全文获取类型
收费全文 | 1584篇 |
免费 | 254篇 |
国内免费 | 210篇 |
专业分类
化学 | 1203篇 |
晶体学 | 17篇 |
力学 | 141篇 |
综合类 | 27篇 |
数学 | 304篇 |
物理学 | 356篇 |
出版年
2024年 | 2篇 |
2023年 | 14篇 |
2022年 | 35篇 |
2021年 | 36篇 |
2020年 | 61篇 |
2019年 | 103篇 |
2018年 | 83篇 |
2017年 | 85篇 |
2016年 | 97篇 |
2015年 | 101篇 |
2014年 | 128篇 |
2013年 | 141篇 |
2012年 | 113篇 |
2011年 | 129篇 |
2010年 | 104篇 |
2009年 | 79篇 |
2008年 | 121篇 |
2007年 | 91篇 |
2006年 | 76篇 |
2005年 | 64篇 |
2004年 | 52篇 |
2003年 | 48篇 |
2002年 | 67篇 |
2001年 | 54篇 |
2000年 | 47篇 |
1999年 | 34篇 |
1998年 | 25篇 |
1997年 | 10篇 |
1996年 | 9篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1977年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有2048条查询结果,搜索用时 15 毫秒
991.
Bipartite network based recommendations have attracted extensive attentions in recent years. Differing from traditional object-oriented recommendations, the recommendation in a Microblog network has two crucial differences. One is high authority users or one’s special friends usually play a very active role in tweet-oriented recommendation. The other is that the object in a Microblog network corresponds to a set of tweets on same topic instead of an actual and single entity, e.g. goods or movies in traditional networks. Thus repeat recommendations of the tweets in one’s collected topics are indispensable. Therefore, this paper improves network based inference (NBI) algorithm by original link matrix and link weight on resource allocation processes. This paper finally proposes the Microblog recommendation model based on the factors of improved network based inference and user influence model. Adjusting the weights of these two factors could generate the best recommendation results in algorithm accuracy and recommendation personalization. 相似文献
992.
Alaa Alhadad Michael Åkesson Leena Lehti Peter Leander Gunnar Sterner Per Åkeson Johan Wassélius 《Magnetic resonance imaging》2014
Purpose
The purpose of this retrospective study was to systematically search for acute adverse reactions and long-term complications in all patients that had been administered gadofosveset at our hospital.Materials and methods
We identified 67 gadofosveset administrations during 2006–2009 in 62 patients from 8 to 84 years of age. Radiological information system (RIS) and clinical patient records were analyzed for suspected acute adverse reactions and long-term complications including nephrogenic systemic fibrosis (NSF).The gadofosveset doses ranged between 0.024 and 0.060 mmol/kg bodyweight with a mean dose of 0.031-mmol/kg bodyweight. Follow-up time of the patients ranged from less than 1 year up to 4 years with a mean follow-up time of 2.1 years.Results
No acute adverse events or technical failures related to the contrast medium were recorded in the RIS. No dermatological and nephrological diseases related to the gadofosveset administration were found in the clinical patient records. Four patients died during follow-up without any apparent relation to the gadofosveset exposure.Conclusions
Based on our clinical material we conclude that gadofosveset is safe for a mixed patient population with no acute adverse events or any indications of long-term complications during the follow-up time up to four years. 相似文献993.
994.
Start‐up demonstration tests were first discussed in the quality/reliability literature about three decades ago. Since then, many variations of these tests have been introduced, and the corresponding distributional characteristics and inferential methods have also been studied. All these developments, based on independent and identically distributed binary trials, have been further generalized to some other forms of trials such as Markov‐dependent trials, exchangeable trials and multistate trials. In this paper, we provide a comprehensive review of all these results and highlight some unifications of the results. We also describe a general estimation method and then present several numerical examples to illustrate some of the models and methods described here. Finally, a number of open issues in this area of research are pointed out. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
995.
《Journal of computational science》2014,5(4):653-663
Information systems security defines three properties of information: confidentiality, integrity, and availability. These characteristics remain major concerns throughout the commercial and military industry. Ordinary users have taken these features as basis for their businesses. Furthermore, users may find it necessary to combine policies in order to protect their information in a suitable way. However, inconsistencies may arise as a result of implementing multiple secrecy and privacy models; and therefore, render these services unsecure. In this paper, we propose an approach to detect and report inconsistencies when choosing mixed models for integrity and security. It is based on specifying the policies in first order logic and applying formal analysis. We demonstrate the feasibility of our proposition by applying it to the Clark Wilson and role based access control models. We use the Alloy language and analyzer to formalize the mixed model and check for any inconsistencies. 相似文献
996.
A new graph‐based move class for global optimization of cluster structures is presented. Its performance and efficiency is analyzed for water clusters (H2O)n, n = 24, 61. This analysis indicates superior basin exploitation capabilities of the new move class for large clusters, compared to traditional moves. © 2014 Wiley Periodicals, Inc. 相似文献
997.
The synthesis of trifunctional allylsilane (2b) is described. 相似文献
998.
Frank Muldoon 《国际流体数值方法杂志》2013,72(1):90-118
The problem of controlling the hydrothermal waves in a thermocapillary flow is addressed using a gradient‐based control strategy. The state equations are the two‐dimensional unsteady incompressible Navier–Stokes and energy equations under the Boussinesq approximation. The modeled problem is the ‘open boat’ process of crystal growth, the flow which is driven by Marangoni and buoyancy effects. The control is a spatially and temporally varying heat flux boundary condition at the free surface. The control that minimizes the hydrothermal waves is found using a conjugate gradient method, where the gradient of the objective function with respect to the control variables is obtained from solving a set of adjoint equations. The effectiveness of choices of the parameters governing the control algorithm is examined. Almost complete suppression of the hydrothermal waves is obtained for certain choices of the parameters governing the control algorithm. The numerical issues involved with finding the control using the optimizer are discussed, and the features of the resulting control are analyzed with the goal of understanding how it affects the flow.Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
999.
Encarnación Borrego Dolores Sicilia Soledad Rubio Dolores Pérez-Bendito 《International journal of environmental analytical chemistry》2013,93(1-2):181-200
Abstract The determination of dialkyldimethylammonium surfactants (DDAS) based on the measurement of the critical micelle concentration (CMC) of mixed sodium dodecylsulphate (SDS)-DDAS aggregates in a basic medium ([NaOH]=4.8 × 10?3 M) is proposed. The dye Coomassie Brilliant Blue G (CBBG) was used as a photometric probe for the rapid determination of CMCs. Formation of CBBG-DDAS and DDAS-SDS premicellar aggregates of well-defined stoichiometrics at cationic and anionic surfactant concentrations far below their CMCs is demonstrated. Increased SDS concentration in the titration medium results in the formation of DDAS-SDS mixed micelles. The strong interaction between the opposite charged head group of DDAS and SDS permits these cationic surfactants to be determined at the ng ml?1 level with a nearly uniform response for all the DDAS tested (12–18 alkyl carbons). The relative standard deviation for 1.10 μg ml?1 ditetradecyldimethylammonium bromide (DTDAB) was 1.5%. The mixed-micelle based methodology was applied to the determination of DDAS in softeners and aqueous environmental samples (river water and laundry effluents) with average recoveries ranged from 87.1 to 100.6 and from 96.3 to 104.0, respectively. 相似文献
1000.
Determination of Silver‐Modified Titanium Phosphate Nanoparticles by Voltammetric and Electrocatalytic Methods 下载免费PDF全文
Daniel Martín‐Yerga Javier Carrasco‐Rodríguez María Begoña González‐García Francisco Javier García Alonso Agustín Costa‐García 《Electroanalysis》2014,26(12):2574-2579
The electrochemical determination of silver‐modified titanium phosphate nanoparticles (Ag‐TiPNPs) was performed using two electrochemical features of this novel kind of nanoparticles. First, a determination using the voltammetric activity of the silver from the Ag‐TiPNPs was carried out. Secondly, the electrocatalytic effect of Ag‐TiPNPs was shown for the first time to the hydrogen evolution reaction (HER) and the determination of these nanoparticles was performed by chronoamperometry using this electrocatalysis. Moreover, it was verified that the catalytic effect was due to the electroreduced silver since the unmodified titanium phosphate nanoparticles (TiPNPs) did not exhibit this effect. Detection limits as low as 0.1 and 0.75 ng µL?1 of Ag‐TiPNPs were obtained with the voltammetric and chronoamperometric methods, respectively. 8‐channel screen‐printed electrochemical arrays (8xSPCEs) were employed as transducers to carry out these electrochemical studies, due to its low cost and time saving. 相似文献