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81.
B. Canals D.A. Garanin 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(4):439-447
Thermodynamic quantities and correlation functions (CFs) of the classical antiferromagnet on the checkerboard lattice are
studied for the exactly solvable infinite-component spin-vector model, D↦∞. In contrast to conventional two-dimensional magnets with continuous symmetry showing extended short-range order at distances
smaller than the correlation length, r
ξ
c∝ exp(T
*/T), correlations in the checkerboard-lattice model decay already at the scale of the lattice spacing due to the strong degeneracy
of the ground state characterized by a macroscopic number of strongly fluctuating local degrees of freedom. At low temperatures,
spin CFs decay as <
>∝ 1/r
2 in the range a
0≪r≪ξ
c∝T
-1/2, where a0 is the lattice spacing. Analytical results for the principal thermodynamic quantities in our model are very similar with
MC simulations, exact and analytical results for the classical Heisenberg model (D = 3) on the pyrochlore lattice. This shows that the ground state of the infinite-component spin vector model on the checkerboard
lattice is a classical spin liquid.
Received 16 November 2001 and Received in final form 12 February 2002 相似文献
82.
E. S. F. Neto N. O. Dantas S. W. da Silva P. C. Morais M. A. Pereira da Silva 《Journal of Raman spectroscopy : JRS》2010,41(10):1302-1305
This work gives the evidence of the lattice contraction in CdSe nanocrystals (NCs) grown in a glass matrix. The CdSe NCs were investigated by atomic force microscopy (AFM), optical absorption (OA), and Raman spectroscopy. The average size of CdSe NCs can be estimated by AFM images. Using the OA spectra and the effective‐mass approximation, it was also possible to estimate the average sizes of CdSe NCs, which agree very well with the AFM data. These results showed that the CdSe NCs grow with increasing time of heat treatment. The blue shift of the longitudinal optical (LO) modes and surface optical (SO) phonon modes with an increase in the average radius of the NCs, shown in the Raman spectra, was explained by the lattice contraction in CdSe NCs caused by thermodynamic interactions at the interface with the host glass matrix. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
83.
ABSTRACT In this paper, the radiation shielding parameters such as linear attenuation coefficients (LAC, µ), mass attenuation coefficients (MAC, µ/ρ), effective atomic numbers (Zeff), effective electron densities (Neff), half value of layers (HVL), mean free paths (MFP) and buildup factors (exposure (EBF) and energy absorption (EABF)) were investigated for cream (M1), pink (M2), white (M3), maroon (M4) and green (M5) marbles. Attenuation coefficients were measured in the energy region 31.18–661.66 keV photon energies. The values of Zeff and Neff were then calculated using these coefficients with logarithmic interpolation method, and HVLs and MFPs were calculated using the values of LAC of marble samples at the same photon energies. The experimental results were compared with the theoretical values obtained from WinXCom program, and good agreements were observed between the experimental and theoretical results. HVLs and MFPs of all marble samples were compared with those of some concretes, glasses and commercial radiation shielding glasses (SCHOTT Co.). The studied marbles were better radiation shielding materials than standard shielding concretes due to lower HVL and MFP values lower than the ordinary concrete. Finally, EBFs and EABFs of the marbles were calculated in the energy region 0.015–1?MeV up to penetration depths of 40 mfps by Geometric Progression method (G-P), and the results were discussed in terms of photon energies and chemical compositions of the marbles. 相似文献
84.
《Surface Science Reports》2020,75(4):100509
It was a long-cherished dream for chemists to take a direct look at chemical bonding, a fundamental component of chemistry. This dream was finally accomplished by the state-of-the-art noncontact atomic force microscopy (NC-AFM) equipped with qPlus force sensors and carbon monoxide (CO) functionalized tips. The resolved interconnectivity between atoms and molecules in NC-AFM frequency shift images is interpreted as chemical bonding, providing essential knowledge of the bond length, bond angle and even bond order. The featured contrast of different chemical bonds can serve as fingerprints for further interpretation of chemical structures toward unknown species synthesized on surfaces. This breakthrough enriches characterization tools for surface science and brings our understanding of on-surface reactions to a new level. Beyond bond imaging, the application of NC-AFM has been extended to quantifying interatomic interactions, identifying three-dimensional nanostructures, manipulating molecules and reactions, as well as determining molecular electronic characteristics. Moreover, some recent efforts address the improvement of the usability and versatility of the bond-resolved NC-AFM technique, including high-resolution molecular investigation on bulk insulators, application-specific tip modification, stable bond imaging above liquid helium temperature and autonomous experimentation implemented by artificial intelligence. 相似文献
85.
Li JiGuang Dong ChenZhong Yu YouJun Ding XiaoBin S. Fritzsche B. Fricke 《中国科学G辑(英文版)》2007,50(6):707-715
A super heavy element Uub (Z = 112) has been studied theoretically in conjunction with rela-tivistic effects and the effects of electron correlations. The atomic structure and the oscillator strengths of low-lying levels have been calculated, and the ground states have also been determined for the singly and doubly charged ions. The influence of relativity and correlation effects to the atomic properties of such a super heavy element has been investigated in detail. The results have been compared with the properties of an element Hg. Two energy levels at wave numbers 64470 and 94392 are suggested to be of good candidates for experimental observations. 相似文献
86.
采用调Q Nd:YAG脉冲激光诱导铝合金E414d,研究了等离子体的谱线强度、电子温度和电子密度。建立Al (Ⅰ) 256.80 nm、Al (Ⅰ) 308.21 nm和Al (Ⅰ) 396.15 nm的波耳兹曼平面,实验发现距靶面高度1.5 mm处等离子体的电子温度最高。罗仑兹函数拟合Mg (Ⅰ) 285.21 nm得到等离子体的电子密度是1.9×1018 cm-3,远大于局域热力学平衡所需的电子密度值9.8×1015 cm-3,证明实验得到的等离子体满足局部热力学平衡。 相似文献
87.
In this contribution, the electronic and linear and nonlinear optical properties of pyramid-shaped GaAs quantum dots (QDs) coupled to wetting layer (WL) in an Al0.3Ga0.7As matrix have been investigated. This nanostructure is relaxed from strain effects due to very small lattice-mismatching. Three transitions of P-to-S, WL-to-P, and WL-to-S were considered and the corresponding transition dipole moments, oscillator strengths, and linear and nonlinear optical properties regarding to these transitions were investigated as a function of the QD height. The results showed that for P-to-S transition, which is a purely in-plane-polarized transition, the dependence of electronic and optical properties on the size is moderate and can be neglected. But for WL-to-P and WL-to-S transitions, which are in-plane- and z-polarized transitions, respectively, the electronic as well as optical properties are strongly size-dependent. Furthermore, a competition between WL-to-S and WL-to-P transitions was observed when the QD size changed. 相似文献
88.
A double-wall cubic metal nanotube consists of the ferromagnetic spin-1 inner shell and spin-3/2 surface shell. It is of the ferrimagnetic exchange coupling between two shells. Considering the single-ion anisotropy and transverse field exist together, the magnetization, the initial susceptibility, the internal energy and the specific heat have been investigated by using the effective-field theory with correlations. Some interesting phenomena have been found in the thermal variations of the system. Magnetization appears two or three compensation points in certain parameters. It is an unconventional ferrimagnetic behavior in the nanotube. The shapes of total magnetization and the initial susceptibility are great influenced by the surface exchange coupling, surface single-ion anisotropy and surface transverse field. Some results of nanotube may have potential applications in different research fields, such as electronics, optics, mechanics, and even biomedicine and molecular devices. 相似文献
89.
石墨探针技术/石墨炉原子吸收光谱测定人发中痕量锰 总被引:6,自引:0,他引:6
本文采用探针原子化技术对痕量锰进行了一系列条件试验,试验结果表明,石墨探针炉法具有灵敏度高,检出限低,重现性好,简便快速等特点,应用于人发中痕量锰的测定,结果满意。 相似文献
90.
采用坩埚扭摆振动法测量Mg-9Al熔体的运动黏度,得到890—1190 K温区内高精度的黏度-温度关系曲线ν(T),发现升温过程中黏度随温度升高发生异常变化,当温度升高至1000—1075 K时,黏度由快速增大转变为逐渐减小,即发生转折变化;在随后的降温和第二次升温过程中,黏度随温度变化呈指数规律单调递增(减),符合Arrhenius方程式.在实验研究基础上,采用剩余键结构模型和"平均原子集团"演变行为的计算模型讨论Mg-9Al熔体的黏度与微观结构之间的相关性,结果表明:类关键词:
合金熔体
结构与黏度相关性
剩余键结构
平均原子集团模型 相似文献