Activation of Oxygen on Gold and Silver Nanoparticles Assisted by Surface Plasmon Resonances

Surface plasmon resonances (SPRs) have been found to promote chemical reactions. In most oxidative chemical reactions oxygen molecules participate and understanding of the activation mechanism of oxygen molecules is highly important. For this purpose, we applied surface‐enhanced Raman spectroscopy (SERS) to find out the mechanism of SPR‐assisted activation of oxygen, by using p‐aminothiophenol (PATP), which undergoes a SPR‐assisted selective oxidation, as a probe molecule. In this way, SPR has the dual function of activating the chemical reaction and enhancing the Raman signal of surface species. Both experiments and DFT calculations reveal that oxygen molecules were activated by accepting an electron from a metal nanoparticle under the excitation of SPR to form a strongly adsorbed oxygen molecule anion. The anion was then transformed to Au or Ag oxides or hydroxides on the surface to oxidize the surface species, which was also supported by the heating effect of the SPR. This work points to a promising new era of SPR‐assisted catalytic reactions.     

用代数模型研究非刚性HCP分子的振动谱

提出一种研究非刚性HCP分子的高激发非线性振动的代数哈米顿量,它在极限条件下退化为传统的用谐振子算子表示的模型,拟合观测的实验数据表明,代数模型比传统模型较好地描述了这些数据．     

Surface-enhanced Raman scattering: realization of localized surface plasmon resonance using unique substrates and methods

Surface-enhanced Raman scattering (SERS) enhancement and the reproducibility of the SERS signal strongly reflect the quality and nature of the SERS substrates because of diverse localized surface plasmon resonance (LSPR) excitations excited at interstitials or sharp edges. LSPR excitations are the most important ingredients for achieving huge enhancements in the SERS process. In this report, we introduce several gold and silver nanoparticle-based SERS-active substrates developed solely by us and use these substrates to investigate the influence of LSPR excitations on SERS. SERS-active gold substrates were fabricated by immobilizing colloidal gold nanoparticles on glass slides without using any surfactants or electrolytes, whereas most of the SERS-active substrates that use colloidal gold/silver nanoparticles are not free of surfactant. Isolated aggregates, chain-like elongated aggregates and two-dimensional (2D) nanostructures were found to consist mostly of monolayers rather than agglomerations. With reference to correlated LSPR and SERS, combined experiments were carried out on a single platform at the same spatial position. The isolated aggregates mostly show a broadened and shifted SPR peak, whereas a weak blue-shifted peak is observed near 430 nm in addition to broadened peaks centered at 635 and 720 nm in the red spectral region in the chain-like elongated aggregates. In the case of 2D nanostructures, several SPR peaks are observed in diverse frequency regions. The characteristics of LSPR and SERS for the same gold nanoaggregates lead to a good correlation between SPR and SERS images. The elongated gold nanostructures show a higher enhancement of the Raman signal than the the isolated and 2D samples. In the case of SERS-active silver substrates for protein detection, a new approach has been adopted, in contrast to the conventional fabrication method. Colloidal silver nanoparticles are immobilized on the protein functionalized glass slides, and further SERS measurements are carried out based on LSPR excitations. A new strategy for the detection of biomolecules, particularly glutathione, under aqueous conditions is proposed. Finally, supramolecular J-aggregates of ionic dyes incorporated with silver colloidal aggregates are characterized by SERS measurements and correlated to finite-difference time-domain analysis with reference to LSPR excitations. Figure SPR and SERS images for isolated, elongated and two-dimensional gold nanostructures     

The Inverse Resonance Problem for Hermite Operators

In this paper the inverse resonance problem for the Hermite operator is investigated. The Hermite operator with the creation operator , the annihilation operator , and a finitely supported multiplication operator b, is an unbounded operator on ℓ ²(ℕ₀) having finitely many eigenvalues and infinitely many resonances (except for b=0, when there are no eigenvalues or resonances). It is shown that knowing the location of eigenvalues and resonances determines the potential b uniquely.      

Analysis of the Triply Heavy Baryon States with QCD Sum Rules

In this article, we study the (1/2) ± and (3/2)± triply heavy baryon states in a systematic way by subtracting the contributions from the corresponding (1/2)■ and (3/2)■ triply heavy baryon states with the QCD sum rules, and make reasonable predictions for their masses.     

Effects of intrasubband coupling on the scattering phases and density of states in a quantum wire

The properties of scattering phases and density of states in a quantum wire with an attractive scatterer are analyzed. We consider two bound states which couple to a scattering channel and give rise to two Fano resonances. It is shown that varying the parameters of the scatterer (such as its strength and position) produces significantly different effects on the phase behavior and density of states, depending on the subband they occur. These effects stem mainly from the difference between the coupling matrix elements of the two resonant levels with the propagating channel mode.     

Experimental Study of a Quad-Band Metamaterial-Based Plasmonic Perfect Absorber as a Biosensor

We present a metamaterial-based perfect absorber (PA) that strongly supports four resonances covering a wide spectral range from 1.8 µm to 10 µm of the electromagnetic spectrum. The designed perfect absorber has metal–dielectric–metal layers where a MgF₂ spacer is sandwiched between an optically thick gold film and patterned gold nanoantennas. The spectral tuning of PA is achieved by calibrating the geometrical parameters numerically and experimentally. The manufactured quad-band plasmonic PA absorbs light close to the unity. Moreover, the biosensing capacity of the PA is tested using a 14 kDa S100A9 antibody, which is a clinically relevant biomarker for brain metastatic cancer cells. We utilize a UV-based photochemical immobilization technique for patterning of the antibody monolayer on a gold surface. Our results reveal that the presented PA is eligible for ultrasensitive detection of such small biomarkers in a point-of-care device to potentially personalize radiotherapy for patients with brain metastases.     

Magnetic-Electric Metamirror and Polarizing Beam Splitter Composed of Anisotropic Nanoparticles

The emergence of new materials and fabrication techniques provides progress in the development of advanced photonic and communication devices. Transition metal dichalcogenides (e.g., molybdenum disulfide, MoS₂) are novel materials possessing unique physical and chemical properties promising for optical applications. In this paper, a metasurface composed of particles made of bulk MoS₂ is proposed and numerically studied considering its operation in the near-infrared range. In the bulk configuration, MoS₂ has a layered structure being a uniaxial anisotropic crystal demonstrating an optical birefringence property. It is supposed that the large-scale and uniform MoS₂ layers are synthesized in a vertical-standing morphology, and then they are patterned into a regular 2D array of disks to form a metasurface. The natural anisotropy of MoS₂ is utilized to realize the splitting of electric and magnetic dipole modes of the disks while optimizing their geometric parameters to bring the desired modes into overlap. At the corresponding resonant frequencies, the metasurface behaves as either an electric or a magnetic mirror, depending on the polarization of incident light. Based on the extraordinary reflection characteristics of the proposed metasurface, it can be considered an alternative to traditional mirrors and optical splitters when designing compact and highly efficient metadevices, which provide polarization and phase manipulation of electromagnetic waves on a subwavelength scale.     

Time asymmetric quantum theory – II. Relativistic resonances from S‐matrix poles

Relativistic resonances and decaying states are described by representations of Poincaré transformations, similar to Wigner's definition of stable particles. To associate decaying state vectors to resonance poles of the S‐matrix, the conventional Hilbert space assumption (or asymptotic completeness) is replaced by a new hypothesis that associates different dense Hardy subspaces to the in‐ and out‐scattering states. Then one can separate the scattering amplitude into a background amplitude and one or several “relativistic Breit‐Wigner” amplitudes, which represent the resonances per se. These Breit‐Wigner amplitudes have a precisely defined lineshape and are associated to exponentially decaying Gamow vectors which furnish the irreducible representation spaces of causal Poincaré transformations into the forward light cone.     

Floquet Transmission in Weyl/Multi-Weyl and Nodal-Line Semimetals through a Time-Periodic Potential Well

A quantum pumping protocol through which the quasiparticles of Weyl/multi-Weyl and nodal-line semimetals are subjected to a time-periodic rectangular potential well is considered. The presence of an oscillating potential of frequency ω creates equispaced Floquet side-bands with spacing $\hslash \omega$. As a result, a Fano resonance is observed when the difference in the Fermi energy (i.e., the energy of the incident quasiparticle), and the energy of one of the (quasi)bound state levels of the well, coincides with the energy of an integer number of photons (each carrying energy quantum $\hslash \omega$). Using the Floquet theory and the scattering matrix approach in the zero-temperature non-adiabatic pumping limit, characteristic Fano resonance patterns are found in the transmission coefficients. The inflection points in the pumped shot noise spectra also serve as a proxy for the corresponding Fano resonances. Therefore, the pumped shot noise is also numerically evaluated. Finally, the existence of the Fano resonance points is correlated to the (quasi)bound states of the well, by explicitly calculating the bound states of the static well (which are a subset of the bound states of the driven system). Since semimetals with anisotropic dispersions are considered, all the features observed depend on the orientation of the potential well.