AB2型超支化聚(胺-酯)活性端羟基与乙酸酐的功能化反应

以二乙醇胺和丙烯酸甲酯为原料合成了具有端羟基的AB2型超支化聚（胺－酯）。研究了超支化聚（胺－酯）端羟基与乙酸酐的功能化反应，分析了温度和搅拌对该反应动力学的影响。实验结果表明：超支化聚（胺－酯）端羟基与乙酸酐的酯化反应动力学偏离二级反应，用反常扩散理论对这一实验现象进行了解释。     

Constraints on anomalous quartic gauge couplings via Wγjj production at the LHC

Vector boson scattering at the Large Hadron Collider (LHC) is sensitive to anomalous quartic gauge couplings (aQGCs). In this study, we investigate the aQGC contribution to \begin{document}$ W \gamma jj$\end{document} production at the LHC with \begin{document}$\sqrt{s}=13$\end{document} TeV in the context of an effective field theory (EFT). The unitarity bound is applied as a cut on the energy scale of this production process, which is found to have significant suppressive effects on signals. To enhance the statistical significance, we analyze the kinematic and polarization features of the aQGC signals in detail. We find that the polarization effects induced by aQGCs are unique and can discriminate the signals from the SM backgrounds well. With the proposed event selection strategy, we obtain the constraints on the coefficients of dimension-8 operators with current luminosity. The results indicate that the process \begin{document}$pp \to W \gamma jj$\end{document} is powerful for searching for the \begin{document}$O_{M_{2,3,4,5}}$\end{document} and \begin{document}$O_{T_{5,6,7}}$\end{document} operators.     

米氏理论的近似及在粒度测量中的应用

将夫琅禾费衍射理论与几何散射 (包括折射和反射 )相结合 ,给出平行光入射下圆形颗粒在前向大角度范围内的散射光强分布近似算法。由于考虑了衍射、折射和反射相互间的干涉效应和颗粒对光的吸收性 ,对于正常或非正常衍射状态下无因次参量α≥ 40的耗散颗粒 ,在前向 0°～ 60°散射之内 ,该方法对散射光强计算结果与米氏理论结果是吻合的。由于计算速度比米氏理论快 ,有效角度范围比夫琅禾费衍射理论宽 ,因而适合于大颗粒的前向光强计算。将这一计算方法应用到大角度采光时的激光粒度测量实验中 ,收到了良好的效果     

铁磁绝缘体间的极薄Bi2Se3薄膜的相变研究

研究一个极薄三维拓扑绝缘体Bi₂Se₃薄膜处于两个铁磁绝缘体层之间, 其铁磁层的磁化方向都处于竖直平面, 系统拓扑性质随磁化方向夹角的变化. 从表面态电子低能有效哈密顿量出发计算系统的Chern 数, 和运用一个具有Armchair边界的单层六角晶格带的紧束缚模型模拟系统的体能带和边缘态, 来确定系统所处的拓扑相. 发现两个铁磁层的磁化方式从平行转到反平行的某一临界角度, 系统经历从反常量子霍尔相到普通绝缘相的转变.     

Environment-dependent continuous time random walk

A generalized continuous time random walk model which is dependent on environmental damping is proposed in which the two key parameters of the usual random walk theory: the jumping distance and the waiting time, are replaced by two new ones: the pulse velocity and the flight time. The anomalous diffusion of a free particle which is characterized by the asymptotical mean square displacement <x²(t)>～t^α is realized numerically and analysed theoretically, where the value of the power index α is in a region of 0 < α < 2. Particularly, the damping leads to a sub-diffusion when the impact velocities are drawn from a Gaussian density function and the super-diffusive effect is related to statistical extremes, which are called rare-though-dominant events.     

基于交叉极化旋转相位梯度超表面的宽带异常反射

设计实现了一种基于双圆弧形金属结构的宽带反射型极化旋转超表面, 在7.9–20.1 GHz的宽频带范围内交叉极化转换率达到99%, 通过改变其结构参数可实现在保持高效的交叉极化转换率的条件下对交叉极化反射相位的自由调控. 基于六种不同结构参数极化旋转超表面结构单元的空间排布设计实现了一维宽带相位梯度超表面, 在宽频带内, 实现了异常反射. 测试了其镜面交叉极化反射率, 与仿真结果基本一致. 仿真计算了x-极化波入射时的电磁场分布和异常反射角度, 与理论计算结果基本一致. 仿真与测试结果均表明这种相位梯度超表面在8.9–10 GHz 和10.0–18.1 GHz的两个宽带频率范围内可分别实现高效的表面波耦合和异常反射.     

非晶FezZn1-xO薄膜的结构、磁性和电性能：

采用射频共溅射方法制备了FezZn1-xO（x=0．80,0．86,0．93）非晶薄膜,该薄膜具有较强的室温铁磁性,制备态的Fe093Zn0．07O的饱和磁化强度Ms可达333．29emu／cm3,磁性能是各向同性的．与多晶的FezZn1-xO（z≤20％）不同的是样品出现了明显的异常霍尔效应（AHE）,样品均为n型半导体,载流子浓度约为10^19-10^20cm^-3．退火后的样品在低温222K下存在着电阻极小值现象．薄膜的低温电阻导电机理属于自旋依赖的电子变程跃迁机理,上述实验结果表明高Fe含量的非晶FeZnO体系有作为新型自旋电子学器件材料的可能．     

利用遗传算法优化线性啁啾光栅性能

针对制作町用于40 Gb/s全光色散补偿的宽带线性啁啾光栅时出现带内群时延纹波波动较大等问题.提出了一种通过设计和改变切趾函数的参量来优化线性啁啾光栅的新方法.该方法实现简单.只需根据需要设计具有不同滚降特性的切趾函数,同时利用遗传箅法来优化切趾参量.结合传输矩阵法经过200代获得了低带内时延纹波的线性啁啾光栅.数值结果验证了采取非对称分段切趾法在保持反射谱宽和平坦性的同时可以抑制带内群时延纹波的优越性.利用该方法制作了反射谱工作带宽为1.06 nm、时延纹波不超过45.60 ps、可用于大容量密集波分复用系统(DWDM)色散补偿的线性啁啾光纤光栅.     

一维光子晶体的折射率研究

对于一维光子晶体反常折射的研究大都基于光子晶体的色散关系解析解,文章作者认为,在光线非正入射时上述方法是不适用的,有必要使用更加合适的方法对一维光子晶体的折射规律加以系统研究,从而对一维光子晶体器件的设计起到些指导作用.文章将一维光子晶体作为二维问题来考察,使用数值方法(平面波展开法)来计算光线在光子晶体中沿各个方向传播时的色散关系,进而得到了折射角与入射角和频率的关系.结果表明:对于一维光子晶体,考查在第一能带范围内的频率,当频率越接近能带边,且入射角越接近敏感区时,折射角对入射角和频率的变化越敏感.而且,敏感区随频率的增大有向小角度移动的趋势.     

Ferromagnetism, variable range hopping and anomalous Hall effect in epitaxial Co:ZnO thin film

A series of high quality single crystalline epitaxial Zn_0.95Co_0.05O thin films is prepared by molecular beam epitaxy. Superparamagnetism and ferromagnetism are observed when the donor density is manipulated in a range of 10¹⁸ cm^-3-10²⁰ cm^-3 by changing the oxygen partial pressure during film growth. The conduction shows variable range hopping at low temperature and thermal activation conduction at high temperature. The ferromagnetism can be maintained up to room temperature. However, the anomalous Hall effect is observed only at low temperature and disappears above 160 K. This phenomenon can be attributed to the local ferromagnetism and the decreased optimal hopping distance at high temperatures.