Picosecond time-resolved nonresonant ionization detected IR spectroscopy on 7-azaindole dimer

The picosecond time-resolved IR spectrum of the 7-azaindole dimer has been measured by picosecond time-resolved nonresonant ionization detected IR spectroscopy. This new time-resolved technique was developed by combining nonresonant ionization detected IR (NID-IR) spectroscopy with tunable picosecond IR and UV lasers. The time-resolved NID-IR spectrum from 2 600 cm^-1 to 3 800 cm^-1 shows a drastic change from 1.5 ps to 11 ps time evolution. A mode-specific vibrational redistribution has been suggested. Received 14 May 2002 / Received in final form 11 June 2002 Published online 13 September 2002     

动态场空间分布实时测量装置的研究

描述了一套多路动态场空间分布实时测量系统，该系统是一套以微要为中心的数字化系统，可实现多路动态场空间分面睥精神病时测量。系统由微机、TMS320C50板、开关电路、检波器、传感器、放大器等设备构成硬件系统，并通过编制C50板嵌入式软件和微机主控程序实现系统功能。     

Er3+:Yb3+共掺杂氟氧混合物玻璃的上转换发光研究

制备了化学配方为 (5 0 -x)GeO2 ·PbF2 ·WO3·(6 +x)CdF2 ·1 4Yb2 O3·0 6Er2 O3(x =10 ,2 0 ,30 )氟氧混合物玻璃。研究了 930nm发光二极管激发下Er3+ :Yb3+ 共掺杂情形下的Er3+ 离子的上转换发光特性 ,观测到了Er3+ 离子中心波长位于 5 4 3,5 5 0和 6 5 5nm处的三个强荧光发射带。通过对样品的反斯托克斯喇曼光谱的测量 ,确定了基质的最大声子能量 ,在此基础上分析了上转换荧光的产生机制。利用基质的平均电负性差和平均阳离子场强这两个参数 ,讨论了基质材料中GeO2 和CdF2 含量的调整对上转换发光的影响。     

Effect of Conversion Process([I]-P→ΛΛ) in[I]--Hypernuclei

Effect of conversion process ([I]-P→ΛΛ) on[I]--hypernucleus is studied for [I]12-Be. It is found that theconversion process has a certain extent effect on properties of low-lying states of the[I]--hypernuclei.     

Distance to Ill-Posedness in Linear Optimization via the Fenchel-Legendre Conjugate

We consider the parameter space of all the linear inequality systems, in the n-dimensional Euclidean space and with a fixed index set, endowed with the topology of the uniform convergence of the coefficient vectors. A system is ill-posed with respect to the consistency when arbitrarily small perturbations yield both consistent and inconsistent systems. In this paper, we establish a formula for measuring the distance from the nominal system to the set of ill-posed systems. To this aim, we use the Fenchel-Legendre conjugation theory and prove a refinement of the formula in Ref. 1 for the distance from any point to the boundary of a convex set.This research has been partially supported by grants BFM2002–04114-C02 (01–02) from MEC (Spain) and FEDER (EU) and by grants GV04B-648 and GRUPOS04/79 from Generalitat Valenciana (Spain).     

Unified Solution of the Expected Maximum of a Discrete Time Random Walk and the Discrete Flux to a Spherical Trap

Two random-walk related problems which have been studied independently in the past, the expected maximum of a random walker in one dimension and the flux to a spherical trap of particles undergoing discrete jumps in three dimensions, are shown to be closely related to each other and are studied using a unified approach as a solution to a Wiener-Hopf problem. For the flux problem, this work shows that a constant c = 0.29795219 which appeared in the context of the boundary extrapolation length, and was previously found only numerically, can be derived analytically. The same constant enters in higher-order corrections to the expected-maximum asymptotics. As a byproduct, we also prove a new universal result in the context of the flux problem which is an analogue of the Sparre Andersen theorem proved in the context of the random walker's maximum.     

第十讲数字信号处理与数字信号处理器(DSP)

文章简要介绍了“数字信号处理”与“数字信号处理器（DSP）”的发展历史．在数字信号处理的应用中，实时实现是非常重要的，而DSP在实时处理中，扮演了一个重要的角色．文章中还介绍了DSP在实际应用中的一些关键技术，例如DSP的种类和选型，DSP的开发工具，实时软件的开发过程等．最后，还介绍了一些DSP的应用实例，如语音编码器，视频电话和视频会议系统，用于雷达和声纳的DSP并行处理系统     

A Note on Mathematical Relationships Among Bond-Torsion Force Fields

A set of mathematical relationship between torsion potential functions such as trigonometric and Fourier series is presented herein. A harmonic approximation form is also introduced, and its stiffness constant is related to the parameters of trigonometric and Fourier series. Mathematical relationships between various force field parameters are presented in the form of conversion matrices.     

Probabilistic derivation of van der Waals' equation

A probabilistic derivation of van der Waals' equation is given where the non-ideal contributions to the entropy coincide with the log-likelihood ratios, at their maxima, of the binomial distribution and the upper or lower bounds on the hypergeometric and Pólya distributions. The hypergeometric distribution accounts for the repulsive interactions of a hard sphere gas while the Pólya distribution accounts for the attractive interactions.1. Work supported in part by contributions from the Ministry of Public Education (M.P.I.) and the National Science Council (C.N.R.).     

Optimizing thermography depth probing with a dynamic thermal point spread function

Derivation of two point spread functions PSFs suitable for infrared thermograms analysis is illustrated, based on two unique approaches, one based on depth decaying limit and one on diffusion limit. Experimental work using PMMA sample with back drilled holes and pulsed thermographic routine is utilized to show the effectiveness of deconvoluting pixel temperature transient history with suggested PSF’s. Synthetic second time derivative thermograms are utilized for comparison and the signal to noise ratio is used as a figure of merit for quantification.