Base dependent pyrrolidine ring pucker in aep-PNA monomers: NMR and PSEUROT analysis

The aep-PNA is a chiral and cyclic PNA analogue, which has a stronger and base dependent binding affinity with complementary DNA. To understand the base dependent properties at monomer level, the structural studies of aep-PNA-(T/C/A) monomers have been carried out focussing on the conformational analysis of pyrrolidine ring pucker in aep-PNA by ¹H NMR and the coupling constant data fitted into PSEUROT software. The results indicate that the type of pyrrolidine pucker depends on the electronic nature of substituent, implying the effect of pyrimidine or purine substituents in determining the ring pucker in monomers. This may consequently influence the aep-PNA oligomer conformation. Since pyrrolidine nucleic acids have emerged as an important class of PNA analogues, present results may have importance for their future development.     

A modification to the Peng–Robinson-fitted equation of state for pure substances

In this work we present two modifications to the Peng–Robinson-Fitted equation of state where pure component parameters are regressed to vapor pressure and saturated liquid density data. The first modification (PR-f-mod) is a method that enhances the equation of state pure component property predictions through simple temperature dependent pure component parameters. In the second modification (PR-f-prop) we propose a temperature dependency for co-volume b in the repulsive parameter of the EoS, and revise the temperature function in the attractive term. The agreement with experimental data for 72 pure substances, including highly polar compounds, is remarkably good. We obtain average absolute deviations in saturated liquid density of less than 1% for all substances studied.     

Comparison of steady and transient optical responses between a four-level Tripod system and a three-level Lambda system

We study and compare the steady and transient optical responses of a four-level system and a three-level system, which are dressed by two and three laser fields, respectively. In the three-level system, a transmissivity window (a reflectivity platform) may be induced on the probe resonance by a traveling-wave (standing-wave) coupling field. In the four-level system, both transmissivity window and reflectivity platform are remarkably modified when a traveling-wave driving field is applied on two-photon resonance with the probe, but change little when the traveling-wave driving field is largely two-photon detuned. This implies that the four-level system can be safely treated as a three-level one in certain frequency regions of interest. Transient behaviors of atomic coherence on the probe resonance are also examined in both three-level and four-level systems to further confirm this conclusion. Our new findings are beneficial to achieve a novel all-optical routing scheme by simultaneously creating a transmissivity window and a reflectivity platform on a single resonance, and may also be used to simplify theoretical treatments in the situations where numerical calculations are complicated and intractable in the presence of at least one standing-wave field.     

Two- and three-dimensional restricted geometry case of luminescence quenching

We present general analytical expression for two and three-dimensional cases of static energy transfer kinetics in doped nanoparticles (of round, spherical and cylindrical shape). A series of numerical experiments has been performed using Monte-Carlo simulation. The analytical expressions have shown very good coincidence with the computer simulation.     

Optical Properties of Model Moderately Coupled Plasmas

We review our approach to the modelling of optical properties of model moderately coupled plasmas. On the basis of the classical theory of moments the external and internal dynamic conductivities and the reflectivity coefficient of a model hydrogen moderately coupled plasma are determined using all known exact relations and sum rules. The sum rules which are the power frequency moments of the loss function are calculated using the Deutsch effective potential and the hypernetted chain equations. MD simulation data are used and numerical simulations are suggested (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

透光脉动检测仪研究碱度对絮体形成、破碎及再生的影响

为了解碱度对絮体的形成、破碎及再生过程的影响,采用PDA2000型透光脉动检测仪测定不同碱度下投加硫酸铝时高岭土悬浮液的絮凝指数(FI指数),并以强度因子和再生因子评价絮体的强度和再生能力。结果表明,碱度的高低在很大程度上会影响絮体的形成、破碎及再生过程,所形成絮体的颗粒随碱度的增加而减小。混凝剂投量和碱度高低共同决定了絮体的抗破碎强度,碱度越高,混凝剂投量越大,絮体的强度越高。在电中和作用下形成的絮体在低碱度下经一次破碎后恢复程度接近100%,在网捕卷扫作用下形成的絮体,无论碱度高低,从第2次破碎起,FI指数均以大于10%的幅度逐次下降,絮体不可恢复程度显著增大。     

温差电技术原理及在工科物理实验中的应用

简要介绍温差电技术的基本原理以及运用该原理设计、制作一些在工科物理实验中的装置。     

Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.