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31.
32.
Arvind K. Gathania 《Liquid crystals》2013,40(7):773-776
Critical behaviour of the order parameters has been investigated in the ferroelectric liquid crystal mixture ZLI‐3654 in a 7.5 µm thick planar cell. The temperature dependence of the primary (tilt angle) and secondary (spontaneous polarisation) order parameters is considered. The critical exponent (β) has been evaluated from the fitting of the temperature dependence of the experimental data for both tilt angle and spontaneous polarisation. Experimental results are compared with the predictions of the de Gennes and Landau models. 相似文献
33.
Organic Crystals with Near‐Infrared Amplified Spontaneous Emissions Based on 2′‐Hydroxychalcone Derivatives: Subtle Structure Modification but Great Property Change
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Xiao Cheng Kai Wang Shuo Huang Dr. Houyu Zhang Prof. Dr. Hongyu Zhang Prof. Dr. Yue Wang 《Angewandte Chemie (International ed. in English)》2015,54(29):8369-8373
A series of highly efficient deep red to near‐infrared (NIR) emissive organic crystals 1 – 3 based on the structurally simple 2′‐hydroxychalcone derivatives were synthesized through a simple one‐step condensation reaction. Crystal 1 displays the highest quantum yield (Φf) of 0.32 among the reported organic single crystals with an emission maximum (λem) over 710 nm. Comparison between the bright emissive crystals 1 – 3 and the nearly nonluminous compounds 4 – 7 clearly gives evidence that a subtle structure modification can arouse great property changes, which is instructive in designing new high‐efficiency organic luminescent materials. Notably, crystals 1 – 3 exhibit amplified spontaneous emissions (ASE) with extremely low thresholds. Thus, organic deep red to NIR emissive crystals with very high Φf have been obtained and are found to display the first example of NIR fluorescent crystal ASE. 相似文献
34.
非晶态MnOx/TiO催化剂的制备及其低温NH-SCR性能 《燃料化学学报》2017,45(8):993-1000
采用自发沉积法、共沉淀法及浸渍法制备MnO_x/TiO_2催化剂,通过XRD、TEM、N2吸附-脱附、XPS、H_2-TPR、NH_3-TPD等一系列表征手段研究MnO_x/TiO_2催化剂的结构与性质,并考察MnO_x/TiO_2催化剂低温NH_3-SCR性能。结果表明,自发沉积法制备的MnO_x/Ti O2(s)催化剂具有完全非晶态结构,Mn和Ti之间存在强相互作用,较共沉淀法制备的MnO_x/TiO_2(c)及浸渍法制备的MnO_x/Ti O2(i)表现出更强的氧化还原能力。MnO_x/TiO_2(s)具有较高的比表面积、较多的表面酸量,有利于NH_3的吸附与活化。且表面高浓度的Mn4+离子及吸附氧,有利于将NO氧化为NO2,促进发生"fast-SCR"反应,进而使其表现出优异的低温脱硝性能。MnO_x/TiO_2(s)催化剂在150℃时NO的转化率高达92.8%,在150-350℃NO的转化率保持在90%以上,此外其还具备较强的抗H_2O和SO_2毒化能力。 相似文献
35.
36.
新颖的双通道输出高功率掺铒光纤宽带光源 总被引:4,自引:3,他引:1
在分析L波段放大自发辐射(ASE)谱产生原理的基础上,设计出一种新颖的双级结构掺铒光纤ASE宽带光源,该光源可在两个端口分别输出高功率的C波段和L波段的ASE谱.设计将C波段ASE谱注入到掺铒光纤中作为L波段ASE谱的二次抽运源,使得L波段ASE谱功率得到了有效提高.优化光源结构参量后从两个端口分别获得了12.97 dBm和12.81 dBm的C波段和L波段ASE宽带谱.将两个输出端口组合得到了功率为15.9 dBm,泵浦转换效率达到21.6%的C+L波段超宽带ASE光源. 相似文献
37.
The tunable nature of lasers provides for a wide range of applications. Most applications rely on finding available laser wavelengths to meet the needs of the research. This article presents the concept of compositional tuning, whereby the laser wavelength is designed by exploiting nonstoichiometry. For research where precise wavelengths are required, such as remote sensing, this is highly advantageous. A theoretical basis for the concept is presented and experimental results in spectroscopic measurements support the theoretical basis. Laser operation nicely demonstrates the validity of the concept of designer lasers. 相似文献
38.
We present a theory for quantum interference of four photons generated by spontaneous parametric downconversion. Detailed investigation of the dependence of fourfold coincidence count rate on time delay between the incident and the reflective pump laser pulses is carried out. Gaussian type dependence is found, and good agreement between our theoretical results and experimental data reported in the literature is achieved. 相似文献
39.
We investigate neutron star properties by constructing a chiral SU(3) spontaneous breaking Lagrangian and using relativistic mean-field approximation. The results show that π- condensate appears at some baryon densities,and hyperons ∑- and A exist in neutron star matter at high density. In this model, neutron star's maximum mass is1.12Ms with corresponding radius about 8 km. 相似文献
40.
A method to calculate the loss coefficient of amplified luminescence loss
lum in the active layer of a laser diode on the basis of radiation transfer equations and the balance between emission, amplification, and absorption of spontaneous radiation is suggested. The values of loss
lum and also of the density of fluxes of amplified luminescence have been determined in one- and two-dimensional approximations for laser diodes based on GaAs, GaN, and ZnSe compounds with different configurations of resonators. 相似文献