Polymorphism in alternating polyketones studied by x-ray diffraction and calorimetry

Differential scanning calorimetry and high temperature x-ray diffraction were used to study the perfectly alternating copolymer of ethene and carbon monoxide (polyketone; POKC2). It was found that oriented POK-C2 fibers show a crystalline phase transition at a temperature between 110–125°C with a 10% change in crystalline density. At this temperature, the crystal structure reported recently (POK-α) is transformed to a crystal structure that was reported in the past for room temperature imperfectly alternating polyketone. The latter structure will be designated as POK-β. The influence of chain defects on the crystal structure was studied by synthesizing terpolymers (POK-C2/C3), in which small amounts of propylene-CO units are incorporated into the polymer backbone. The resulting terpolymers differ from the copolymer by the presence of methyl groups randomly distributed along the polyketone backbone chain. Evidence is presented that indicates that the methyl groups are built into the crystal lattice as defects. With more than 5 mole-% propene the terpolymer fibers crystallize exclusively in the β-modification. Below this level the α/β ratio (at room temperature) increases with decreasing amounts of propene. Both as-synthesized and as-spun POK-C2 were found to consist of both POK-α and POK-β; the α/β ratio depends on the method of preparation. Because the drawn POK-C2 fibers studied here consist exclusively of POK-α, the process of spinning and drawing leads to the transformation of unoriented β-rich material into oriented POK-α. © 1995 John Wiley & Sons, Inc.     

Study of thermal aging effect on space charge in poly(methyl methacrylate)

Charges evolution in poly(methyl methacrylate) (PMMA) samples under thermal aging effect has been studied by means of two complementary techniques, thermal step method (TSM) and thermally stimulated depolarization current (TSDC). For the first method, measurements reveal that injected charges, whose quantity is found depending on the number of applied temperature cycles, remain close to the surface sample. TSDC measurements have been carried out for different temperatures ranging from 25 °C to 140 °C. Three distinguishable dipolar relaxations (β₁, β₂ and α) have been highlighted. In the same way, the presence of polarization and injected charges has been confirmed. In support of electric characterization, X-ray reflectometry has been used. The obtained results equally emphasized the thermal aging effect on the material.     

Analysis of Threshold Current and Wall-Plug Efficiency of Diode Lasers with Asymmetric Facet Reflectivity

Threshold current and differential quantum efficiency of broad contact lasers with asymmetric facet reflectivity are discussed with the purpose to reveal factors essential for optimisation of the wall-plug efficiency of such lasers. Lasers with low front facet reflectivity and short cavity often exhibit behaviour difficult to explain with a classical theory. More rigorous calculation performed in this work show that differential quantum efficiency is indeed less affected by a change of the front facet reflectivity or cavity length than predicted by such theory. These findings greatly simplify criteria for optimisation of the wall-plug efficiency of broad contact lasers with coated facets.     

等效法在伏安法测量中的应用

本文提出了在伏安法测量中，消除电表内阻对实验结果影响的一种新方法     

复合结构丝中的电流密度分布和巨磁阻抗效应

提出了由中间为高电导率的非铁磁性金属丝外面包裹一层铁磁材料组成的复合结构丝的电流 密度分布和巨磁阻抗(GMI)效应模型，并对Cu/FeCoNi复合丝进行了数值模拟. 结果表明：在 相同的磁性材料几何尺寸和磁特性时，Cu/FeCoNi复合丝铁磁层内的电流随频率的升高比匀 质FeCoNi铁磁丝内的电流更趋于表面分布，而且开始出现趋肤效应时对应的频率明显降低. 当在比较低的频率下就可以观察到明显的MI变化时，复合结构丝中的电阻和电抗变化主要是 由趋肤效应引起，趋肤效应仍然是引起复合结构材料(包括多层薄膜结构) 关键词： 电流密度 巨磁阻抗效应 趋肤效应     

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用TSC程序模拟了EAST装置等离子体放电的全过程。模拟中考虑了自举电流，并加入了离子回旋共振加热ICRH和快波电流驱动FWCD，得到了中心电子温度4.5keV、中心离子温度3.8keV、中心电子密度1.2×1020m–3的D形截面的等离子体。根据模拟结果对EAST装置进行了伏秒数分析，并研究了不同等离子体电流上升时间、有效电荷数Zeff对放电的影响。     

Recent studies on phosphorus-bridging carbonyl derivatives: organophosphorus analogs of aldehydes and ketones

Reactions of disodium tetracarbonylferrate, Na₂Fe(CO)₄, with sterically hindered dialkylaminodichlorophosphines, R₂NPCl₂ (R₂N=diisopropylamino, dicyclohexylamino, and 2,2, 6, 6-tetramethylpiperidino) in diethyl ether lead to the air-stable phosphorus-bridging carbonyl derivatives (R₂NP)₂COFe₂(CO)₆ as the major products. The phosphorus-bridging carbonyl group in (i-Pr₂NP)₂COFe₂(CO)₆ has been found to undergo the following types of reactions: 1)Reduction, 2)Acylation, 3)Extrusion of the carbonyl group. The mechanisms of the reactions have been considered.This work was presented at the Workshop «The Modern Problems of Heteroorganic Chemistry» held on the ship «Nikolai Bauman» during the period May 8–13, 1993.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1858–1867, November, 1993.     

程控电流示波计时电位法

使用计算机产生极化电流具有纯度高，稳定性好和波形形状种类多等优点。研究了极化电流的频率，波形和相角对示波图的影响。对Ｃｄ＾２＋的测定的线性范围为２×１０＾－５～２×１０＾－４ｍｏｌ／Ｌ，相关系数为０．９９７，该方法可且希望用于分析测试和动力学方面的研究。     

Diagrams,orientations, and varieties

One of the central problems in the theory of ordered sets is to describe the orientations of the covering graph of an ordered set. We show that the particular operation called inversion, together with the classical constructions of retraction and product, provide a context for the classification of all such orientations. AMS subject classifications (1980). 06A10, 05C75, 05C20.     

2-(3-吡唑基)咪唑并[4,5-f]邻菲咯啉的合成

以邻菲咯啉-5,6二-酮和3醛-基吡唑为原料,合成了一种新的配体——2-(3吡-唑基)咪唑并[4,5-f]邻菲咯啉(1),其结构经1H NMR,IR及MS表征。研究了1的电子吸收和荧光性质。