Y2O3:Eu纳米晶的硝基取代苯甲酸配合物固相热解制备和性能

以苯甲酸、邻硝基苯甲酸、间硝基苯甲酸、对硝基苯甲酸、3,5 二硝基苯甲酸等为配体制备了Y3+、Eu3+二元配合物,配合物中Y3+与Eu3+的摩尔比为9：1.利用这些配合物的爆炸式热分解特性通过固相热解反应制备了一系列Y2O3:Eu纳米晶.透射电镜观察,可以看出所得纳米晶呈球形,粒度介于40～60 nm,X射线衍射分析表明实验所得纳米晶属立方晶系,粒径与电镜观察所得结果基本一致；Eu3+的引入并不影响Y2O3的晶相组成；配体类型对纳米晶的结构没有显著影响,不过相对于硝基取代苯甲酸配合物,苯甲酸配合物热解所得Y2O3∶Eu纳米晶团聚严重；退火温度显著影响纳米晶粒度,退火温度高,纳米晶粒度大,反之亦然.荧光光谱测定表明所有Y2O3∶Eu纳米晶具有相似的发光行为,其中以苯甲酸配合物分解所得Y2O3:Eu纳米晶发光性能最为优越.     

A New 4.0-Generation Dendrimer Phosphorescence Labeling Reagent and Its Application to Determination of Trace Alkaline Phosphatase by Affinity Adsorption Solid Substrate-room Temperature Phosphorimetry

A Triton X-100-4.0G-D （4.0G-D refers to a 4.0-generation dendrimer） was brought forward as a new phosphorescence labeling reagent. Two types of specific affinity adsorption （AA） reactions （direct method and sandwich method） were carried out between the labeling product of Triton X-100-4：0G-D-Wheat germ agglutinin （WGA） and alkaline phosphatase （ALP）, the product of AA reaction preserved the good characteristics of room temperature phosphorescence （RTP） of 4.0G-D and △Ip of the product was proportional to the content of ALP. According to the fact stated above, a new method for the determination of trace ALP by affinity adsorption solid substrate-room temperature phosphorimetry （AA-SS-RTP） was established on the basis of WGA labeled with the Triton X-100-4.0G-D. The detection limits were 0.20 ag·spot^-1 （corresponding concentration： 5.0×10^-16 g·mL^-1, namely 5.0×10^-18 mol·L^-1） for a direct method and 0.14 ag·spot^-1 （corresponding concentration： 3.5×10^-16 g·mL^-1, namely 3.5×10^-18 mol·L^-1） for a sandwich method, respectively. For their high sensitivity, good repeatability and high accuracy, the direct method and sandwich method have been successfully appfied to determine the content of ALP in human serum, and the results were coincided with the clinical detection results of the enzyme-linked immunosorbent assay method by the Zhangzhou Hospital of Traditional Chinese Medicine. Meanwhile, the mechanism for the determination of trace ALP by AA-SS-RTP was discussed.     

CROSS-LINKING OF AROMATIC POLY（THIOETHER）S

A novel cross-linking process using two high molecular weight aromatic poly(thioether)s,which were synthesized by the reactions of 4,4′-thiobisbenzenethiol with 4,4′-difluorobenzophenone and 4,4′-difluorodiphenylsulfone,respectively, and commercially available lower molecular weight poly(p-phenylene sulfide)was investigated.These reactions were carried out in bulk by the addition of silver tetrafluroborate andα,α′-dibromo-p-xylene at 190℃over a period of 45 min. Furthermore,the same procedure could be modified to cross-link compression-molded films of these three polymers.The thermal and solubility behaviors of these polymers before and after cross-linking reactions,are presented.     

CaO和NaCl焙烧混合稀土精矿过程中的分解反应

用XRD和TG-DTA热分析技术, 研究了含独居石和氟碳铈镧矿的混合稀土精矿在100～1000 ℃焙烧过程中, 添加CaO, NaCl时, REPO4和REFCO3的分解反应. 研究结果表明: 不添加CaO和NaCl时, 仅在377～450 ℃范围内存在REFCO3的分解反应, 其产物是REOF, RE2O3, 以及Ce2O3进一步的氧化产物CeO2, 而REPO4不分解; 添加CaO后在660～750 ℃之间, CaO有3种分解作用: (1) CaO分解REPO4, 其产物是RE2O3和Ca3(PO4)2. (2) CaO分解REOF, 其产物是RE2O3和CaF2. (3) CaO和REOF的分解产物CaF2共同作用分解REPO4, 其分解产物为RE2O3, Ca5F(PO4)3; 添加CaO, NaCl后, 混合精矿的分解率明显提高, NaCl的作用是为反应体系提供了液相, 促进了固相反应物间的传质过程, 加快了反应速度. 与此同时NaCl还可能参加了CaO分解REPO4的反应.     

The effect of H2S concentration on the corrosion behavior of API 5L X-70 steel

This work presents electrochemical data measured during the corrosion of API 5L X-70 pipeline steel immersed in aqueous environments containing dissolved H₂S. Three different electrolyte were used: a 3 wt% NaCl solution containing 100, 650 and 2,550 ppm of H₂S respectively. The corrosion of steel is described by means of electrochemical impedance spectroscopy. The electrochemical data obtained from the steel monitoring are presented in terms of Nyquist plots. The influence of the total H₂S concentration as well as the effect of temperature on the corrosion of API 5L X-70 steel were also studied. In the presence of H₂S the R_ct values decrease as the H₂S concentration increases.     

Ge—132与稀土离子的配合物及其对单核苷酸磷酯键的催化水解作用

Ｇｅ－１３２的羧酸阴离子与稀土离子螯合配位，生成３：１型配合物，在配合物中，Ｇｅ－１３２的ＧｅＯ３／２基团水解为Ｇｅ（ＯＨ）３，并且不参与稀土配位，系列稀土离子配合物的结构性质基本相同，在５０℃，ｐＨ值为６的水溶液中，该配合物选择性地催化５’－ＡＭＰ或５‘－ｄＡＭＰ的磷酯键水解断裂、生成相应的核苷和磷酸，而不影响碱基与戌糖之间的苷键。     

RESEARCH ON CATALYSTS OF ANTI-CARBON DEPOSITION FOR CH_4 REFORMING WITH CO_2

IntroductionMethaneandcarbondioxidearetWomaincompositionsforthegreenhouseeffectandtheworldglobewanningll].ItisbeneficialtoourlivingenviroIUnenttocontrolthereleaseofthesetwogases.Theconversionofmethanetothecommonfeedstocksynthesisgas(carbonmonoxideandhydro…     

α-异丙基、β-异丁基丙烯酸希土配合物的合成和配位性质研究

本文制备了α-异丙基、β-异丁基丙烯酸的15种希土配合物RE(C₉H₁₇COO)₃,用X射线多晶粉末衍射、电子光谱、红外光谱和热重差热分析方法研究了配合物中RE-O键的成键性能以及羧基的配位性质.配合物中存在两种不同的羧基配位形式,轻中希土配合物(La,Ce,Pr,Nd,Sm,Eu)中羧基具有不对称桥式双齿配位形式,而重希土配合物(Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y)中羧基具有对称螯合双齿配位形式,配位形式的不同使得希土配合物呈现两种不同的多晶衍射图和热分解过程.     

稀土乙酰丙氨酸咪唑配合物的合成及光谱性质

稀土元素由于特殊的外层电子构型,在与不同类型配体配位时,呈现出丰富多彩的配位行为和结构,其配合物,特别是有机配合物,由于具有发光性强、选择性好的特点,在发光、激光材料创制、结构探针、荧光免疫分析及生物传感器等领域的研究和应用引起广泛关注.氨基酸、肽是各种生物大分子的基本组成单元,咪唑存在于组氨酸、羧肽酶、血红蛋白等生物分子中参与配位或"变构效应"成为活性部位结构,唑环有丰富的能级,其作为含N富电子体系可与稀土离子形成既有生物活性,又有优良光学性能的配合物.     

Crystallographic evidence of hexacoordination at phosphorus via intramolecular coordination of donor groups on phosphane and phosphane sulphide

The X-ray structure analysis of bis(8-dimethylamino-l-naphthyl)phenylphosphane (3) and of the corresponding sulphide 4 has revealed hexacoordination at phosphorus in both cases, the N … P separations being less than the sum of the van der Waal radii. Furthermore, in both cases the overall geometry corresponds to a distorted bicapped tetrahedron. The optimum geometry calculated for 4 via the program developed by Autodesk (MM + method) suggests that the structure of the molecule is a function not only of steric requirements but also of electronic effects.