气固两相槽道湍流拟序结构变动的PIV测量

运用粒子成像测速仪(PIV)对壁面雷诺数为Re_τ=430、质量载荷为0.25×10~(-3)～5×10~(-3)的110μm聚乙烯颗粒加入前后的水平槽道湍流变动进行了研究。实验结果表明低载荷下气相湍流变动源于颗粒对湍流拟序结构的作用。颗粒的存在抑制了湍流拟序结构的发展,使得湍流准流向结构长度减小、猝发频率降低、猝发强度减弱;另外,颗粒尾涡脱落还导致了壁面附近的气相剪切雷诺应力增强。     

Mask相位法校准液晶空间光调制器的相位调制特性

提出Mask相位法校准出厂标定波长在532 nm的液晶空间光调制器(LC-SLM)在561 nm处的相位调制特性曲线.首先基于傅里叶光学模拟计算得出棋盘型二维相位光栅相位对比度与零级衍射光斑光强之间的对应关系,然后搭建实验光路测量计算机所发灰度图所对应的零级衍射光斑光强值.根据前面两组结果最后得到相位延迟量与计算机灰度...     

Active Electron Density Modulation of Co3O4‐Based Catalysts Enhances their Oxygen Evolution Performance

Despite the fact that many strategies have been developed to improve the efficiency of the oxygen evolution reaction (OER), the precise modulation of the surface electronic properties of catalysts to improve their catalytic activity is still challenging. Herein, we demonstrate that the surface active electron density of Co₃O₄ can be effectively regulated by an argon‐ion irradiation method. X‐ray photoelectron and synchrotron x‐ray absorption spectroscopy, UV photoelectron spectrometry, and DFT calculations show that the surface active electron density band center of Co₃O₄ has been upshifted, leading to a significantly enhanced absorption capability of the oxo group. The optimized Co₃O₄‐based catalysts exhibit an excellent overpotential of 260 mV at 10 mA cm^?2 and Tafel slope of 54 mV dec^?1, superior to the capability of the benchmark RuO₂, representing one of the best Co‐based OER catalysts. This approach could guide the future rational design and discovery of ideal electrocatalysts.     

A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba,Sr)

Structural modulations have been recently found to cause some unusual physical properties, such as superconductivity or charge density waves; however, thus‐induced nonlinear optical properties are rare. We report herein two unprecedented incommensurately modulated nonlinear optical sulfides exhibiting phase matching behavior, A₂SnS₅ (A=Ba, Sr), with the (3+1)D superspace groups P2₁2₁2(00γ)00s or P2₁(α0γ)0, featuring different modulations of the [Sn₂S₇]_∞ belts. Remarkably, Ba₂SnS₅ exhibits an excellent second harmonic generation (SHG) of 1.1 times that of the benchmark compound AgGaS₂ at 1570 nm and a very large laser‐induced damage threshold (LIDT) of 8×AgGaS₂. Theoretical studies revealed that the structural modulations increase the distortions of the Sn/S building units by about 44 or 25 % in A₂SnS₅ (A=Ba, Sr), respectively, and enhance significantly the SHG compared with α‐Ba₂SnSe₅ without modulation. Besides, despite the smaller E_g, the A₂SnS₅ samples exhibit higher LIDTs owing to their smaller thermal expansion anisotropies (Ba₂SnS₅ (1.51)<Sr₂SnS₅ (2.08)<AgGaS₂ (2.97)).     

Microfluidic Assisted Flash Precipitation of Photocrosslinkable Fluorescent Organic Nanoparticles for Fine Size Tuning and Enhanced Photoinduced Processes

Highly concentrated dispersions of fluorescent organic nanoparticles (FONs), broadly used for optical tracking, bioimaging and drug delivery monitoring, are obtained using a newly designed micromixer chamber involving high impacting flows. Fine size tuning and narrow size distributions are easily obtained by varying independently the flow rates of the injected fluids and the concentration of the dye stock solution. The flash nanoprecipitation process employed herein is successfully applied to the fabrication of bicomposite FONs designed to allow energy transfer. Considerable enhancement of the emission signal of the energy acceptors is promoted and its origin is found to result from polarity rather than steric effects. Finally, we exploit the high spatial confinement encountered in FONs and their ability to encapsulate hydrophobic photosensitizers to induce photocrosslinking. An increase in the photocrosslinked FON stiffness is evidenced by measuring the elastic modulus at the nanoscale using atomic force microscopy. These results pave the way toward the straightforward fabrication of multifunctional and mechanically photoswitchable FONs, opening novel opportunities in sensing, multimodal imaging, and theranostics.     

Efficient intensity modulation due to surface acoustic waves on windows of the AlGaN/InGaN multiple quantum well laser

An alternative method for modulation of light generated by AlGaN/InGaN multiple quantum well laser with quartz antireflective (AR) coatings covering the resonator windows was modelled and studied theoretically. Disturbance of the piezoelectric coatings caused by surface acoustic waves (SAW) results in efficient intensity modulation of the laser beam. The model for the laser diode operating at DC demonstrates that the modulation factor can exceed 0.2 in sub-nanometer SAW displacement. For quarter-wave AR films, the carrier frequency of modulated beam has twice the frequency of SAW.     

位相型全息记录介质的浮雕深度和折射率变化的测量方法

本文提出了一种直接测量位相型全息记录介质的浮雕深度和折射率改变量的方法，它利用干涉显微镜及带ＣＣＤ摄像头的微机组成的简单系统，可获得很高的测量精度。本文分析了测量误差以及为使系统保持最高测量精度而应选取的最佳测量条件。     

The optimal design for weak optical feedback semiconductor laser with frequency modulation

In this paper the frequency modulation characteristics the semiconductor laserwith weak optical feedback are presented,considering both the frequency deviation and thespurious intensity modulation.The frequency modulation can be realized without spurious in-tensity modulation under proper feedback conditions.There is an optimal feedback intensity tomaximize the frequency deviation.     

加速器电子枪控制器的设计及其远程光纤通讯的实现

 介绍了合肥国家同步辐射实验室200 MeV电子直线加速器新型脉冲电子枪控制器的工作原理，以及I²C总线和嵌入式微控制器在电子枪控制器中的应用，详细分析了加热灯丝的数控电流源、引出电子束的数控电压源和脉冲电压源等模块的硬件实现，并给出了光纤通讯和后端微机控制软件的设计过程。该电子枪已成功应用于加速器的实际运行中，性能稳定，工作可靠，完全替代了以前的机械控制方式。     

用智能波长校正的扫描式ICP光谱仪测定铬铁矿中六种元素成分

本文利用作者所在实研究室开发的扫描式ＩＣＰ光谱仪的智能波长校正装置取代传统的ＩＣＰ光谱仪的局部恒温系统，测定了铬铁矿及铬酸盐中的Ｃｒ，Ｓｉ，Ａｌ，Ｆｅ，Ｍｎ和Ｍｇ六种元素成分。测定结果与铬矿标样的鉴定值基本一致，测量的相对标准偏差（ＲＳＤ）为１．０％，智能波和工校正装置的波长校正结果与谱线峰值描迹结果的比较表明，该智能波长校正装置是有效的，具有省时，安全，结构简单的特点，有广泛的应用的前景。