全文获取类型
收费全文 | 8028篇 |
免费 | 1234篇 |
国内免费 | 672篇 |
专业分类
化学 | 4161篇 |
晶体学 | 1167篇 |
力学 | 485篇 |
综合类 | 114篇 |
数学 | 1576篇 |
物理学 | 2431篇 |
出版年
2024年 | 8篇 |
2023年 | 77篇 |
2022年 | 206篇 |
2021年 | 259篇 |
2020年 | 310篇 |
2019年 | 232篇 |
2018年 | 161篇 |
2017年 | 232篇 |
2016年 | 378篇 |
2015年 | 312篇 |
2014年 | 484篇 |
2013年 | 608篇 |
2012年 | 461篇 |
2011年 | 591篇 |
2010年 | 534篇 |
2009年 | 517篇 |
2008年 | 543篇 |
2007年 | 557篇 |
2006年 | 523篇 |
2005年 | 430篇 |
2004年 | 399篇 |
2003年 | 324篇 |
2002年 | 250篇 |
2001年 | 188篇 |
2000年 | 219篇 |
1999年 | 165篇 |
1998年 | 157篇 |
1997年 | 151篇 |
1996年 | 104篇 |
1995年 | 76篇 |
1994年 | 89篇 |
1993年 | 62篇 |
1992年 | 52篇 |
1991年 | 55篇 |
1990年 | 37篇 |
1989年 | 33篇 |
1988年 | 33篇 |
1987年 | 27篇 |
1986年 | 16篇 |
1985年 | 20篇 |
1984年 | 16篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1973年 | 2篇 |
1959年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有9934条查询结果,搜索用时 15 毫秒
931.
外来种喜旱莲子草的克隆生长特性 总被引:2,自引:0,他引:2
通过对外来种喜旱莲子草(Alternanthera philoxeroides(Mart.)Griseb)生长指标的测定和分析,研究了它的克隆生长规律,并探讨丁它的觅食行为.在一个生长季节内,喜旱莲子草生物量增加了近30倍,一级葡萄茎分株数增加了近50倍,最长的一级葡萄茎长度增长了近40倍,一级葡萄茎总长度增长了近13倍;一、二、三级葡萄茎上的总分株数增加了近130倍,3个级别匍匍苇总长度增长了近28倍.通过各级葡萄茎个数,葡萄茎总长度和葡萄茎总分株数比较发现,二级葡萄茎比一、二级葡萄苇生长的都要快,而一级葡萄茎的间隔物平均长度远远大于二级和三级葡萄茎.克隆植物的觅食行为与它的克隆生长紧密相连,从觅食行为来看,喜旱莲子草克隆构型随生长季节的变化说明了它对生长季节具有很强的适应性.这种快速克隆生长的特性和对生长季节的适应性有利于喜旱莲子成功入侵新的生境。 相似文献
932.
Densely grafted polyacrylic acids (d-PAAs) with overcrowded PAA side chains on the polyacrylate main chains were synthesized and characterized. Acryloyl poly(tert-butyl acrylate) macromonomer [M-P(tert-BA)] was prepared with a definite chain length (n=29) by atom-transfer radical polymerization (ATRP), then homopolymerization was carried out to produce densely grafted P(tert-BA)s with polyacrylate main chains of two different lengths (m=27 and 161). The two d-PAAs were obtained by hydrolyzing d-P(tert-BA)s in the presence of trifluoroacetic acid (TFA). The d-PAAs exhibit intermolecular and intramolecular hydrogen bonding between the carboxylic groups of PAA side chains in dioxane and pyridine; both were investigated using proton nuclear magnetic resonance (1H NMR) spectroscopy. The intermolecular hydrogen bonding was found to be dependent on polymer concentration, temperature, and water content. The intramolecular association between the PAA side chains was found to produce a contraction of the hydrodynamic volume of the d-PAA. Intermolecular hydrogen bonding produces aggregates, as demonstrated by dynamic light scattering (DLS). The clusters were found to shrink as the overall water concentration decreased, and this effect is tentatively explained by considering the gradient in chemical potential of water inside the clusters in comparison with the solvent phase. 相似文献
933.
934.
Peter Apostoli 《Mathematical Logic Quarterly》1996,42(1):175-190
This paper articulates the structure of a two species of weakly aggregative necessity in a common idiom, neighbourhood semantics, using the notion of a k-filter of propositions. A k-filter on a non-empty set I is a collection of subsets of I which (i) contains I, (ii) is closed under supersets on I, and (iii) contains ∪{Xi ≤ Xj : 0 ≤ i < j ≤ k} whenever it contains the subsets X0,…, Xk. The mathematical content of the proof that weakly aggregative modal logic is complete relative to k-ary frame theory, the standard semantic idiom for weakly aggregative modal logic (see [1]) is presented in language-independent terms as a representation theorem for k-filters: every non-trivial k-filter is included in the union of ≤ k non-trivial filters. The elementary theory of k-filters is developed and then applied in the form of an ultrafilter extension result for k-ary frame theory. Mathematics Subject Classification: 03B45. 相似文献
935.
A three-dimensional computer simulation has been used to predict crystallization kinetics and crystalline morphology in composite materials that are based on crystallizable thermoplastics. Reinforcing fibers in three-dimensional simulations show similar behavior to those in two-dimensional simulations; fibers suppress crystallization relative to an unreinforced polymer since they constrain spherulitic growth by an impingement mechanism, and also enhance crystallization by providing added surface nucleation sites. The effects of varying controlling parameters on crystallization kinetics and morphology are qualitatively the same as those observed in the two-dimensional case. The relative bulk and fiber nucleation denisities, in addition to the fiber volume fraction, fiber diameter, and spherulitic growth rate control the crystallization kinetics and crystalline morphology that develop in reinforced thermoplastic composites. It is more difficult to achieve the transcrystalline morphology in slices of three-dimensional composites than it is in two-dimensional composites because nuclei in 3-D systems are not constrained to positions in or near a 2-D plane. © 1993 John Wiley & Sons, Inc. 相似文献
936.
The 7Li and 39K NMR relaxations in a LiKSO4 single crystal grown by the slow evaporation method were investigated by employing a pulse NMR spectrometer. From the experimental data, the quadrupole coupling constant and asymmetry parameter were determined at the temperatures of 180 and 300 K. The relaxation processes of 7Li and 39K were studied for the LiKSO4 crystal, and the relaxation times for the 7Li and 39K nuclei exhibit remarkable changes near Tc2 (=190 K). The activation energies for 7Li and 39K were determined in phases I and III. The large change in the activation energy at 190 K indicates that the Li and K ions are significantly affected during this transition. The correlation time of the 7Li calculated from the spin-lattice relaxation time and quadrupole parameters was larger than that of the 39K calculated using the same method. The reason for this is that the Li ion undergoes molecular motion as in the LiO4 groups. 相似文献
937.
Summary β-Cyclodextrin sulfate having heparin-mimicking activity was immobilized on a hydrophilic vinyl-polymer gel, TSKgel AF-Epoxy,
TOYOPEARL 650M. A column packed with this material could be used for high-performance affinity chromatographic separation
of heparin-binding substances such as growth factors, enzymes, coagulation factors and lipoproteins. The substances retained
on the column were recovered more easily than those on a heparin-immobilized column. Furthermore, the β-Cyclodextin sulfate-immobilized
gel was superior in stability to the heparin-immobilized gel when exposed to acidic and basic solutions. 相似文献
938.
Molecular Control of Bioactivity in Sol-Gel Glasses 总被引:2,自引:0,他引:2
Hench Larry L. Wheeler Donna L. Greenspan David C. 《Journal of Sol-Gel Science and Technology》1998,13(1-3):245-250
Bioactive materials can be divided into: Class A bioactive glasses which exhibit rapid bonding to bone and soft connective tissue and are osteoproductive, and osteoconductive; and Class B bioactive ceramics, which bond slowly only to bone and are only osteoconductive. Bioactive sol-gel glasses composed of SiO2-CaO-P2O5 have Class A behavior in vitro and in vivo and also resorb as they enhance the proliferation of new trabecular bone. 相似文献
939.
Zhiyuan Tian Yazhou Zhang Yanli Zhang Aidong Peng Ying Ma Yu Chen Wensheng Yang Yalin Tang Jiannian Yao 《Journal of nanoparticle research》2006,8(1):65-77
Nanostructures with well-defined shape and highly monodisperse size were fabricated from model stilbazolium-like dyes with specific molecular structural and conformational characteristics. With the help of absorption and fluorescence optical spectroscopy, the correlated spectroscopy (COSY) and two- dimensional nuclear Overhauser effect spectroscopy (2D NOESY) techniques, along with X-ray diffraction (XRD) measurement, distinctively different aggregation processes of the model molecules are demonstrated. For model dye molecule with linear donor–π system–acceptor (D–π–A) structure, strong D–A pair, and planar conformation, specific intermolecular interaction was identified and special crystal structures as well as spectral properties were observed. For model dye molecules bearing nonlinear D–π–A–π–D structure, weak D–A pair but actual amphiphilic characteristics, a special aggregation process was confirmed and a focused size distribution of the produced nanostructures was obtained. 相似文献
940.
Let A be a complex n × n matrix, and let A = B + iC, B = B*, C = C* be its Toeplitz decomposition. Then A is said to be (strictly) accretive if B > 0 and (strictly) dissipative if C > 0. We study the properties of matrices that satisfy both these conditions, in other words, of accretive-dissipative matrices. In many respects, these matrices behave as numbers in the first quadrant of the complex plane. Some other properties are natural extensions of the corresponding properties of Hermitian positive-definite matrices.__________Translated from Matematicheskie Zametki, vol. 77, no. 6, 2005, pp. 832–843.Original Russian Text Copyright ©2005 by A. George, Kh. D. Ikramov. 相似文献