Temperature‐dependent location of a weakly segregated block copolymer in binary blends of block copolymers

The phase behaviors of binary blends of poly(styrene‐b‐butadiene) block copolymers were investigated by a small‐angle X‐ray scattering technique. The blends were composed of weakly segregated one in a random micellar phase and the other in a cylindrical phase with similar molecular weights and complementary volume fractions. Morphologies, domain spacings, and order–disorder transition temperatures of the blends indicated that the junctions of the constituent block copolymers share the interface at low temperatures. The domain spacing decreased as temperature increased in a blend with a small amount of the weakly segregated block copolymer. In the cases of the blends with a large amount of the weakly segregated constituent, domain spacing increased with increasing temperature. These results implied that some of the weakly segregated block copolymer moved from the interface to one microdomain at higher temperatures. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 470–476     

Faraday Rotation of Overdense Magnetized Plasma

In this study, we investigate Faraday rotation of electromagnetic waves that are anomalously transmitted through an over‐dense magnetized plasma layer. Here, magnetized plasma indicates that the plasma layer is immersed in a uniform magnetic field. Firstly, normally opaque over‐dense magnetized plasma is shown to be transparent to obliquely incident electromagnetic waves. This high transparency can be achieved by providing conditions for resonant excitations of plasmonic modes. The resonant characteristics of the transmission coefficient of the considered structure are determined and discussed. The conditions under which the magnetized plasma behaves as a complete reflector are also obtained. Faraday rotation is shown to be enhanced under high transparency conditions. The reflected wave also exhibits Faraday rotation and is enhanced under total reflection conditions. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

宽入射角度偏振不敏感高效异常反射梯度超表面

偏振不敏感超表面在实际应用中具有重要意义, 本文提出了一种光通信波段的、对偏振不敏感的异常反射式梯度超表面, 这种超表面对于x-偏振和y-偏振入射光都能够实现高效率的异常反射, 表现出偏振不敏感特性, 为解决传统反射式超表面的偏振敏感性问题提供了一种新途径. 它采用金属(Au)-绝缘层(SiO₂)-金属(Au)结构, 超表面的超晶胞由五个各向同性的、尺寸不同的十字形基本结构单元组成. 仿真结果表明, 这种超表面结构对不同线偏振入射平面光波有几乎相同的相位和振幅响应; 合理的选取五个基本结构单元的尺寸, 在一个超晶胞内实现了2πup 相位的覆盖, 反射光波阵面畸变小, 而且反射光都集中到异常反射级次, 在工作波长1480 nm处具有较高的异常反射率(～ 70%). 此外, 这种结构的超表面在-30°–0°的宽入射角度范围内都具有偏振不敏感的异常反射特性. 在光通信、光信号处理、显示成像等领域具有潜在的应用前景.     

Localization correction to the anomalous Hall effect in amorphous CoFeB thin films

An obvious weak localization correction to anomalous Hall conductance(AHC) in very thin CoFeB film is reported.We find that both the weak localization to AHC and the mechanism of the anomalous Hall effect are related to the CoFeB thickness.When the film is thicker than 3 nm,the side jump mechanism dominates and the weak locaUzation to AHC vanishes.For very thin CoFeB films,both the side jump and skew scattering mechanisms contribute to the anomalous Hall effect,and the weak localization correction to AHC is observed.     

Status of the Fermilab muon （g-2） experiment

The New Muon （g-2） Collaboration at Fermilab has proposed to measure the anomalous magnetic moment of the muon, αμ, a factor of four better than was done in E821 at the Brookhaven AGS, which obtained αμ = [116592089（63）] × 10^-11 ±0.54 ppm. The last digit of a, is changed from the published value owing to a new value of the ratio of the muon-to-proton magnetic moment that has become available. At present there appears to be a difference between the Standard-Model value and the measured value, at the ≌ 3 standard deviation level when electron-positron annihilation data are used to determine the lowest-order hadronic piece of the Standard Model contribution. The improved experiment, along with further advances in the determination of the hadronic contribution, should clarify this difference. Because of its ability to constrain the interpretation of discoveries made at the LHC, the improved measurement will be of significant value, whatever discoveries may come from the LHC.     

Quantum Macroscopic Effects in a Degenerate Strongly Magnetized Nucleon Gas

A model of a degenerate gas consisting of neutrons that are in chemical equilibrium with degenerate protons and electrons in a stationary and homogeneous superstrong magnetic field is used to describe the state of the matter in central regions of strongly magnetized neutron stars. Expressions for thermodynamic quantities (such as energy density, particle density, pressure, and magnetization) characterizing a degenerate gas of neutrons, protons, and electrons are obtained. In these expressions, the contributions determined by the interaction between anomalous magnetic moments of fermions and the magnetic field are taken into account. Macroscopic effects that may occur in strongly magnetized neutron stars are discussed. We show that all thermodynamic quantities characterizing electrically charged fermions in a strong magnetic field are subject to nonperiodic oscillations caused by the interaction of the anomalous magnetic moments of protons and electrons with the magnetic field. We also show that if the nucleon density and the electron density exceed threshold values that are relatively small and depend on the magnetic field strength, all fermions are fully polarized with respect to the spin. The full spin polarization effect in neutrons is caused by the interaction between the anomalous magnetic moment and the magnetic field. The obtained results may prove useful in understanding processes that occur in the nucleus of a neutron star with a magnetic field frozen into the star.     

Organo-lithiation and halogen metal exchange reactions in organic synthesis-an anomolous aromatic substitution via halogen-metal exchange

Synthesis via organo-lithium compounds is reviewed. An anomalous aromatic substitution via halogen-metal exchange is described. Here, the substitution does not occur at the position where the halogen was present; but at an alternate position. A mechanism is advanced, in which the halogen-metal exchange is proposed as being faster than the hydrogen(acidic)-metal exchange.     

Anomalous1H NMR spectra of 3,4-dihydroisoquinolines and related compounds

Solutions of 3,4-dihydro-6,7-methylenedioxyisoquinoline (1) and analogues2–5 and9 as well as isoquinolines7 and8 in certain samples of CDCl₃, CCl₄, DMSO-d₆ or acetone-d₆ gave rise to anomalous¹Hnmr spectra with extreme line broadening, signals due to protons at C-l and C-3 most often not being seen. The spectra of1 and3 were most striking in this respect.¹Hnmr spectra of the quaternary salt10 and the model schiff base11 were normal. Several hypotheses for the observed line broadening have been considered and rejected, a slow equilibrium1 ⇆13 being one of them. NaBH₄ reduction of1 and2 followed by mass spectrometric analysis of the crude tetrahydroisoquinolines16 and17 ruled out a slow equilibrium1 ⇆14 and2 ⇆15 as contributory cause for line broadening. The crude reduction products unexpectedly contained N-ethyl species22 and25. Their formation is rationalised     

反常输运现象中的分数阶扩散方程

 根据连续性方程,可以得到分形上的标准扩散方程。然而这个标准扩散方程并不能真正描述分形介质中的反常扩散,其根源在于分形介质中的扩散具有记忆效应,为了得到更普遍的扩散方程,通过讨论早期提出的扩散方程的缺陷,可以得到分数阶扩散方程,并且更具有普遍性。     

Anomalous diffusion in fractal porous medium

ＩｎｔｒｏｄｕｃｔｉｏｎＡｎｕｍｂｅｒｏｆｆｉｅｌｄｄａｔａｈａｖｅｓｈｏｗｎｔｈａｔｍａｎｙｋｉｎｄｓｏｆｐｏｒｏｕｓｍｅｄｉａｓｙｓｔｅｍｈａｖｅｄｉｆｆｅｒｅｎｔｋｉｎｄｓｏｆｈｅｔｅｒｏｇｅｎｅｏｕｓｓｔｒｕｃｔｕｒｅｉｎｄｉｆｆｅｒｅｎｔｓｃａｌｅ.Ｔｈｅｓｅｈｅｔｅｒｏｇｅｎｅｏｕｓｓｔｒｕｃｔｕｒｅａｓｓｏｃｉａｔｅｗｉｔｈｅａｃｈｏｔｈｅｒａｎｄｈａｖｅｓｏｍｅｋｉｎｄｓｏｆｓｅｌｆ＿ｓｉｍｉｌａｒｉｔｙａｎｄｗｅｃａｌｌｔｈｉｓｋｉｎｄｐｏｒｏｕｓｍｅｄｉａａｓｆｒａｃｔａｌｐ…