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991.
Due to the extremely large de Broglie wavelength of cold molecules, cold inelastic scattering is always characterized by the time-independent close-coupling (TICC) method. However, the TICC method is difficult to apply to collisions of large molecular systems. Here, we present a new strategy for characterizing cold inelastic scattering using wave packet (WP) method. In order to deal with the long de Broglie wavelength of cold molecules, the total wave function is divided into interaction, asymptotic and long-range regions (IALR). The three regions use different numbers of ro-vibrational basis functions, especially the long-range region, which uses only one function corresponding to the initial ro-vibrational state. Thus, a very large grid range can be used to characterize long de Broglie wavelengths in scattering coordinates. Due to its better numerical scaling law, the IALR-WP method has great potential in studying the inelastic scatterings of larger collision systems at cold and ultracold regimes. 相似文献
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993.
贵金属钯(Pd)基纳米材料是一类具有优异催化活性的电催化材料,其中钯-铜(Pd-Cu)二元材料由于具有低成本和高活性的优点,近年来备受瞩目。铜(Cu)的引入不但降低了Pd的用量,还带来了诸如配体效应、应力效应、聚集体效应等协同作用,这为优化材料的电催化性能带来了多种切入角度。特殊形貌及结构的构建可以使催化剂暴露更多的活性位点,增大电化学活性表面积,提高电催化性能。此外,对Pd-Cu组分的调整或构建复合结构可以实现对d带中心的调控,从而优化电极界面吸附能,最终实现增强活性和改善稳定性的目的。本文总结了具有球形、多面体、核壳、多孔、枝晶状以及单原子等结构的Pd-Cu二元材料的制备方法,并概述了它们在有机小分子(甲醇、乙醇、甲酸等)电氧化、无机小分子(氧、二氧化碳、氮、水等)电还原以及化学镀铜上的应用。最后展望了Pd-Cu电催化剂的发展前景。 相似文献
994.
Experimental Study of the Thermal Decomposition Properties of Binary Imidazole Ionic Liquid Mixtures
Fan Yang Xin Zhang Yong Pan Hongpeng He Yuqing Ni Gan Wang Juncheng Jiang 《Molecules (Basel, Switzerland)》2022,27(4)
Ionic liquids (ILs) have a wide range of applications, owing to their negligible vapor pressure, high electrical conductivity, and low melting point. However, the thermal hazards of ILs and their mixtures are also non-negligible. In this study, the thermal hazards of various binary imidazolium ionic liquids (BIIL) mixtures were investigated. The effects of parent salt components and molar ratios on the thermal decomposition temperature (Td) and flashpoint temperature (Tf) are investigated. It is found that both Td and Tf increase as the proportion of highly thermally stable components in BIIL mixtures increases. Furthermore, the decomposition process of BIIL mixtures can be divided into two stages. For most molar ratios, the Tf of the BIIL mixtures is in the first stage of thermal decomposition. When the proportion of highly thermally stable components is relatively high, Tf is in the second stage of thermal decomposition. The flammability is attributed to the produced combustible gases during the thermal decomposition process. This work would be reasonably expected to provide some guidance for the safety design and application of IL mixtures for engineering. 相似文献
995.
为了更好地发挥中巴地球资源卫星的社会效益,同时为中巴地球资源卫星的使用和管理部门提供决策参考依据,应用条件价值法(CVM),采用支付意愿问卷调查的方式,通过数据统计和回归分析,对中巴地球资源卫星的社会效益进行定量评价,得到了影响中巴地球资源卫星社会效益支付意愿的主要因素.共发放问卷2330份,收回有效问卷2285份,通过对问卷数据的描述性统计,得到支付意愿的分布情况和在各单一因素影响下的变化规律.用主成分分析简化影响因素,运用二元Logit回归模型和Tobit模型,得到在所有的影响因素中,对中巴地球资源卫星的重视性、个人平均年收入是影响被调查者对中巴地球资源卫星社会效益的支付意愿的主要因素.研究结论使得中巴地球资源卫星的收益和成本的比较成为可能,为政府制定相关政策提供理论基础. 相似文献
996.
997.
998.
STAR’s measurement of directed flow for pions,kaons(K 0 S ),protons and anti-protons,for Au+Au collisions at 200 GeV obtained in Run7 are presented,as well as elliptic flow for identified particles measured in Au+Au(Run7) and Cu+Cu(Run5) collisions.It is found that the slope of proton v 1 (y) at midrapidity is extremely small.Elliptic flow results are compared to Hydro calculation and the discrepancy is discussed. 相似文献
999.
Dr. Xinjian Huang Dr. Haiqiang Deng Cheng Liu Jing Jiang Dr. Qiang Zeng Prof. Dr. Lishi Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(28):9523-9527
Direct electrochemical characterization of freely moving nanoparticles (NPs) at the individual particle level is challenging. A method is presented that can achieve this goal based on the collision between a NP and an ultramicroelectrode (UME). By applying a sinusoidal potential to the UME and monitoring the current response in the frequency domain, a sudden change in the phase angle indicates the arrival of a NP at the UME. The response induced by the collision can be isolated and used to explore the properties of the NP. This method, analogous to a high‐speed camera, can obtain a snapshot of the properties of the single NP at the moment of a collision. The proposed method was employed to investigate the properties of both the hard catalytic Pt NP and soft electroactive emulsion droplets, and many new insights were revealed thereafter. The method also has the potential to be applied in many other fields, where the interested signals appear as discrete events. 相似文献
1000.
《Mathematical Methods in the Applied Sciences》2018,41(12):4776-4794
Our aim in this paper is to study the asymptotic behavior, in terms of finite‐dimensional attractors, for higher‐order Navier‐Stokes‐Cahn‐Hilliard systems. Such equations describe the evolution of a mixture of 2 immiscible incompressible fluids. We also give several numerical simulations. 相似文献