全文获取类型
收费全文 | 861篇 |
免费 | 73篇 |
国内免费 | 120篇 |
专业分类
化学 | 399篇 |
晶体学 | 2篇 |
力学 | 77篇 |
综合类 | 25篇 |
数学 | 418篇 |
物理学 | 133篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 16篇 |
2021年 | 31篇 |
2020年 | 25篇 |
2019年 | 36篇 |
2018年 | 18篇 |
2017年 | 27篇 |
2016年 | 38篇 |
2015年 | 28篇 |
2014年 | 49篇 |
2013年 | 54篇 |
2012年 | 35篇 |
2011年 | 35篇 |
2010年 | 39篇 |
2009年 | 46篇 |
2008年 | 40篇 |
2007年 | 60篇 |
2006年 | 36篇 |
2005年 | 48篇 |
2004年 | 34篇 |
2003年 | 52篇 |
2002年 | 42篇 |
2001年 | 31篇 |
2000年 | 31篇 |
1999年 | 31篇 |
1998年 | 26篇 |
1997年 | 24篇 |
1996年 | 17篇 |
1995年 | 23篇 |
1994年 | 15篇 |
1993年 | 13篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1054条查询结果,搜索用时 390 毫秒
971.
A new numerical manifold (NMM) method is derived on the basis of quartic uniform B-spline interpolation. The analysis shows that the new interpolation function possesses higher-order continuity and polynomial consistency compared with the conven- tional NMM. The stiffness matrix of the new element is well-conditioned. The proposed method is applied for the numerical example of thin plate bending. Based on the prin- ciple of minimum potential energy, the manifold matrices and equilibrium equation are deduced. Numerical results reveal that the NMM has high interpolation accuracy and rapid convergence for the global cover function and its higher-order partial derivatives. 相似文献
972.
光子晶体在分析化学中的应用 总被引:1,自引:0,他引:1
光子晶体是一新兴的光学材料,正越来越多地应用于分析化学领域,有可能成为新的研究热点。本文着重介绍与分析化学相关的光子晶体研究,特别关注其在色谱、毛细管与芯片电泳等分离分析方面的应用。 相似文献
973.
浙江省玄武岩台地地质灾害十分发育.从古沉积环境和微地貌分析入手,根据台地形成的古地理环境,划分了5种基本的台地类型,提出了玄武岩台地的微地貌划分方法,并探讨了玄武岩台地区地质灾害发育的特殊地貌条件.研究表明河谷型台地地质灾害最为发育,台地前缘斜坡亚区是地质灾害的多发微地貌区,地质灾害的规模与地形切割深度具有较好的正相关性,从而为基于地貌分区的地质灾害易发程度评价提供了可能. 相似文献
974.
The control and handling of fluids is central to many applications
of the lab-on-chip. This paper analyzes the basic theory of
manipulating different electrolytes and finds the two-dimensional
model. Coulomb force and dielectric force belonging to the body
force of different electrolytes in the microchannel were analyzed.
The force criterion at the interface was concluded, and testified by
the specific example. Three basic equations were analyzed and
applied to simulate the phenomenon. The force criterion was proved
to be correct based on the simulation results. 相似文献
975.
本文扼要回顾了20世纪八、九十年代当时高等工业学校物理课程教学指导委员会制定物理实验教学大纲的点滴往事,并对贯彻、实施当前“教指分委会”制定的大学物理实验教学基本要求,提出了一点建议. 相似文献
976.
数值摄动算法及其CFD格式 总被引:2,自引:1,他引:1
作者提出的数值摄动算法把流体动力学效应耦合进NS方程组和对流扩散(CD)方程离散的数学基本格式(MBS),特别是耦合进最简单的MBS即一阶迎风和二阶中心格式之中,由此构建成一系列新格式,称呼方便和强调耦合流体动力学起见,称它们为流体力学基本格式(FMBS)。构建FMBS的主要步骤是把MBS中的通量摄动重构为步长的幂级数,利用空间分裂和导出的高阶流体动力学关系式,把结点变量展开成Taylor级数,通过消除重构格式修正微分方程的截断误差诸项求出幂级数的待定系数,由此获得非线性FMBS。FMBS的公式是MBS与 (及 )之简单多项式的乘积, 和 分别是网格Reynolds数和网格CFL数。FMBS和MBS使用相同结点,简单性彼此相当,但FMBS精度高稳定范围大,例如FMBS包含了许多绝对稳定和绝对正型、高阶迎风和中心有限差分(FD)格式和有限体积(FV)格式,这些格式对网格Reynolds数的任意值均为不振荡格式。可见对不振荡CFD格式的构建,数值摄动算法提供了不同于调节数值耗散等常见的人为构建方法,而利用流体力学自身关系以及把迎风机制通过上、下游摄动重构引入中心MBS的解析构建方法,FMBS除了直接应用于流体计算外;对于通过调节数值耗散、色散和数值群速度特性重构高分辨率格式的研究,最简单FMBS提供了比最简单MBS更精确、但同样简单的基础和起步格式。FMBS用于计算不可压缩流,可压缩流,液滴萃取传质,微通道两相流等,均获得良好数值结果或与已有Benchmark解一致的数值结果。已有文献称数值摄动算法为新型高精度格式和高的算法和高的格式;本文FMBS比数值摄动格式的称呼可更好反映FMBS的物理内容。文中也讨论了值得进一步研究的一些课题,该法亦可用于其它一些数学物理方程(例如,简化Boltzmann方程、磁流体方程、KdV-Burgers方程等)MBS耦合物理动力学效应的重构。 相似文献
977.
近年来碱性离子液体的设计、合成及应用获得广泛关注. 离子液体碱性表征对于碱性离子液体的应用具有重要意义. 然而, 关于碱性离子液体碱性表征深入研究的报道还比较少. 我们合成了系列碱性离子液体, 利用电位滴定法测定了碱性离子液体的pKb值, 通过相应pKb值来表征离子液体的碱性强度, 最后考察了离子液体碱性与其结构之间的关联关系. 结果表明, 羧酸根碱性离子液体的碱性主要由阴离子决定, 但不同的阳离子也会影响到其碱性强度, 从而对离子液体的碱性进行微调; 对于胺基功能化的咪唑型离子液体, 由于离子液体结构中咪唑阳离子具有较强的吸电子诱导效应, 相对于对应的三乙胺其碱性显著下降. 相似文献
978.
Hyperspectral images contain both spectral and spatial image information and were investigated to characterize the freshness of fish. However, most studies of this application have focused on spectral signals rather than image features. The goal of this work was to investigate the ability of spectral and image textural variables for predicting the chemical and physical qualities of fish, respectively, and to optimize the variables for the specific quality determination. The chemical (total volatile basic nitrogen, TVB-N) and physical (texture profile analysis, TPA) properties were investigated. Partial least square (PLS) was applied to develop fish quality prediction models with the spectral and textural variables from the hyperspectral images. The results showed that the TVB-N content of fish fillets was accurately predicted using the spectra. Meanwhile, the TPA parameters were determined through the image textural features with high accuracy, which indicated image textural features were highly related with the TPA parameters. Moreover, spectral and textural features were also extracted from fish eyes and gills and were further used to predict the intact fish quality, taking advantage of the freshness sensitivity of the eyes and gills. The results illustrate that spectra from fish eyes and gills are a potential tool to predict the TVB-N content and TPA parameters for intact fish. 相似文献
979.
Laura S. Bailey Mlanie Alves Nicolas Galy Amanda L. Patrick Nicolas C. Polfer 《Journal of mass spectrometry : JMS》2019,54(5):449-458
We report on the rearrangement chemistry of model phosphorylated peptides during collision‐induced dissociation (CID), where intramolecular phosphate group transfers are observed from donor to acceptor residues. Such “scrambling” could result in inaccurate modification localization, potentially leading to misidentifications. Systematic studies presented herein provide mechanistic insights for the unusually high phosphate group rearrangements presented some time ago by Reid and coworkers (Proteomics 2013, 13 [6], 964‐973). It is postulated here that a basic residue like histidine can play a key role in mediating the phosphate group transfer by deprotonating the serine acceptor site. The proposed mechanism is consistent with the observation that fast collisional activation by collision‐cell CID and higher‐energy collisional dissociation (HCD) can shut down rearrangement chemistry. Additionally, the rearrangement chemistry is highly dependent on the charge state of the peptide, mirroring previous studies that less rearrangement is observed under mobile proton conditions. 相似文献
980.
Zhong Huang Yohei Ishida Tetsu Yonezawa 《Angewandte Chemie (International ed. in English)》2019,58(38):13411-13415
The synthesis of high‐purity and high‐yield Au25 clusters protected by the basic pyridyl ethanethiol (HSCH2CH2Py, 4‐PyET and 2‐PyET) is presented. Single‐crystal X‐ray diffraction of the [Au25(4‐PyET)18]??Na+ clusters has revealed a structure similar to that known for the phenyl ethanethiolate analogue, but with pyridyl‐N coordination to Na+, a more relaxed ligand shell, and a profoundly layered arrangement in the solid state. Because of the pendant Py moiety, the [Au25(PyET)18]? clusters are endowed with unique (de)protonation equilibria, which has been characterized in detail by UV/Vis absorption and 1H NMR spectroscopy. [Au25(PyET)18]? clusters showed an unexpectedly H+‐dependent solubility that is tunable in aqueous and organic solvents. The successful synthesis of the basic Py‐terminated thiolate‐protected Au25 clusters paves the way to realize a new family of metalloid clusters possessing basic properties. 相似文献