全文获取类型
收费全文 | 7957篇 |
免费 | 1060篇 |
国内免费 | 630篇 |
专业分类
化学 | 2927篇 |
晶体学 | 61篇 |
力学 | 2464篇 |
综合类 | 175篇 |
数学 | 1715篇 |
物理学 | 2305篇 |
出版年
2024年 | 30篇 |
2023年 | 86篇 |
2022年 | 253篇 |
2021年 | 227篇 |
2020年 | 303篇 |
2019年 | 239篇 |
2018年 | 263篇 |
2017年 | 299篇 |
2016年 | 358篇 |
2015年 | 289篇 |
2014年 | 295篇 |
2013年 | 679篇 |
2012年 | 421篇 |
2011年 | 403篇 |
2010年 | 338篇 |
2009年 | 361篇 |
2008年 | 364篇 |
2007年 | 378篇 |
2006年 | 434篇 |
2005年 | 375篇 |
2004年 | 360篇 |
2003年 | 359篇 |
2002年 | 280篇 |
2001年 | 257篇 |
2000年 | 273篇 |
1999年 | 236篇 |
1998年 | 196篇 |
1997年 | 168篇 |
1996年 | 174篇 |
1995年 | 150篇 |
1994年 | 117篇 |
1993年 | 106篇 |
1992年 | 96篇 |
1991年 | 68篇 |
1990年 | 75篇 |
1989年 | 43篇 |
1988年 | 56篇 |
1987年 | 37篇 |
1986年 | 23篇 |
1985年 | 38篇 |
1984年 | 28篇 |
1983年 | 10篇 |
1982年 | 31篇 |
1981年 | 17篇 |
1980年 | 5篇 |
1978年 | 10篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1957年 | 13篇 |
排序方式: 共有9647条查询结果,搜索用时 0 毫秒
111.
Xiangchuan Meng Zhi Xing Xiaotian Hu Zengqi Huang Ting Hu Licheng Tan Fengyu Li Yiwang Chen 《Angewandte Chemie (International ed. in English)》2020,59(38):16602-16608
Perovskite solar cells (PSCs) are a promising photovoltaic technology for stretchable applications because of their flexible, light‐weight, and low‐cost characteristics. However, the fragility of crystals and poor crystallinity of perovskite on stretchable substrates results in performance loss. In fact, grain boundary defects are the “Achilles’ heel” of optoelectronic and mechanical stability. We incorporate a self‐healing polyurethane (s‐PU) with dynamic oxime–carbamate bonds as a scaffold into the perovskite films, which simultaneously enhances crystallinity and passivates the grain boundary of the perovskite films. The stretchable PSCs with s‐PU deliver a stabilized efficiency of 19.15 % with negligible hysteresis, which is comparable to the performance on rigid substrates. The PSCs can maintain over 90 % of their initial efficiency after 3000 hours in air because of their self‐encapsulating structure. Importantly, the self‐healing function of the s‐PU scaffold was verified in situ. The s‐PU can release mechanical stress and repair cracks at the grain boundary on multiple levels. The devices recover 88 % of their original efficiency after 1000 cycles at 20 % stretch. We believe that this ingenious growth strategy for crystalline semiconductors will facilitate development of flexible and stretchable electronics. 相似文献
112.
Morphology development during isothermal annealing of poly(ether-ester) multiblock copolymers with hard segments containing poly(tetramethylene isophthalate) is examined by differential scanning calorimetry (DSC) and small-angle x-ray scattering (SAXS). Reorganization in the solid-state occurs by melting and recrystallization. At temperatures close to the melting point, glass transition measurements after quenching from the annealing temperature suggest microphase mixing follows melting. The temperature of maximum recrystallization rate is elevated relative to that of isothermal crystallization. SAXS experiments suggest that a memory of the initial morphology is retained during annealing. Aspects of the DSC scans related to crystallization on cooling and rescanning also suggest that the morphology at the annealing temperature plays a governing role in the determination of the degree of order possible on cooling. The crystalline regions stable at the annealing temperature are envisioned to function in a dual role, acting as nucleation centers for recrystallization and as a form of “constraint” to ordering on cooling. © 1996 John Wiley & Sons, Inc. 相似文献
113.
金属的冲击温度及熔化温度测量对构建其完全状态方程具有重要意义。简要综述了用于金属冲击温度及熔化温度辐射法测量的一维热传导理想界面模型和非理想界面模型,并着重对模型中明示或隐含的关键假定的合理性、影响金属冲击温度与熔化温度结果的主要因素进行了分析、讨论,以期对实验数据有一个合理的评估。还讨论了求解理想和非理想界面模型一维热传导方程界面温度时所隐含的冲击压缩下热导率不随温度而变、冲击压缩下金属样品/窗口界面辐射的灰体假定,以及窗口材料的透明性、非理想界面模型中表观界面温度的修正、动载条件下金属高压熔化温度的测量、界面的非Flourier热传导等问题。分析结果表明,目前采用辐射法测量大致可以得到冲击温度,在发生熔化的情况下可获得熔化温度,但离精密测量的要求还有较大差距。 相似文献
114.
Tehrim Motiwala Blessing Oluebube Akumadu Sbahle Zuma Mbalenhle Sizamile Mfeka Wanping Chen Ikechukwu Achilonu Khajamohiddin Syed Thandeka Khoza 《Molecules (Basel, Switzerland)》2022,27(1)
Caseinolytic proteins (Clp), which are present in both prokaryotes and eukaryotes, play a major role in cell protein quality control and survival of bacteria in harsh environmental conditions. Recently, a member of this protein family, ClpK was identified in a pathogenic strain of Klebsiella pneumoniae which was responsible for nosocomial infections. ClpK is linked to the thermal stress survival of this pathogen. The genome wide analysis of Clp proteins in Klebsiella spp. indicates that ClpK is present in only 34% of the investigated strains. This suggests that the uptake of the clpk gene is selective and may only be taken up by a pathogen that needs to survive harsh environmental conditions. In silico analyses and molecular dynamic simulations show that ClpK is mainly α-helical and is highly dynamic. ClpK was successfully expressed and purified to homogeneity using affinity and anion exchange chromatography. Biophysical characterization of ClpK showed that it is predominantly alpha-helical, and this is in agreement with in silico analysis of the protein structure. Furthermore, the purified protein is biologically active and hydrolyses ATP in a concentration- dependent manner. 相似文献
115.
动态环境约束下企业的资本积累 总被引:1,自引:0,他引:1
本文讨论动态环境约束下企业的动态投资行为,拓广了文献[4]的结果.为了使讨论的问题更符合实际情况,本文假设政府设定的污染排放上限是与企业的规模大小有关,即假设污染排放上限是生产资本的函数,讨论动态环境约束下企业的最佳动态投资行为,并为政府制定污染排放政策提供依据. 相似文献
116.
构建了基于二阶段异质随机森林的汽油辛烷值预测模型.首先利用样本-位点信息表知识约简模型,筛选出对汽油辛烷值影响大的位点数据作为第一阶段;然后,利用集成学习思想集成支持向量回归和动态时间序列神经网络,构建异质随机森林预测模型作为第二阶段.利用十折交叉法验证模型精度,结果表明该集成学习算法具有有效性和高精度. 相似文献
117.
118.
119.
Sumeng Wang Yue Luo Wei Jiang Xiaomeng Li Qingsheng Qi Quanfeng Liang 《Molecules (Basel, Switzerland)》2022,27(3)
Several strategies, including inducer addition and biosensor use, have been developed for dynamical regulation. However, the toxicity, cost, and inflexibility of existing strategies have created a demand for superior technology. In this study, we designed an optogenetic dual-switch system and applied it to increase polyhydroxybutyrate (PHB) production. First, an optimized chromatic acclimation sensor/regulator (RBS10–CcaS#10–CcaR) system (comprising an optimized ribosomal binding site (RBS), light sensory protein CcaS, and response regulator CcaR) was selected for a wide sensing range of approximately 10-fold between green-light activation and red-light repression. The RBS10–CcaS#10–CcaR system was combined with a blue light-activated YF1–FixJ–PhlF system (containing histidine kinase YF1, response regulator FixJ, and repressor PhlF) engineered with reduced crosstalk. Finally, the optogenetic dual-switch system was used to rewire the metabolic flux for PHB production by regulating the sequences and intervals of the citrate synthase gene (gltA) and PHB synthesis gene (phbCAB) expression. Consequently, the strain RBS34, which has high gltA expression and a time lag of 3 h, achieved the highest PHB content of 16.6 wt%, which was approximately 3-fold that of F34 (expressed at 0 h). The results indicate that the optogenetic dual-switch system was verified as a practical and convenient tool for increasing PHB production. 相似文献
120.
Angelika Macior Izabela Zaborniak Pawe Chmielarz Joanna Smenda Karol Wolski Ewa Ciszkowicz Katarzyna Lecka-Szlachta 《Molecules (Basel, Switzerland)》2022,27(3)
The article presents the modification of ash wood via surface initiated activators regenerated by electron transfer atom transfer radical polymerization mediated by elemental silver (Ag0 SI-ARGET ATRP) at a diminished catalyst concentration. Ash wood is functionalized with poly(methyl methacrylate) (PMMA) and poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) to yield wood grafted with PMMA-b-PDMAEMA-Br copolymers with hydrophobic and antibacterial properties. Fourier transform infrared (FT-IR) spectroscopy confirmed the covalent incorporation of functional ATRP initiation sites and polymer chains into the wood structure. The polymerization kinetics was followed by the analysis of the polymer grown in solution from the sacrificial initiator by proton nuclear magnetic resonance (1H NMR) and gel permeation chromatography (GPC). The polymer layer covalently attached to the wood surface was observed by scanning electron microscopy (SEM). The hydrophobic properties of hybrid materials were confirmed by water contact angle measurements. Water and sodium chloride salt aqueous solution uptake tests confirmed a significant improvement in resistance to the absorption of wood samples after modification with polymers. Antibacterial tests revealed that wood-QPDMAEMA-Br, as well as wood-PMMA-b-QPDMAEMA-Br, exhibited higher antibacterial activity against Gram-positive bacteria (Staphylococcus aureus) in comparison with Gram-negative bacteria (Escherichia coli). The paper presents an economic concept with ecological aspects of improving wood properties, which gives great opportunities to use the proposed approach in the production of functional hybrid materials for industry and high quality sports equipment, and in furniture production. 相似文献