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161.
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为了提高大口径光学元件子孔径拼接测量的检测精度,提出一种平面绝对测量技术,修正子孔径拼接过程中产生的系统误差。利用改进的三面互检法获得参考平面的面形数据,采用这些测量数据构建基于Zernike多项式的参考面面形误差修正波面,在拼接过程中运用误差修正波面对获得的子孔径测量数据进行实时修正,并与全口径直接测量结果进行对比,结果PV(peak value,PV,峰谷值)误差从0.072 1 减少到0.028 6 。结果表明该方法有效减少了参考平面系统误差对拼接测量精度的影响,提高了大口径光学元件的检测精度。 相似文献
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在微扰理论的基础上导出高斯光束相位归一化频谱的普遍表达式,进而法庭是归一化光束抖动频谱的普遍表达式以及准直光束和球面波光束在均匀光路条件下的分析表达式,计算表明这些频谱中存在一个与湍流外尺度,横截风速有确定关系的峰值频率。 相似文献
165.
Yan J Kline AD Mo H Shapiro MJ Zartler ER 《Magnetic resonance in chemistry : MRC》2004,42(11):962-967
A novel methodology using the order matrix calculation to determine the absolute sign of spin-spin couplings based on the structure of organic compounds is presented. The sign of the residual dipolar coupling (RDC) depends on the sign of corresponding scalar spin-spin coupling constant and the sign of the RDC has a dramatic influence on the order matrix calculation. Therefore, the sign of the spin-spin coupling constant can be obtained by an order matrix calculation through the corresponding RDC. Six types of spin-spin coupling constants, including 2J(H,H), 1J(C,F), 2J(C,F), 3J(C,F), 2J(F,H) and 3J(F,H), were obtained simultaneously. Except for 3J(C,F) where the measured RDCs have very small magnitudes, the signs were determined unambiguously. 相似文献
166.
Oleg Burdakov Anders Grimvall Oleg Sysoev 《计算数学(英文版)》2006,24(6):771-790
Monotonic regression (MR) is a least distance problem with monotonicity constraints induced by a partiaily ordered data set of observations. In our recent publication [In Ser. Nonconvex Optimization and Its Applications, Springer-Verlag, (2006) 83, pp. 25-33], the Pool-Adjazent-Violators algorithm (PAV) was generalized from completely to partially ordered data sets (posets). The new algorithm, called CPAV, is characterized by the very low computational complexity, which is of second order in the number of observations. It treats the observations in a consecutive order, and it can follow any arbitrarily chosen topological order of the poset of observations. The CPAV algorithm produces a sufficiently accurate solution to the MR problem, but the accuracy depends on the chosen topological order. Here we prove that there exists a topological order for which the resulted CPAV solution is optimal. Furthermore, we present results of extensive numerical experiments, from which we draw conclusions about the most and the least preferable topological orders. 相似文献
167.
We have performed the direct measurements of 13C magnetic shielding for pure liquid TMS, solution of 1% TMS in CDCl3 and solid fullerene. The measurements were carried out in spherical ampoules exploring the relation between the resonance frequencies, shielding constants and magnetic moments of 13C and 3He nuclei. Next the 13C shielding constants of glycine, hexamethylbenzene and adamantane were established on the basis of appropriate chemical shifts measured in the solid state. All the new results are free from susceptibility effects and can be recommended as the reference standards of 13C shielding scale in the magic angle spinning NMR experiments. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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Shamsuddeen A. Haladu Shaikh A. Ali 《Journal of polymer science. Part A, Polymer chemistry》2013,51(23):5130-5142
A new zwitterionic monomer 3‐[diallyl{3‐(diethoxyphosphoryl)propyl}ammonio]propane‐1‐sulfonate has been synthesized and cyclopolymerized to give the corresponding polyzwitterion (±) (PZ) bearing both phosphonate and sulfonate functionalities on each repeating unit. phosphonate ester hydrolysis in PZ gave a pH‐responsive dibasic polyzwitterionic acid (±) (PZA) bearing ? PO3H2 units. The PZA under pH‐induced transformation was converted into polyzwitterion/anion (± ?) (PZAN) and polyzwitterion/dianion (± =) (PZDAN) having respective ? PO3H? and ? PO32? units. The polymers′ interesting solubility and viscosity behaviors have been investigated in detail. The apparent protonation constants in salt‐free water and 0.1 M NaCl of the ? PO32? in (± =) (PZDAN) and ? PO3H– in (± ?) (PZAN) as well as in their corresponding monomeric units have been determined. Evaluation of antiscaling properties of the PZA using supersaturated solution of CaSO4 revealed ≈100% scale inhibition efficiency at a meager concentration of 20 ppm for a duration of 45 h at 40 °C. The PZA has the potential to be used effectively as an antiscalant in reverse osmosis plant. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 5130–5142 相似文献
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