648nm激光雪崩抽运掺Tm晶体的本征光学双稳特性研究

理论研究了648nm激光雪崩抽运掺Tm晶体的本征光学双稳态.根据系统的非线性速率方程理论，推导出了稳态近似下雪崩阈值的解析表达式，数值研究了光子雪崩动力学响应、本征光学双稳性以及系统参数对光学双稳态的影响等.研究结果表明，648nm激光抽运下可以观察到掺Tm激光晶体的2μm荧光辐射本征光学双稳态，通过改变可控的实验参数能够实现对光学双稳回线环的形状调节.     

Investigation of the linear and nonlinear properties of a Drude model photonic crystal

The optical transmission properties of a one-dimensional Drude model photonic crystal are investigated. The linear wave propagation is studied by the transfer matrix method. Using a delta-function approximation a nonlinear 2-d map is obtained and used to explore the global transmission properties of nonlinear wave propagation in this system. Inclusion of a frequency-dependent refractive index represented by the Drude model results in a considerable modification of the characteristics of the linear and nonlinear wave propagation of the one-dimensional photonic crystal.     

On the controlled propagation of wave signals in a sinusoidally forced two-dimensional continuous Frenkel-Kontorova model

The nonlinear processes of supratransmission and infratransmission are employed here in order to show numerically that binary information may be transmitted into (2 + 1)-dimensional, continuous Frenkel-Kontorova media spatially defined on a square, by perturbing harmonically two adjacent boundaries by means of Neumann conditions. The presence of these nonlinear phenomena is established numerically through a computational method that preserves the positivity of the energy operators, and that consistently approximates the solution of the model, the local energy density, the total energy and its dissipation; the existence of a region of bistability where two regimes coexist (conducting and insulating) is established as a corollary. The transmission of binary information is accomplished by fixing a frequency in the forbidden band-gap of the system, and modulating the amplitude of the signals as the sum of a seed (whose amplitude oscillates sinusoidally between the supratransmission and infratransmission thresholds) and small, positive, constant perturbations associated to nonzero bits. Our simulations show that a reliable transmission of information is indeed feasible.     

Optical bistability and multistability via quantum interference in an Er-doped optical fiber

The optical bistability and multistability in an Er³⁺-doped ZrF₄-BaF₂-LaF₃-AlF₃-NaF optical fiber inside a ring cavity are investigated. The underlying mechanism shows some new characteristics that other schemes do not have. Thus, it may provide some new possibilities for technological applications in optoelectronics and quantum information science.     

Intramolecular electron transfer and charge delocalization in bistable donor–acceptor systems based on perchlorotriphenylmethyl radicals linked to ferrocene and tetrathiafulvalene units

A comparative analysis of the physicochemical properties of different donor–acceptor dyads, based on a perchlorotriphenylmethyl radical acceptor subunit linked through a vinylene π‐bridge to ferrocene derivatives (1–3) or a tetrathiafulvalene (4) donor subunit, is presented. Intramolecular electron transfer and charge delocalization of these donor–acceptor dyads are discussed on the basis of data obtained in solution by cyclic voltammetry, UV–Vis near‐infrared, and electron spin resonance spectroscopies. Bistability in the crystalline phase is also discussed on the basis of the results provided by X‐ray diffraction analysis and temperature‐dependent Mössbauer spectra. Copyright © 2014 John Wiley & Sons, Ltd.     

Tetrathiafulvalene radical cation dimerization in a bistable tripodal [4]rotaxane

The template-directed synthesis of a bistable tripodal [4]rotaxane, which has cyclobis(paraquat-p-phenylene) (CBPQT4+) as the pi-electron-deficient rings, and tetrathiafulvalene (TTF) and 1,5-dioxynaphthalene units as the pairs of pi-electron-rich recognition sites located on all three legs of the tripodal dumbbell, is described. The chemical and electrochemical oxidation of the [4]rotaxane and its tripodal dumbbell have allowed us to unravel an unprecedented TTF.+ radical cation dimerization. In fact, two types of TTF dimers, namely, the radical cation dimer [TTF.+]2 and the mixed-valence one [(TTF)2].+, have been observed at room temperature for the tripodal dumbbell, whereas, in the case of the [4]rotaxane, only the radical cation dimer [TTF.+]2 is formed. This anomaly can be explained if it is accepted that most of the neutral TTF units in the [4]rotaxane are encircled by CBPQT4+ rings, which renders the formation of the mixed-valence dimer [(TTF)2].+ highly unfavorable.     

Noticeable positive Doppler effect on optical bistability in an N-type active Raman gain atomic system

We theoretically investigate the Doppler effect on optical bistability in an N-type active Raman gain atomic system inside an optical ring cavity.It is shown that the Doppler effect can greatly enhance the dispersion and thus create the bistable behaviour or greatly increase the bistable region,which has been known as the positive Doppler effect on optical bistability.In addition,we find that a positive Doppler effect can change optical bistability from the hybrid dispersion-gain type to a dispersive type.     

Controllable optical bistability of Bose-Einstein condensate in an optical cavity with a Kerr medium

We study the optical bistability for a Bose-Einstein condensate of atoms in a driven optical cavity with a Kerr medium. We find that both the threshold point of optical bistability transition and the width of optical bistability hysteresis can be controlled by appropriately adjusting the Kerr interaction between the photons. In particular, we show that the optical bistability will disappear when the Kerr interaction exceeds a critical value.     

ESI-FTICRMS与更换底物保护基团方法联用表征烯醇反应中间体

更换底物保护基团的化学方法与质谱、同位素标记以及核磁方法联用表征钯催化的烯醇环化反应中间体。实验表明更换底物的保护基团方法可以明显降低反应速度,延长关键中间体离子的存活寿命,不仅清晰地观察了反应的整个进程而且成功地捕获检测表征了其中关键中间体离子。进一步,串联质谱(SORI-CAD)方法研究了其中一些中间体离子的气相裂解反应行为,归纳总结其气相裂解反应的途径。结合同位素标记的结构为它们结构的确证提供了丰富信息。