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101.
《中国化学》2017,35(12):1889-1893
Three new chromone derivatives, phomochromenones A‐C ( 1–3 ), and one known chaetocyclinone B ( 4 ) were obtained from the cultures of Phomopsis sp. HNY29‐2B isolated from the mangrove Acanthus ilicifolius Linn., which was collected from the South China Sea. Their structures were determined by the analysis of 1D NMR and 2D NMR as well as mass spectroscopic data. The absolute configurations of 1 and 2 were assigned by quantum chemical calculations of the electronic circular dichroism (ECD ) spectra. Compound 3 is the third example of alkaloids possessing the unique chromeno [3,2‐c ] pyridine nucleus. In the bioactivity assay, compound 4 showed cytotoxicity against human prostate cancer cell lines (PC ‐3 and DU145 cells) with the IC50 values of 8.13 and 3.59 µmol/L, respectively. 相似文献
102.
Highly Axial Magnetic Anisotropy in a N3O5 Dysprosium(III) Coordination Environment Generated by a Merocyanine Ligand
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Pramila Selvanathan Gang Huang Thierry Guizouarn Dr. Thierry Roisnel Dr. Guglielmo Fernandez‐Garcia Dr. Federico Totti Dr. Boris Le Guennic Dr. Guillaume Calvez Dr. Kévin Bernot Dr. Lucie Norel Prof. Stéphane Rigaut 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(43):15222-15226
A spiropyran‐based switchable ligand isomerizes upon reaction with lanthanide(III) precursors to generate complexes with an unusual N3O5 coordination sphere. The air‐stable dysprosium(III) complex shows a hysteresis loop at 2 K and a very strong axial magnetic anisotropy generated by the merocyanine phenolate donor. 相似文献
103.
Inside Back Cover: Weak Ligand‐Field Effect from Ancillary Ligands on Enhancing Single‐Ion Magnet Performance (Chem. Eur. J. 36/2016)
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104.
Magnetic domain structures of precipitation-hardened SmCo 2:17-type sintered magnets: Heat treatment effect
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The typical magnetic domains of Sm(CObalFe0.25Cuo.07Zr0.02)7.4 magnets quenched through various heattreatment steps have been revealed by using magnetic force microscopy (MFM). For the specimens in which the nominal c-axis is perpendicular to the imaging plane, the domain configurations change from plate-like for the as-sintered magnet to corrugation and spike-like for the homogenized one, and then to a coarse and finally to a finer domain structure when isothermally aged at 830℃ and then annealed at 400℃. However, only plate-like domains can be detected on the surfaces with the nominal c-axis parallel to the imaging plane. The finer domain (so-called interaction domain) is a characteristic magnetic domain pattern of the SmCo 2:IT-type magnets with high coercivities. Domain walls in a zigzag shape are revealed by means of MFM in final bulk SraCo 2:17-type sintered magnets. 相似文献
105.
The design of the China Spallation Neutron Source (CSNS) low-energy beam transport (LEBT) line, which locates between the ion source and the radio-frequency quadrupole (RFQ), has been completed with the TRACE3D code. The design aims at perfect matching, primary chopping, a small emittance growth and sufficient space for beam diagnostics. The line consists of three solenoids, three vacuum chambers, two steering magnets and a pre-chopper. The total length of LEBT is about 1.74 m. This LEBT is designed to transfer 20 mA of H-pulsed beam from the ion source to the RFQ. An induction cavity is adopted as the pre-chopper.The electrostatic octupole steerer is discussed as a candidate. A four-quadrant aperture for beam scraping and beam position monitoring is designed. 相似文献
106.
M. Sasaki V. Dupuis J.-P. Bouchaud E. Vincent 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,29(3):469-479
We study the deviations from perfect memory in negative temperature cycle spin glass experiments. It is known that the a.c.
susceptibility after the temperature is raised back to its initial value is superimposed to the reference isothermal curve
for large enough temperature jumps ΔT (perfect memory). For smaller ΔT, the deviation from this perfect memory has a striking non monotonous behavior: the `memory anomaly' is negative for small ΔT's, becomes positive for intermediate ΔT's, before vanishing for still larger ΔT's. We show that this interesting behavior can be reproduced by simple Random Energy trap models. We discuss an alternative
interpretation in terms of droplets and temperature chaos.
Received 23 May 2002 Published online 14 October 2002
RID="a"
ID="a"e-mail: sasaki@ipno.in2p3.fr 相似文献
107.
C. Djurberg K. Jonason P. Nordblad 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,10(1):15-21
Experiments on the temperature and time dependence of the response function and the field cooled magnetisation of a Cu(Mn)
spin glass at temperatures below the zero field spin glass temperature are used to explore the non-equilibrium nature of the
underlying spin configuration. The results imply that a certain spin configuration is imprinted on the system as the temperature
is decreased at a constant cooling rate. The cooling rate governs the magnitude of the FC magnetisation ((H,T)). Any intermittent halt at a constant temperature, , imprints an extended spin configuration, a process that is reflected e.g. in a downward relaxation of . On continued cooling at the same rate, the magnitude of (T) remains at a lower level than that of a continuous cooling curve. These results are put into the context of the corresponding
behaviour of the response function as observed in measurements of the relaxation of the zero field cooled magnetisation.
Received 27 October 1998 and Received in final form 30 November 1998 相似文献
108.
109.
110.
In this review article, we discuss a class of biosensors that exploit the change in the colorimetric properties of noble metal nanoparticles in response to biomolecular binding at their surface. Several sensor fabrication techniques as well as sensor configurations are discussed with an emphasis on their strengths and limitations. We conclude by presenting the future prospects and challenges for the successful transition of this technology from the laboratory to a commercial product. 相似文献