站数量确定的双边拆卸线平衡问题进行研究,建立问题数学模型,设计一种变邻域蛙跳算法。所提算法在寻优过程中采用变邻域搜索提高族群局部搜索效率;引入个体学习机制加快精英个体进化速度;提出基于二分法的节拍时间调整策略加快对最优节拍的搜索。最后,通过算例对算法性能进行验证并通过实例说明任务在拆卸线上平衡分配的重要性。     

Limit cycles of a class of Liénard systems derived from state-dependent impulses

Discontinuous phenomena, in which objects may behave continuously and sometimes discretely are not only found in nature and under laboratory conditions but also in simple, familiar contexts. For example, this phenomenon is skillfully incorporated into the internal structure of mechanical wristwatches. Unless an extremely small amount of state-dependent impulse is applied intermittently, the reciprocating rotational movement of the balance and hairspring, which is the heart of the mechanical wristwatch, cannot be maintained. The small amount of state-dependent impulse, which is often overlooked, can make a significant difference; however, very few studies have examined this subject. This study assumes the underlying cause of discontinuous behaviors as impulses generated when an object reaches a particular state, assuming that the continuous behavior follows the Liénard system, which is widely studied in the field of electrical circuits. The main theorem provides the conditions under which the effect of the impulses causes a stable limit cycle in the Liénard system, even if no limit cycle exists when there are no impulses. The Poincaré–Bendixson theorem for discontinuous dynamical systems and phase plane analysis are used to prove the main theorem. Several examples and their simulations are provided to illustrate the main theorem.     

Limit cycle analysis of a class of strongly nonlinear oscillation equations

The limit cycle of a class of strongly nonlinear oscillation equations of the form % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiqadwhagaWaaiabgUcaRmXvP5wqonvsaeHbbjxAHXgiofMCY92D% aGqbciab-DgaNjab-HcaOiaadwhacqWFPaqkcqWF9aqpcqaH1oqzca% WGMbGaaiikaiaadwhacaGGSaGabmyDayaacaGaaiykaaaa!50B8!\[\ddot u + g(u) = \varepsilon f(u,\dot u)\] is investigated by means of a modified version of the KBM method, where is a positive small parameter. The advantage of our method is its straightforwardness and effectiveness, which is suitable for the above equation, where g(u) need not be restricted to an odd function of u, provided that the reduced equation, corresponding to =0, has a periodic solution. A specific example is presented to demonstrate the validity and accuracy of our 09 method by comparing our results with numerical ones, which are in good agreement with each other even for relatively large .     

Cyclical games with prohibitions

We consider a certain combinatorial game on a digraph for two cases of the price function. For one case the game in question extends the cyclical game studied in Ehrenfeucht and Mycielski (1979) and Gurvitch, Karzanov and Khachiyan (1988) which, in its turn, is a generalization of the well-known problem of finding a minimum mean cycle in an edge-weighted digraph. We prove the existence of optimal uniform stationary strategies for both cases and give algorithms to find such strategies.This work was partially supported by Chaire municipale, Mairie de Grenoble.     

The regioselectivity of the formation of 2-pyrazolylthiazoles and their precursors from the reaction of 2-hydrazinothiazoles with 4,4,4-trifluoro-1-hetaryl-1,3-butanediones

Reaction of 2-hydrazinothiazoles 1 with 1-thienyl- and 1-furyl-1,3-butanediones 2a,b in methanol in the presence of hydrochloric acid mainly leads to a mixture of pyrazoles 3 and pyrazolines 4 or pyrazoles 3 and 5 in strong acidic conditions. Isomeric hydrazones 6 and pyrazolines 4 were formed and isolated in these reactions in the absence of hydrochloric acid. It has been shown that the regioselectivity in the reaction of diketones 2 with hydrazine 1 is governed by both the concentration of acid and the nature of substituents in the 1,3-diketones 2. Cyclization of hydrazones 6 is shown to occur under milder conditions than dehydration for pyrazolines 4. The new heterocyclic compounds were prepared and fully characterized by NMR spectra and by X-ray analysis for 3c.     

土壤环境中铅的化学

论述了环境中铅的背景值、来源、污染、质量标准、化学循环以及环境中铅的烷基化，为铅污染治理提供理论依据。     

Thermodynamic investigation of zirconium diselenite

Summary On the basis of calorimetric research of selenium dioxide, zirconium dioxide and zirconium diselenite dissolution reactions in the hydrofluoric acid solution under 298 K a standard enthalpy of Zr(SeO₃)₂ formation reaction from ZrO₂ and SeO₂ and a standard enthalpy of zirconium diselenite formation have been obtained. The value of enthalpy has been equal to -58.1±3.43 kJ mol^-1 in ZrO_2(solid)+2SeO_2(solid) Zr(SeO₃)_2(solid) reaction. The standard enthalpy of zirconium diselenite formation is equal to H_f,298⁰Zr(SeO₃)_2(solid)= -1603.2±3.8 kJ mol^-1. The H_f,298⁰ Zr(SeO₃)_2(solid) value has been determined for the first time.