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63.
Arabinda Mallick 《Journal of luminescence》2006,118(2):165-172
Solvatochromic effects on the fluorescence behavior of 7-hydroxy-4-methyl-8-(4′-methyl-piperazine-1′ yl)methylcoumarin (HMMC) was studied in different solvents. The fluorescence of HMMC was found to be highly sensitive to both the polarity and the protic character of the solvent. Exploiting the polarity-sensitive fluorescence property of HMMC, its excited-state dipole moment has been determined. Fluorescence (Förster) resonance energy transfer (FRET) process from HMMC to a potent bioactive molecule 3-acetyl-4-oxo-6,7-dihydro-12 H indolo-[2,3-a] quinolizine (AODIQ) was studied. From the determined KSV and R0 values, it is argued that a long-range dipole-dipole interaction is operating for the energy transfer mechanism. The energy transfer efficiency (E) and the distance between the acceptor and the donor (r0) have been determined. 相似文献
64.
We derive the basic canonical brackets amongst the creation and annihilation operators for a two (1 + 1)- dimensional (2D) gauge field theoretic model of an interacting Hodge theory where a U(1) gauge field (Aμ) is coupled with the fermionic Dirac fields (ψ and ψ). In this derivation, we exploit the spin-statistics theorem, normal ordering and the strength of the underlying six infinitesimal continuous symmetries (and the concept of their generators) that are present in the theory. We do not use the definition of the canonical conjugate momenta (corresponding to the basic fields of the theory) anywhere in our whole discussion. Thus, we conjecture that our present approach provides an alternative to the canonical method of quantization for a class of gauge field theories that are physical examples of Hodge theory where the continuous symmetries (and corresponding generators) provide the physical realizations of the de Rham cohomological operators of differential geometry at the algebraic level. 相似文献
65.
K. K. Sabelfeld 《Journal of statistical physics》2008,133(6):1107-1136
A viscous Stokes flow over a disc under random fluctuations of the velocity on the boundary is studied. We give exact Karhunen-Loève
(K-L) expansions for the velocity components, pressure, stress, and vorticity, and the series representations for the corresponding
correlation tensors. Both the white noise fluctuations, and general homogeneous random excitations of the velocities prescribed
on the boundary are studied. We analyze the decay of correlation functions in angular and radial directions, both for exterior
and interior Stokes problems. Numerical experiments show the fast convergence of the K-L expansions. The results indicate
that ignoring the stochastic fluctuations in boundary conditions dramatically underestimates the variance of the velocity
and pressure in the interior/exterior of the domain.
The support of the RFBR Grant N 06-01-00498 is kindly acknowledged. 相似文献
66.
Quanhua Liu Fuzhong Weng 《Journal of Quantitative Spectroscopy & Radiative Transfer》2008,109(10):1943-1950
Microwave radiances are usually converted into brightness temperatures for data assimilation and retrievals. The Rayleigh-Jeans approximation has been believed to be a good approximation for the conversion at low frequencies, but inaccurate at high frequencies. However, the simplified radiative transfer models under the Rayleigh-Jeans approximation (hereafter referred as BT-RTE) have been successfully applied in radiance simulations for frequencies below 183 GHz, which has somewhat puzzled the radiative transfer community. This paper clarifies the confusion. In addition, the conversion formula for the third and the fourth Stokes components are derived.Simulations for a polarized sensor, the Special Sensor Microwave Imager and Sounder, show that the BT-RTE is generally accurate. Results for a polarimetric sensor, WINDSAT, show that the third and the fourth Stokes radiances should be converted using the exact conversion formula given in this study rather than using a direct Planck function conversion. 相似文献
67.
A simple and efficient time-dependent method is presented for solving the steady compressible Euler and Navier–Stokes equations with third-order accuracy. Owing to its residual-based structure, the numerical scheme is compact without requiring any linear algebra, and it uses a simple numerical dissipation built on the residual. The method contains no tuning parameter. Accuracy and efficiency are demonstrated for 2-D inviscid and viscous model problems. Navier–Stokes calculations are presented for a shock/boundary layer interaction, a separated laminar flow, and a transonic turbulent flow over an airfoil. 相似文献
68.
It is shown that polarized light can be polarization squeezed only if it exhibits sub-Poissonian statistics with the Mandel's Q factor less than − 1/2. 相似文献
69.
反斯托克斯荧光制冷 (Anti StokesFluorescentCooling)也被称为激光制冷 (LaserCooling)。自 1 995年以来 ,该项研究取得了飞速的发展。目前 ,人们利用激光制冷的方法已经得到了比家用冰箱冷冻室还低的温度 ,并能够利用半导体量子阱材料得到低于液氮温区的降温。由于这项技术具有全光性 ,它的制冷器具有体积小、重量轻、无电磁辐射、无振动、无噪声等特点 ,因此也就具有了非常诱人的应用前景和符合军事、空间、集成光学、微电子、医学等领域的特殊要求 ,而被国外研究者所重视。做为一项基本技术 ,激光制冷研究的突破必然会导致许多对温度有特殊要求的高技术实用化 ,推动那些领域向前发展。本文详细地介绍了反斯托克斯荧光制冷研究的历史和最新进展 ,详细地介绍了该项研究中的方法和理论。着重介绍了激光制冷的热力学限制、发光过程的热力学理论 ,探讨激光制冷产生的机制和制冷理论。最后 ,对激光制冷器的发展前景和设计依据进行了讨论 ,尝试性地探讨了线圈型制冷器、用于芯片的制冷器和单分子 光子泵型制冷器的应用考虑。 相似文献
70.
偏振相函数是气溶胶重要的光学参数之一,它对气溶胶复折射指数、粒子尺度和形状都十分敏感。多角度多光谱偏振遥感可以有效获取气溶胶偏振相函数信息。新一代CIMEL太阳-天空偏振辐射计CE318-DP作为高精度地基气溶胶偏振遥感仪器已被引入全球气溶胶自动观测网AERONET(AErosol RObotic NETwork),并作为扩展多波长偏振测量的太阳-天空辐射计观测网SONET(Sun/sky-radiometer Observation NETwork)的主要仪器,已在不同类型气溶胶观测站点积累了多年的偏振数据。但目前偏振反演仅能利用线偏振度或偏振辐亮度。与线偏振度和偏振辐亮度相比,Stokes参数Q和U不仅包含天空光线偏振强度信息还包含偏振方向信息。利用CE318-DP多光谱多角度测量的天空光Stokes参数Q和U反演气溶胶偏振相函数的方法。针对CE318-DP标准主平面偏振观测模式PPP(Polarized Principal Plane)下Stokes参数U对气溶胶特性变化不敏感、信息难以利用的不足,测试了新的平纬圈偏振扫描模式ALMP(ALMucantar Polarization)获取Stokes参数Q和U,并成功应用于偏振相函数的反演。系统分析了340~1 640 nm多光谱通道上典型生物质燃烧型气溶胶和水溶性气溶胶的-P12/P11反演结果并测试了反演方法在晴朗和灰霾不同大气条件下的适用性。无论在主平面还是平纬圈观测几何下,反演结果在可见光和近红外通道上均与真实值具有较好的一致性。进一步讨论了模型中基于气溶胶参数初始值和大气气溶胶参数真实值计算的“大气单次散射/大气散射”的比值近似相等的假设条件在短波通道不能很好地满足是造成紫外波段反演结果偏差较大的原因之一。后续有待进一步提高反演模型在短波通道的适用性,为利用不同光谱通道上-P12/P11的变化特征改进气溶胶微物理参数反演奠定了基础。 相似文献