Excitation‐energy transport (EET) phenomena in meso–meso directly linked Zn(II )porphyrin arrays in the singlet and triplet excited states were investigated with a view to electronic coupling strength and coherence length by steady‐state and time‐resolved spectroscopic measurements. To investigate energy transfer in the triplet states, we modified the Zn(II )porphyrin arrays with bromo substituents at both ends. The coupling strength of the Soret bands of the arrays was estimated to be about 2200 cm?1, and that of the Q bands is about 570 cm?1. The coherence length in the S1state of the Zn(II )porphyrin arrays was determined to be 4–5 porphyrin units, which is comparable to that of the well‐ordered two‐dimensional circular structure B850 in the peripheral light‐harvesting antenna (LH2) in photosynthetic purple bacteria. This indicates that the Zn(II )porphyrin arrays are well suited for mimicking natural light‐harvesting antenna complexes. On the other hand, the rate of energy transfer in the triplet state is estimated to be on the order of 100 μs?1, and the very weak coupling between the triplet states (ca. 0.003 cm?1), indicates that the triplet excitation energy is essentially localized on a single porphyrin moiety.相似文献
Research methods for the formation of BER in the ground-to-ground Free-Space Laser Communication Systems (Free-Space Optics – FSO) with increased analytical effectiveness have been suggested. They correspond to physically rightful approximations with approbated quantity effectiveness. The methods have been used to study the influence of heterogeneous stochastic factors, such as: quantum noises, atmospheric transmittance fluctuations, mechanical vibrations of the transmitting laser antenna, atmospheric turbulence, on BER of FSO.
An algorithm for quantity estimation of the joint influence of all stochastic factors has been created. Numerical examples, illustrated by graphic material, have been shown. 相似文献
Microwave invasion into living bodies through a millimeter wave catheter irradiation is described. As radiation sources for millimeter wave irradiation tests both Impatt oscillator (IO) and a Gunn oscillator were used. Irradiated samples are cow livers and living rats. A newly designed wave-guide vent antenna (WVA) with an anti-reflecting layer (ARL) is used as a launcher for the irradiation and the reflectance measurements. The correlation between the denaturation of the
tissue and the reflectance from the WVA is studied in detail. 相似文献
The air breakdown in the high-power antenna near-field region limits the enhancement of the radiated power. A model coupling the field equivalent principle and the electron number density equation is presented to study the breakdown process in the near-field region of the circular aperture antenna at atmospheric pressure. Simulation results show that, although the electric field in the near-field region is nonuniform, the electron diffusion has small influence on the breakdown process when the initial electron number density is uniform in space. The field magnitude distribution on the aperture plays an important role in the maximum radiated power above which the air breakdown occurs. The maximum radiated power also depends on the phase difference of the fields at the center and edge of the aperture, especially for the uniform field magnitude distribution. 相似文献
Photoconductive antennas are promising sources of terahertz radiation that is widely used for spectroscopy, characterization, and imaging of biological objects, deep space studies, scanning of surfaces, and detection of potentially hazardous substances. These antennas are compact and allow for generation of both ultrabroadband pulses and tunable continuous wave terahertz signals at room temperatures, with no need for high‐power optical sources. However, such antennas have relatively low energy conversion efficiency of femtosecond laser pulses or two close pump wavelengths (photomixers) into the pulsed and continuous terahertz radiation, correspondingly. Recently, an approach to solving this problem that involves known methods of nanophotonics applied to terahertz photoconductive antennas and photomixers has been proposed. This approach comprises the use of optical nanoantennas for enhancing the absorption of pump laser radiation in the antenna gap, reducing the lifetime of photoexcited carriers, and improving the antenna thermal efficiency. This Review is intended to systematize the main results obtained by researchers in this promising field of hybrid optical‐to‐terahertz photoconductive antennas and photomixers. We summarize the main results on hybrid THz antennas, compare the approaches to their implementation, and offer further perspectives of their development including an application of all‐dielectric nanoantennas instead of plasmonic ones.
In this paper, we first propose a metamaterial structure by etching the same two interdigital fingers on the upper ground of quarter mode substrate integrated waveguide(QMSIW). The simulated results show that the proposed QMSIWbased metamaterial has a continuous phase constant changing from negative to positive values within its passband. A periodic leaky-wave antenna(LWA), which consists of 11 QMSIW-based metamaterial unit cells, is designed, fabricated,and measured. The measured results show that the fabricated antenna achieves a continuous beam scanning property from backward-43° to forward +32° over an operating frequencyrange of 8.9 GHz–11.8 GHz with return loss better than 10 d B.The measured antenna gain keeps consistent with the variation of less than 2 d B over the operating frequency range with a maximum gain of 12 d B. Besides, the measured and simulated results are in good agreement with each other, indicating the significance and effectiveness of this method. 相似文献
In view of the complicated structure of the deflector-jet mechanism,a mathematical model based on the turbulent jet flow theory in the deflector-jet amplifier is proposed.Considering the energy transformation and momentum variation,an equation of the flow velocity distribution at the key fluid region is established to describe the morphological changes of the fluid when it passes through the deflector and jets into the receiver.Moreover,the process is segmented into four stages.According to the research results,the oil enters the deflector and impinges with the side wall.Then one part of the oil's flow velocity decreases and a high pressure zone is formed by the oil accumulation,the other part of the oil reverses out of the deflector along the side wall.Prior to entering the receiver,the flow is a kind of plane impinging jet.Virtually,the working pressure of the receiver is generated by the impact force,while the high speed fluid flows out of the receiver and forms a violent vortex,which generates negative pressure and causes the oil to be gasified.Compared with the numerical simulation results,the turbulent jet model that can effectively describe the characteristics of the deflector-jet mechanism is accurate.In addition,the calculation results of the prestage pressure characteristic have been verified by experiments. 相似文献
A new method to design an ultra-thin high-gain circularly-polarized antenna system with high efficiency is proposed based on the geometrical phase gradient metasurface(GPGM).With an accuracy control of the transmission phase and also the high transmission amplitude,the GPGM is capable of manipulating an electromagnetic wave arbitrarily.A focusing transmission lens working at Ku band is well optimized with the F /D of 0.32.A good focusing effect is demonstrated clearly by theoretical calculation and electromagnetic simulation.For further application,an ultra-thin single-layer transmissive lens antenna based on the proposed focusing metasurface operating at 13 GHz is implemented and launched by an original patch antenna from the perspective of high integration,simple structure,and low cost.Numerical and experimental results coincide well,indicating the advantages of the antenna system,such as a high gain of 17.6 d B,the axis ratio better than 2 d B,a high aperture efficiency of 41%,and also a simple fabrication process based on the convenient print circuit board technology.The good performance of the proposed antenna indicates promising applications in portable communication systems. 相似文献