高频调制大功率窄线宽分布反馈光纤激光器

研制了一种窄线宽光纤激光器.在有源相移光栅后加一段掺铒光纤,当用980 nm抽运光注入时,首先形成了分布反馈(DFB)光纤激光器,而残余抽运光将铒纤中铒离子从基态抽运到了激发态,对DFB激光实现了有效放大,实现了对残余抽运光的充分利用,节省了功耗、降低了成本;同时利用温控技术克服了DFB光纤激光器的温度敏感问题;将相移光栅黏贴于片状压电陶瓷(PZT)的表面实现了高频调制.实验研制的激光器的最高调制频率为2 kHz、输出功率为15.6 dBm,线宽为300 kHz. 关键词： 分布反馈光纤激光器 窄线宽 大功率 高频调制     

大气湍流对多抖动法相干合成技术中相位调制信号的影响

分析了大气湍流对采用多抖动法实现的相干合成阵列光束中相位调制信号的影响. 文章首先根据广义惠更斯-菲涅耳原理,采用折射率结构函数对大气湍流进行描述,推导了多抖动法相干合成中阵列光束通过大气湍流后相位调制信号的一般表达式. 在此基础上进行数值模拟,分析了传输距离、湍流强度、光束阵列占空比和光斑尺寸等因素对相位调制信号的影响. 研究发现随着传输距离的增大,相位调制信号强度会先增大后减小,存在一个极大值点;随着湍流强度的增强,相位调制信号强度极大值点的出现距离不断缩短;当光束阵列占空比一定时,随着光斑尺寸的增大 关键词： 大气湍流 相干合成 多抖动法 相位调制     

基于减反膜外腔反馈半导体激光器拉曼光的产生

通过直接对减反膜外腔反馈半导体激光器进行电流调制的方法,得到了两束位相锁定且频率差在6.0-9.3GHz范围内连续可调的激光,其中6.835和9.192GHz分别对应Rb⁸⁷和Cs¹³³原子基态超精细能级之间的频率差,激光功率分别可以达到6.87mW和5.09mW. 根据减反膜外腔反馈半导体激光器的特点,通过调整外腔腔长、激光器工作温度、电流以及所加射频调制信号的功率和频率,在调制频率小于等于4.0GHz时可以将载波完全压制. 调制频率大于4.0GHz时,虽不能将载波完全压制,但由于外腔与调制频率共振时对调制的增强也得到了调制深度很高的激光,并对其中的物理机理作了分析. 通过后续滤波等方法处理以后,该拉曼光源可以广泛应用到原子的量子操控中. 关键词： 受激拉曼光 高频调制 调制增强     

非标定波长调制吸收光谱气体测量研究

为消除可调谐激光调制吸收光谱气体测量技术对于标定过程的依赖,研究了二次谐波信号的非标定波长调制气体测量方法.通过对测量的二次谐波线型进行分析,给出相同工况下二次谐波模拟信号,并利用测量与模拟二次谐波信号进行线性拟合直接计算气体浓度.实验室内采用非标定波长调制气体测量方法,利用 6336.24 cm^-1处特征吸收谱线对10 cm长气体吸收池内的CO₂进行了测量.结果表明,非标定波长调制气体测量方法可适应各种不同条件,适合于现场气体在线测量.当调制系数在1.8—3. 关键词： 波长调制 二次谐波 吸收光谱 半导体激光器     

HPLC同时测定清胃黄连丸中的4种有效成分

建立同时测定清胃黄连丸中栀子苷、黄芩苷、小檗碱和巴马汀含量的HPLC方法。结果表明,栀子苷、黄芩苷、小檗碱和巴马汀分别在2.07—66.2μg/mL（r=0.9997）、2.72—86.9μg/mL（r=0.9998）、2.23—71.3μg/mL（r=0.9998）、2.13—68.1μg/mL（r=0.9998）范围内与峰面积呈良好的线性关系;平均回收率分别为103.2%（RSD=3.27%）、106.7%（RSD=2.46%）、103.5%（RSD=2.13%）、95.7%（RSD=2.68%）。该方法简便可行、重现性好、能更好的控制清胃黄连丸的质量。     

Extension of the cumulant definition for low particle number systems

Cumulants are usually interpreted as the connected components of density matrices, but this interpretation fails and practical problems arise when the rank n of cumulants is larger than the number of particles (N) in the system. In that case, cumulants defined in the traditional way become disconnected. To solve this problem, the definition of cumulants is extended by introducing a simple modulation factor. The modified cumulants reduce to the conventional definition, but they vanish when N < n. Using the modified definition also eliminates the error in the approximation of density matrices by low‐rank cumulants, when N < n. The problem assumes a slightly different form when we work with active space–based theories, and it can be solved by a similar approach. Another problem with cumulants, due to spin coupling [Herbert, Int J Quantum Chem 2007, 107, 703], can be solved via the introduction of a similar modulation factor. A related yet more serious issue, termed as the local particle number constraint problem, is also discussed. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011     

Development of a new consumable-free thermal modulator for comprehensive two-dimensional gas chromatography

A simple and cost-effective GC × GC modulator requiring no moving parts or consumables, hence suitable for field analysis and monitoring, was developed. The modulator was constructed from a specially designed Silcosteel^® trapping capillary, installed outside the GC oven, and coated inside with polydimethylsiloxane (PDMS) stationary phase. Dual-stage modulation was accomplished by resistively heating alternate segments of the trap with a custom-designed capacitive discharge power supply. The performance of the proposed modulator was comparable to many GC × GC systems currently in use, with the injection band widths as low as 60 ms at half height. With proper selection of the stationary phase in the trap, the modulator can be used for the analysis of complex mixtures with volatility range spanning from n-C5 to n-C40.     

Structural behavior and thermoelectric properties of the brownmillerite system Ca2(ZnxFe2−x)O5

The Ca₂(Zn_xFe_2−x)O₅ series was synthesized and characterized to determine the influence of zinc dopant on the brownmillerite structure for thermoelectric applications. All single-phase compounds exhibited Pnma symmetry at room temperature up to the solubility limit at x=0.10. High-temperature X-ray powder diffraction was used to show that the nature of the Pnma-Imma(0 0 γ)s00 transition in Ca₂Fe₂O₅ is modified by the presence of zinc. While the Zn-free composition transitions to an incommensurate phase, the Zn-containing phases transition instead to a commensurate phase, Imma(0 0 γ)s00 with γ=1/2. Both the Néel temperature and the onset temperature of the Pnma-Imma(0 0 γ)s00 phase transition decreased with increasing zinc concentration. Rietveld analysis of the in situ diffraction pattern for the x=0 sample at 1300 °C demonstrates that the structure contains statistically disordered chain orientations as described by space group Imma. Thermoelectric properties were analyzed in air from 100 to 800 °C. The positive Seebeck coefficient revealed hole-type conduction for all compositions. Doped samples exhibited electrical conductivities up to 3.4 S/cm and thermal conductivity of 1.5 W/mK. Transport analysis revealed thermally activated mobility consistent with polaron conduction behavior for all compositions.     

Surface chemistry of metal-organic frameworks at the liquid-solid interface

Metal-organic frameworks (MOFs) are a fascinating class of novel inorganic-organic hybrid materials. They are essentially based on classic coordination chemistry and hold much promise for unique applications ranging from gas storage and separation to chemical sensing, catalysis, and drug release. The evolution of the full innovative potential of MOFs, in particular for nanotechnology and device integration, however requires a fundamental understanding of the formation process of MOFs. Also necessary is the ability to control the growth of thin MOF films and the positioning of size- and shape-selected crystals as well as MOF heterostructures on a given surface in a well-defined and oriented fashion. MOFs are solid-state materials typically formed by solvothermal reactions and their crystallization from the liquid phase involves the surface chemistry of their building blocks. This Review brings together various key aspects of the surface chemistry of MOFs.     

Rapid detection of Rosa laevigata polysaccharide content by near-infrared spectroscopy

We have investigated surface-enhanced Raman spectroscopy (SERS) spectrum of Omethoate (O,O-dimethyl-S-methylcarbamoylmethylthiophosphate). It is found significant signals in the ordinary Raman spectrum for solid-state Omethoate as well as strong vibrational signals absorbed on the silver sol surface which is prepared by γ-irradiation technique at a very low concentration. Effects of pH and anions (Cl-, Br-, I-) on the adsorption orientation are investigated as well. Two different adsorption mechanisms are deduced, depending on the experimental conditions. The sulfur atom or the sulfur and two oxygen atoms are adsorbed onto the silver sol surface. Among halide ions, Br- and I- are more strongly adsorbed onto the silver sol surface. As a result, the adsorption of Omethoate is less effective due to their steric hindrance.