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1.
2.
Tereza C. R. dos Santos Ricardo Q. Aucélio Reinaldo C. Campos 《Mikrochimica acta》2003,142(1-2):63-66
A simple and direct spectrofluorimetric method has been developed for the determination of aluminum using alizarin red PS
(1,2,4-trihydroxy 9,10-anthraquinone-3-sulfonic acid). The method is based on the strong fluorescence (480/564 nm) of Al3+ and alizarin red. Experimental parameters such as pH, concentration of the ligand, ionic strength of the solution, reaction
time and temperature were optimized in order to maximize the analytical signal. Interferences of several ions (anions and
cations) were studied and evaluated. The linear range of the method extends from 3 to 100 μg L−1. Limit of detection (3sb) was 0.9 μg L−1. The method was tested with a silicate certified reference material. Interferences were eliminated by a liquid extraction
with cupferron.
Author for correspondence. E-mail: aucelior@rdc.puc-rio.br
Received September 10, 2002; accepted January 15, 2003
Published online May 5, 2003 相似文献
3.
Luminescence properties of anodic aluminum oxide films with organic luminophores embedded into pores
V. V. Gruzinskii A. V. Kukhto A. M. Mozalev V. F. Surganov 《Journal of Applied Spectroscopy》1997,64(4):497-502
Luminescence properties of porous anodic aluminum oxide films formed in a 0.6 M solution of citric acid and luminescence of
paraterphenyl, perylene, coumarin 7, and rhodamine 6G dyes adsorbed by the films are investigated. The nature of emitting
centers in anodic aluminum oxide is revealed. Intense photoluminescence of all tested dyes embedded into pores of anodic aluminum
oxide has been found. A redshift of fluorescence spectra of dyes adsorbed by the matrix and emergence of an additional longwave
band have been detected. Data obtained can be used in developing new thin-film luminescent coatings for future applications
in optoelectronics and molecular electronics.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No 4, pp. 483–488, July–August, 1997. 相似文献
4.
痕量铝在硝酸介质中能催化加速过氧化氢和高碘酸钾与二甲苯胺兰FF之间的褪色反应。研究了反应的最佳实验条件,建立了测定痕量铝的新方法。方法检出限为6.1×10-10gAl3+/mL,检测范围为0-1.0μgAl3+/25mL。本方法具有高灵敏度,选择性较好,操作简便,快速的特点。用以测定水样中的痕量铝,获得满意结果。 相似文献
5.
In photochemical vapor deposition of aluminum film on silicon using dimethylaluminum hydride, (CH3)2AlH, a surface reaction dominated below a (CH3)2AlH pressure of 0.3 m Torr at 200°C, which was induced only with the 160 nm band emitted from a deuterium lamp. A gas-phase reaction occurred above 0.3 mTorr at 200°C, which could be induced by both 160 nm and 240 nm emission bands from the lamp. To distinguish between surface ad gas-phase reactions, a thickness profile was used. At 240°C the surface reaction could be induced even by the 240 nm band, while the deposits formed under illumination of the two bands were thinner than those obtained with only the 240 nm band, indicating occurrence of vacuum ultraviolet (VUV)-enhanced desorption. The mechanism responsible for the observed wavelength dependence in unclear. The electrical resistivity of the films deposited at 200°C was 4.5 μΩ cm, which did not change with wavelength. 相似文献
6.
利用富铈混合稀土改善工业纯铝中富铁相形貌的研究 总被引:1,自引:0,他引:1
利用金相分析方法研究了富Ce混合稀土变质对含不同Fe量的工业纯铝的组织和其中富铁相形貌的影响。试验结果表明,随着Fe含量的增加,富铁相由弥散细小的颗粒状向短棒状、长针状转变;富Ce混合稀土变质使铝中的富铁相由长针状变为弥散细小的颗粒状。随着稀土含量的增加,-αAl晶粒逐渐细化,富铁相尺寸及数量逐渐减小。添加0.5%稀土时,-αAl晶粒细化效果最佳,而且富铁相呈细小颗粒状均匀分布在-αAl基体的晶界处。本文还对稀土改善富铁相的机制进行了分析。 相似文献
7.
Highly ordered composite nanowires with multilayer Ni/Cu and NiFe/Cu have been fabricated by pulsed electrodeposition into
nanoporous alumina membrane. The diameter of wires can be easily varied by pore size of alumina, ranging from 30 to 100 nm.
The applied potential and the duration of each potential square pulse determine the thickness of the metal layers. The nanowires
have been characterized by transmission electron microscopy (TEM), magnetic force microscopy (MFM), and vibrating sample magnetometer
(VSM) measurements. The MFM images indicate that every ferromagnetic layer separated by Cu layer was present as single isolated
domain-like magnet. This technique has potential use in the measurement and application of magnetic nanodevices. 相似文献
8.
在应变速率为5.56×10-5s-1—5.56×10-3s-1的范围内,在不同温度下(从223K至773K),对3004铝合金进行系列拉伸试验,探索其锯齿屈服规律;通过激活能的计算、内耗研究、微观组织观察和能谱分析,探讨锯齿屈服的机理与物理本质.结果表明,3004铝合金在形变过程中会出现动态应变时效现象;发现了一种“反常”的锯齿屈服现象:在出现锯齿屈服的温区内,存在锯齿屈服临界应变量转变温度Tt,
关键词:
动态应变时效
锯齿屈服
铝合金
内耗 相似文献
9.
10.
The stoichiometric reactions of trimethylaluminum with 2,6‐(MeOCH2)2C6H3OH (LH) revealed compounds L3Al ( 1 ) and L2AlMe ( 2 ). On the other hand reaction of 1 equiv. of LH with trimethylaluminum did not lead to the formation of complex LAlMe2 ( 3 ), rather 2 together with Me3Al were observed as a result of a disproportionation of 3 . Compounds 1 and 2 were characterized by elemental analysis, 1H and 13C NMR spectroscopy and in the case of 1 by X‐ray diffraction. Derivative 2 underwent transmetalation with Ph3SnOH, giving LSnPh3 ( 4 ) as the result of a migration of ligand L from the aluminum to the tin atom. The identity of 4 was established by elemental analysis, 1H, 13C and 119Sn NMR spectroscopy and 1H, 119Sn HMBC experiments. The system 2 and B(C6F5)3 in a 1:1 molar ratio was shown to be active in the polymerization of propylene oxide and ε‐caprolactone. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献