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991.
对溶胶-凝胶技术在制备电化学和生物传感器中的应用近况(涉及年份主要在1992-2006年间)作了评述,内容主要集中在应用此技术包埋某些电化学活性物质或生物化学活性分子于其中而制备相关传感器的方法及其原理,在制备传感器过程中的影响因素以及此类传感器的分析应用。此外,对其发展趋势也作了简单的讨论(引用参考文献51篇)。 相似文献
992.
食品中化学性有害物是导致食品安全问题的重要原因,质谱是对食品中化学性有害物进行定性定量分析的有效方法。该文按照化合物结构类别,综述了食品中重要化学性有害物的质谱软电离裂解机理,包括农药、兽药、真菌毒素,以及其他化学污染物。对于每类化合物,重点综述化合物质谱裂解产生的特征碎片、中性丢失等,以及这些质谱软电离裂解机理在食品中化学性有害物筛查及发现中的应用。研究化合物的质谱裂解机理可以帮助研究者对化合物进行结构解析和结构确证,为食品中同类结构新型化学性有害物的发掘提供理论依据。 相似文献
993.
《Arabian Journal of Chemistry》2022,15(7):103933
In this study, a fingerprint-activity relationship modeling between chemical fingerprints and antirheumatic activity was established, and multivariate statistical analysis was used to evaluate the quality of Taxilli Herba (TH) from different hosts. Characteristic fingerprints of 20 batches of TH samples were generated by high-performance liquid chromatography coupled with triple quadrupole-time of flight tandem mass spectrometry (HPLC-Triple TOF-MS/MS), and the similarity analysis was calculated based on thirteen common characteristic peaks by hierarchical clustering analysis (HCA). Subsequently, nine efficacy markers were discovered by combining fingerprints and antirheumatic activity through grey correlation analysis (GCA) and bivariate correlation analysis (BCA). Meanwhile, the content of 5 constituents in 9 markers was determined by high-performance liquid chromatography coupled with triple quadrupole-linear ion trap tandem mass spectrometry (HPLC-QTRAP-MS/MS). The comprehensive quality of TH was assessed using multivariate statistical analysis, including principal components analysis (PCA) and technique for order preference by similarity to ideal solution (TOPSIS). The results showed that a high dose of TH extract could markedly ameliorate arthritis damage compared to other doses, with flavonoids playing an important role in the antirheumatic activity. The comprehensive quality of samples from Morus alba L. (SS) was superior to those from Liquidambar formosana Hance (FXS). The present study will demonstrate the markers associated with efficacy, and provide an applicable strategy for more comprehensive quality control and evaluation of TH. 相似文献
994.
以分子末端带有多官能度活泼端基的PAMAM等为原料 ,通过缩聚反应制备了一类新型体型缩聚物 .借助X射线光电子能谱仪 (XPS)对制备的体型缩聚物进行分析 ,利用其化学分析电子光谱 (ESCA)中碳元素价态的拟合数据判断体型缩聚反应进行的程度 ,数据表明酯基碳 (—COO)拟合峰已基本消失 ,说明其与氨基缩合反应转化为酰胺基 (—CON) ,且反应进行的比较彻底 .通过体型缩聚物在乙醇、正己烷、甲苯、氯仿、异丙醇、乙酸、甲酸、去离子水中进行溶胀试验 ,发现其在甲酸作为溶剂体系中的溶胀比出现最大值 ,根据溶度参数的意义估测体型缩聚物的溶度参数约为δ2 =2 7 6 (MJ m3) 1 2 (即甲酸的溶度参数 ) .对原料PAMAM以及制备的体型缩聚物进行DSC分析 ,发现制备体型缩聚物的玻璃化转变温度 (Tg)有了较大提高 ,从初始原料PAMAM的负值提高到 4 8℃左右 . 相似文献
995.
Elhabiri M Siri O Sornosa-Tent A Albrecht-Gary AM Braunstein P 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(1):134-141
We present a detailed study on the acid-base behaviour of a family of "potentially antiaromatic" p-benzoquinonediimine ligands. These 12pi electron molecules can be considered as constituted of two chemically connected but electronically not conjugated 6pi-electron subunits. Upon successive protonation, "mono" and "double" cyanine-type chromophores are generated in solution and allow a precise and sensitive spectrophotometric detection. These molecules represent a new class of tunable quinones whose electronic and structural properties can be triggered by proton input, as established by a complete physico-chemical study involving a combination of potentiometric and spectrophotometric methods (absorption and emission). 相似文献
996.
用重复卷积法求解物理宽化函数吴万国,林嘉 (福州大学中心实验室,福州350002)(中国(福建)对外贸易中心集团,福州350001)关键词X射线衍射,晶粒度,晶格畸变,重复卷积粉末试样的X射线衍射谱线一般具有一定的宽度,引起话线宽化的主要原因有仪器致... 相似文献
997.
Morin N. Chilouet A. Millet J. Rouland J.-C. 《Journal of Thermal Analysis and Calorimetry》2000,62(1):187-201
The complexation of bifonazole, an antimycotic hydrophobic imidazole derivative, with β-cyclodextrin (β-CD) was investigated
in solid phase, using the following complementary techniques: differential scanning calorimetry (DSC), thermogravimetric analysis
(TG) and X-ray powder diffractometry. The β-CD-bifonazole samples were prepared in both aqueous medium by coprecipitation
and in solid state by kneading method and the β-CD-bifonazole binary diagrams were drawn. The experimental results demonstrate
the formation of two binary compounds, β-CD-bifonazole and (β-CD)x bifonazole (x =2 or 4). The first compound may be an inclusion compound and the second a crystallized compound, in which the bifonazole
is not necessarily included in the cyclodextrin internal cavity.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
998.
V. V. Dotsenko S. G. Krivokolysko E. B. Rusanov V. P. Litvinov 《Russian Chemical Bulletin》2007,56(7):1437-1440
Reactions of 6-aryl-5-cyano-4-oxo-2-thioxo-1,2,3,4-tetrahydropyrimidines with formaldehyde and primary amines gave earlier
unknown 3,4-dihydro-2H,6H-pyrimido[2,1-b]-[1,3,5]thiadiazine derivatives in 58–94% yields. In boiling AcOH, these pyrimidothiadiazines underwent the retro-Mannich
reaction leading to the starting pyrimidine-2-thiones. The structure of 3-(4-ethoxyphenyl)-6-oxo-8-phenyl-3,4-dihydro-2H,6H-pyrimido[2,1-b][1,3,5]thiadiazine-7-carbonitrile was studied by X-ray diffraction analysis.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1384–1387, July, 2007. 相似文献
999.
Tatjana Topalovic Vincent A. Nierstrasz Lorenzo Bautista Dragan Jocic Antonio Navarro Marijn M. C. G. Warmoeskerken 《Cellulose (London, England)》2007,14(4):385-400
Hydrogen peroxide can be catalyzed to bleach cotton fibers at temperatures as low as 30°C by incorporating dinuclear tri-μ-oxo
bridged manganese(IV) complex of the ligand 1,4,7-trimethyl-1,4,7-triazacyclononane (MnTACN) as the catalyst in the bleaching
solution. The catalytic system was found to be more selective under the conditions applied than the non-catalytic H2O2 system, showing better bleaching performance while causing slightly lower decrease in degree of polymerization (DP) of cellulose.
In order to gain fundamental knowledge of the bleach effect on cotton fibers and cellulose as its main component, especially
after catalytic bleaching, X-ray Photoelectron Spectroscopy (XPS) was used to study surface chemical effects. The Washburn
method was applied to investigate wetting properties, and liquid porosity was used to obtain pore volume distribution (PVD)
plots. Parallel analyzes performed on model cotton fabric, i.e. “clean” cotton fabric stained with morin - a pigment regularly
found in native cotton fiber, helped to differentiate between pigment oxidation and other bleaching effects produced on the
(regular) industrially scoured cotton fabric. Bleaching was not limited to the chemical action but also affected cotton fiber
capillary parameters most likely due to the removal of non-cellulosic materials as well as chain-shortened cellulose. 相似文献
1000.
We show that the mono-N-methylated and -ethylated derivatives of the achiral compound bisguanidinobenzene undergo spontaneous asymmetric crystallization into a chiral form with chiral space group P212121. The absolute configurations of the chiral crystals were determined by X-ray crystallography and correlated with circular dichroism (CD) spectra recorded in the solid state. The corresponding protonated and isopropylated derivatives, by contrast, afforded achiral crystals. 相似文献