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981.
Quantitative,In Situ Visualization of Metal‐Ion Dissolution and Transport Using 1H Magnetic Resonance Imaging 下载免费PDF全文
Dr. Joshua M. Bray Prof. Alison J. Davenport Prof. Karl S. Ryder Dr. Melanie M. Britton 《Angewandte Chemie (International ed. in English)》2016,55(32):9394-9397
Quantitative mapping of metal ions freely diffusing in solution is important across a diverse range of disciplines and is particularly significant for dissolution processes in batteries, metal corrosion, and electroplating/polishing of manufactured components. However, most current techniques are invasive, requiring sample extraction, insertion of an electrode, application of an electric potential or the inclusion of a molecular sensor. Thus, there is a need for techniques to visualize the distribution of metal ions non‐invasively, in situ, quantitatively, in three dimensions (3D) and in real time. Here we have used 1H magnetic resonance imaging (MRI) to make quantitative 3D maps showing evolution of the distribution of Cu2+ ions, not directly visible by MRI, during the electrodissolution of copper, with high sensitivity and spatial resolution. The images are sensitive to the speciation of copper, the depletion of dissolved O2 in the electrolyte and show the dissolution of Cu2+ ions is not uniform across the anode. 相似文献
982.
Dr. Pavel Zrazhevskiy Dr. Shreeram Akilesh Dr. Wanyi Tai Konstantin Queitsch Prof. Lawrence D. True Prof. Jonathan Fromm Prof. David Wu Prof. Peter Nelson Prof. John A. Stamatoyannopoulos Prof. Xiaohu Gao 《Angewandte Chemie (International ed. in English)》2016,55(31):8975-8978
Integration of imaging data across different molecular target types can provide in‐depth insight into cell physiology and pathology, but remains challenging owing to poor compatibility between target‐type‐specific labeling methods. We show that cross‐platform imaging analysis can be readily achieved through DNA encoding of molecular targets, which translates the molecular identity of various target types into a uniform in situ array of ssDNA tags for subsequent labeling with complementary imaging probes. The concept was demonstrated through multiplexed imaging of mRNAs and their corresponding proteins with multicolor quantum dots. The results reveal heterogeneity of cell transfection with siRNA and outline disparity in RNA interference (RNAi) kinetics at the level of both the mRNA and the encoded protein. 相似文献
983.
Inside Cover: Kinetics of Reactive Modules Adds Discriminative Dimensions for Selective Cell Imaging (ChemPhysChem 10/2016) 下载免费PDF全文
984.
Cover Picture: Absolute Configuration from Different Multifragmentation Pathways in Light‐Induced Coulomb Explosion Imaging (ChemPhysChem 16/2016) 下载免费PDF全文
Dr. Martin Pitzer Gregor Kastirke Dr. Maksim Kunitski Dr. Till Jahnke Dr. Tobias Bauer Christoph Goihl Florian Trinter Carl Schober Kevin Henrichs Jasper Becht Stefan Zeller Helena Gassert Markus Waitz Andreas Kuhlins Hendrik Sann Felix Sturm Florian Wiegandt Dr. Robert Wallauer Dr. Lothar Ph. H. Schmidt Allan S. Johnson Manuel Mazenauer Benjamin Spenger Sabrina Marquardt Sebastian Marquardt Prof. Dr. Horst Schmidt‐Böcking Prof. Dr. Jürgen Stohner Prof. Dr. Reinhard Dörner Dr. Markus Schöffler Prof. Dr. Robert Berger 《Chemphyschem》2016,17(16):2448-2448
985.
Spatially Heterogeneous Nature of Self‐Catalytic Reaction in Hetero‐Double Helix Formation of Helicene Oligomers 下载免费PDF全文
Dr. Yo Kushida Tsukasa Sawato Dr. Nozomi Saito Dr. Masanori Shigeno Dr. Hiroshi Satozono Prof. Dr. Masahiko Yamaguchi 《Chemphyschem》2016,17(20):3283-3288
A 1:1 mixture of pseudoenantiomeric aminomethylenehelicene oligomers, (P)‐tetramer and (M)‐pentamer, in fluorobenzene show a self‐catalytic phenomenon in the formation of hetero‐double helices from random coils. This study visualizes the spatially heterogeneous nature of the self‐catalytic reaction in dilute solution. UV/Vis imaging analysis of the mixture at 70 °C, containing random coils, exhibits a homogeneous bright area. When the solution is cooled from 70 to 30 °C and held at that temperature, dark domains of approximately 1 mm in size appear, which move approximately at a rate of 1 mm min?1. The dark domains indicate that weaker UV/Vis absorption results from the formation of hetero‐double helices, which is supported by circular dichroism (CD) imaging experiments. Then a homogeneous mixture is regenerated upon heating to 55 °C, as shown by CD imaging. Under self‐catalytic conditions, a homogeneous solution spontaneously changed to a heterogeneous solution in the process of hetero‐double‐helix formation. 相似文献
986.
Aggregation‐induced emission (AIE) luminogens show abnormal fluorescent behavior; they are non‐emissive in solution, but they become strongly emissive after aggregation. Sensing and imaging are the major applications of AIE luminogens. By properly manipulating the aggregation and deaggregation of AIE molecules, various bio‐/chemosensors have been developed. Moreover, AIE molecules with targeting groups have been devised for imaging of organelles and cancer cells. In this account, we report our recent work on the application of AIE luminogens for the construction of bio‐/chemosensors and imaging.
987.
Conjugated polyelectrolytes (CPEs) are macromolecules with highly delocalized π‐conjugated backbones and charged side chains, which are unique types of active materials, with wide applications in optoelectronics, sensing, imaging, and therapy. By attaching specific groups (e.g., recognition elements, magnetic resonance (MR) contrast agents, gene carriers, and drugs) to the side chain or backbone of CPEs, functionalized CPEs have been developed and used for specific biological applications. In this account, we summarize the recent progress of functionalized CPEs with respect to their synthesis and biomedical applications. Future perspectives are also discussed at the end. 相似文献
988.
989.
为了提高单臂压缩感知鬼成像的成像质量,减少成像系统本身和外部环境的干扰,提出了一种光强扩散函数分析方法.在单臂压缩感知鬼成像原理的基础上分析了成像过程,指出降低成像质量的主要因素是菲涅尔衍射和大气湍流.针对这两个因素,推导并分析了光强度扩散函数的公式,研究透镜的焦距与口径之比和照明光源的波长对鬼成像的影响.仿真结果表明:在单臂压缩感知鬼成像中,使用焦距与尺寸半径之比在2~5范围内的成像投影透镜可以消除衍射效应的影响;短波长光源适用于大气湍流较弱时的成像,长波长光源在大气湍流较强时对干扰有更好的耐受能力.该方法可以有效地提高成像质量并优化成像系统. 相似文献
990.
微通道板电压与增益对数理论上呈线性关系,为了更接近实际情况,根据已知的微通道板电压与增益对数的函数关系选取一组线性数据点,并在其基础上加一组随机数作为波动,得到新的电压与增益对数的关系,获得指数拟合公式,用于还原目标的距离信息.对成像准确度进行理论分析,结果表明成像准确度与系统信噪比和增益调制函数有关,且信噪比越高,距离准确度越高.测量了微通道板增益与电压的关系曲线,在不同电压条件下照射同一距离同一目标得到回波图像,利用不同电压下回波图像灰度值之比得到相对增益之比.分别在恒定增益和调制增益下,对距离成像系统60m的目标进行成像,利用增益曲线对所得的图像进行处理,准确还原出目标的距离信息,准确度达到分米量级. 相似文献