WDM系统中ASE噪声的二阶色散效应

讨论了采用小信号分析法研究脉冲波在色散、非线性光纤中的传输时,放大的自发辐射(ASE)噪声作为功率调制项加入脉冲波的传输方程后所产生的效应.ASE噪声不仅被互相位调制不稳定增益所放大,还受二阶色散成分的影响.其传输函数为COS(1/2β2dzω2),这一函数不能通过色散补偿来消除,会削弱ASE噪声的影响.鉴于此,ASE...     

双后向结构的线宽拓展L波段超荧光光源

报道了采用两级级联双后向抽运的光源结构,实现高效率和线宽拓展的L波段掺铒光纤超荧光光源.通过数值模拟,研究了两级光纤长度分配和抽运功率比例对光源输出特性的影响.模拟表明,该结构可获得线宽拓展的平坦L波段光谱,相比常规L波段光谱线宽拓展了15 nm,达近60 nm.此外,抽运功率比例为1∶1时该结构的抽运转换效率最高.利...     

光的真实本性与未来科技飞跃发展预测

物理学史上,有三大主宰着物理学发展的跨世纪大论战,其中前两次论战的主题是光的概念,第三次论战的主题关系整个现代物理,但整个第三次论战被光的概念所主宰.错误的光子概念与第三次论战占了上风的超距心灵作用结合形成物理学最严重的百年大错.研究发现了三大跨世纪论战中造成真理失败的根源.关于光的本性,论文提供了九项证据证明光只是波...     

Solvent-vapour treatment induced performance enhancement of amplified spontaneous emission based on poly[2-methoxy-5-(2’-ethyl-hexyloxy)-1,4-phenylene vinylene]

In this work,performance enhancements of amplified spontaneous emission(ASE) from poly[2-methoxy-5-(2éthyl-hexyloxy)-1,4-phenylene vinylene](MEH-PPV) have been achieved via solvent vapour treatment.Correlations between the morphology of the film and the optical performance of polymer-based ASE are investigated.The active layers are characterised by atomic force microscopy and optical absorption.The results show that the solvent-vapour treatment can induce the MEH-PPV self-organisation into an ordered structure with a smooth surface,leading to enhanced optical gain.Thus the solvent-vapour treatment is a good method for improving the optical properties of the MEH-PPV.     

A novel hybrid mode of sample injection to enhance CZE sensitivity for simultaneous determination of a pyridine-triphenylborane anti-fouling agent and its degradation products

We developed a novel hybrid sample injection mode (HSIM) that presents the combination of electrokinetic injection and vacuum injection to enhance detection sensitivity in CZE. Samples were introduced using both vacuum and electrokinetic injections simultaneously, with a water plug injected into the capillary prior to sample introduction (i.e. similarly to field-amplified sample injection, FASI). Using a sample mixture containing an anti-fouling agent applied to ship hulls, pyridine-triphenylborane and its degradation products (diphenylborinic acid, phenylboronic acid, and phenol) dissolved in ACN, the length of water plug, time, and voltage for sample introduction were optimized. The signal intensity (peak height) was found to be up to a 30-fold increased using HSIM by applying 4 kV for 4 s at the inlet end of the capillary as the cathode with supplementary vacuum in comparison with only vacuum injection for 4 s. The LODs (at a S/N of 3) for pyridine-triphenylborane, diphenylborinic acid, phenylboronic acid, and phenol were 0.88, 1.0, 21, and 23 μg/L, respectively. At the level of 0.04 mg/L, the RSDs (n=4, intra-day) for the above analytes were in the ranges of 1.9-11, 4.3-9.2, and 0.34-0.66% for peak area, peak height, and migration time, respectively. The HSIM is a simple and promising procedure useful for enhancing the sensitivity for both low-and high-mobility ions in CZE.     

微乳液毛细管电动色谱-场放大富集法灵敏分析尿液中的9种麻醉剂类药物

建立了一种微乳液毛细管电动色谱(MEEKC)-场放大富集(FASI)分析尿液中多种麻醉剂(吗啡、可待因、纳洛酮、海洛因、蒂巴因、可卡因、哌替啶、芬太尼、美沙酮)的方法。考察了微乳液组成、分离电压等因素的影响,得到的最佳微乳液组成(质量分数)为0.6%十二烷基硫酸钠、1.2%正丁醇、0.6%乙酸乙酯和97.6% 10 mmol/L硼砂缓冲液(pH 9.5);分离电压为25 kV。在上述微乳体系中,9种化合物在15 min内得到了基线分离。采用场放大在线富集技术提高了分析灵敏度,检出限(S/N=3)低至0.3 μg/L。模拟尿样样品中9种麻醉剂的加标回收率介于79.4%～119.9%之间,日内相对标准偏差小于5.5%。将该方法应用于美沙酮大鼠体外代谢样品的测定,结果令人满意。     

Genetic Diversity Caused by Environmental Stress in Natural Populations of Niupidujuan as Revealed by RAPD Technique

Multiplex environmental factors are generally expected to have significant effects on genetic diversity of plant populations.In this study,randomly amplified polymorphic DNA(RAPD) technique was used to reveal the genetic diversity in the same species of four populations collected from Niupidujuan(Rhododendron chrysanthum) at different altitudes,an endangered species,endemic to Northeast China.Initially,twenty informative and reproducible primers were chosen for final RAPD analysis.A total of 152 clear bands...     

二能级原子与高品质因子腔的自发辐射特性

用全量子理论研究二能级原子单模腔耦合系统,通过理论推导和数值计算得出系统的自发辐射光谱和平均粒子数密度.共振时腔与原子的发射光谱在强耦合与弱耦合区域有所不同,腔发射光谱分裂只出现于强耦合区域,而原子发射光谱由于腔感应透明效应在弱耦合区域出现了缺口.本文系统地研究了原子与腔在失谐时的发射光谱,在好腔机理(腔线宽小于原子线宽g)原子与腔即使在大失谐时腔发射出腔频率的光子,这给当前实验上困惑的特性提供了一个理论依据.为了给腔感应透明效应一个新的深入了解,还研究了原子与腔平均粒子数密度随时间的演化,以及平均粒子数密度与光强度之间的关系. 关键词： 自发辐射 强耦合 腔感应透明 好腔机理     

Absolute Asymmetric Synthesis of Enantiopure Organozinc Reagents,Followed by Highly Enantioselective Chlorination

We report the absolute asymmetric synthesis (AAS) of indenylzinc reagents by using total spontaneous resolution followed by enantiospecific conversion into 1‐chloroindene. The chiral complex [Zn(dcp)(ind)(tmeda)] (dcp=2,6‐dichlorophenoxy and tmeda=N,N,N′,N′‐tetramethylethylenediamine) ( 3 ) was prepared from the achiral starting materials indene, potassium, zinc chloride, TMEDA, and 2,6‐dichlorophenol. The reagent resolved spontaneously on crystallization, and single crystals of 3 react with N‐chlorosuccinimide in the presence of benzoquinone in 2‐propanol to give 1‐chloroindene in >98 % enantiomeric excess. It was found that (R)‐ 3 gave (R)‐1‐chloroindene upon reaction, indicating an S_E2′‐mechanism. Since bulk samples of 3 gave optically active product upon chlorination, total spontaneous resolution must have occurred. This demonstrates that enantiopure products can be obtained through the absolute asymmetric synthesis of organometallic reagents starting from achiral materials. The general absolute asymmetric synthesis (AAS) method offers easy access to both enantiomers and an almost limitless variation in the design of the product.     

分子构型对有机半导体分子TPD,DDB和NPB激射性能的影响

N,N′-二苯基-N,N′-二（3-甲苯基）-1,1′-联苯-4,4′-二胺（TPD）分子已证明能够在掺杂和非掺杂平面波导结构中产生受激发射,然而对于该分子激射特性的机理却很模糊.为了得到其激射特性的微观解释,我们通过实验和量化理论研究TPD分子的吸收、光致发光、受激发射以及与TPD分子结构类似的两个分子：1,4-二（二苯胺基）联苯（DDB）和N,N′-二苯基-N,N′-二（1-萘基）-1,1′-联苯-4,4′-二胺（NPB）.我们发现,DDB分子具有与TPD分子相似的自发辐射放大（ASE）特性,然而NPB分子却没有ASE特性,尽管其斯托克斯位移较大,约0.754eV.量子化学计算分析中,我们利用密度泛函理论（DFT）和弗朗克-康登（Franck-Condon）原理研究分子在电子基态和激发态的分子构型以及电子基态的振动能级.理论分析表明,对于TPD和DDB分子,一些苯环中的较强高频拉伸模式（1199～1664cm-1）对PL谱中的第一振动带（0-1跃迁）有显著贡献,该振动带有利于形成激光的四能级系统.而对于NPB分子,相对大的萘基基团取代了TPD和DDB分子外围的甲基与苯环,会产生一些较强的分子低频振动模式（11～689cm-1）,这些低频振动模式则会破坏激光四能级系统.研究结果有助于深刻理解有机分子的激射特性,为新型激射材料的设计和应用提供了理论基础.