IM－DD SCM光波系统的非线性分析

本文在简要分析了激光器非线性机理的基础上,采用计算机模拟及数学归纳的方法,着重分析了IM-DDSCM光纤通信系统中各种非线性失真项的数目、幅度及其抑制方法,归纳出了落入各个信道中的各种非线性失真项的数目的数学表达式,推导出了非线性失真项的功率之和的计算公式;通过对计算结果的比较得知,激光器P-I曲线的非线性是影响系统非线性失真的主要因素,指出了利用预失真的方法补偿激光器P-I曲线非线性的影响。     

菱面片层氧化镁的制备及晶格畸变与反常红外特性

以低品位白云石为原料采用二次酸浸、EDTA-氨水沉淀法制备前驱体Mg（OH）2，经煅烧得到菱面片层状多空隙结构的纳米MgO晶体。通过X射线衍射（XRD）、高分辨率扫描电镜（HRSEM）及傅立叶红外光谱（FT—IR）等测试手段对所得产物的物相和形貌等进行了表征。分析表明：氧化镁为结晶良好、立方晶系，厚度约10～20nm，最大面积可达1μm^2左右的菱形纳米片层结构；XRD数据表明纳米氧化镁的微结构存在晶格畸变并导致XRD相位差发生变化；红外光谱表明，Mg-O键伸缩特征吸收峰向高波数方向移动（蓝移）了约84．82cm^-1，而弯曲特征吸收峰向低波数方向移动（红移）了约31．88cm^-1，并导致红外吸收光谱的宽频化。结合XRD数据分析结果和界面效应等物理现象讨论了反常红外吸收机理。     

X-ray diffraction line profile from the aggregate of distorted crystallites. II

An expression for the fourth moment of the line profile in terms of several strain derivatives and the possibility of measuring the ‘wavelength’ of crystal distortions (λ) for any sinusoidally varying component of the strain are available. The experimental means for evaluating such strain derivatives in the expression for the fourth moment was earlier described. A numerical method for evaluating this wavelength and its subsequent use to determineλ in several samples ofα-brass is presented here. The data used are taken from the earlier paper of the authors. An attempt has been made to interpret the values ofλ and their changes with cold working and annealing in terms of lattice strain.     

Earthquake曲线切向量上的范数

本文研究了定义在earthquake曲线切向量上的范数，首先证明了一条earthquake曲线ht上初始切向量的范数等价于earthquake测度σ的Thurston范数．其次证明了当t→∞时，ht的切向量Vt的范数增长渐近等于O(||→||The^Ct||σ||Th)，其中C是正的万有常数，||σ||Th是σ的Thurston范数，而O所代表的常数是渐近万有的，也即当t||σ||Th充分大时它是万有的．此外，附带证明了定义在Zygmund有界函数上的两种交比范数是等价的．     

Computer Aided Analysis of Nonlinear Distortion for Laser Diode under Intensity Modulation

1.IntroductionNonlineardistortionisanimportantindextoappreciateasubcarriermultiplexing(SCs)lightwavetransmissionsystem.Itconsistsofthedistortionoflaserdiode(LD)module,distortionoffiber--optictransmissionsystemandthatofreceiversystem,amongwhichLD'shasagreatinfluenceonsystem'scharacteristicsbecauseitisanonlineardeviceinitself.LDnonlineardistortioncomesfromP--Icharacreristicsandinteractionbetweenphotonsandelectrons.WhenLDworksatlineararea,theformercanbeneglectedandthelatteristhemain,whichisd…     

Spiral distortion of magnetic lenses with fields of the form B(z) ∝ z, n = 2, 3, 4

The spiral distortion of magnetic lenses with a field distribution in the form of an inverse power law has been studied. The spiral distortion coefficient can be evaluated explicitly in terms of Bessel function. For spherical field (B ∝ Z⁻³), which is useful for the study of single pole magnetic lens, the spiral distortion coefficient was analytically expressed.     

Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one‐dimensional coordination chains sustained by tris(3,4,5‐trimethyl‐1H‐pyrazole)copper(II)

Electronic distortions, which are inherent in the oxide fluoride anions [MOF₅]²⁻ (M = Nb and Ta), provide an origin of polar molecular arrangements for the development of new polar second‐harmonic‐generating, piezo‐, pyro‐ and ferroelectric materials. It is still a challenge to expand this approach to the realm of metal–organic polymers, while insufficient control over the environment of the [MOF₅]²⁻ units results in their orientational disorder and loss of polarity. The structures of catena‐poly[[tris(3,4,5‐trimethyl‐1H‐pyrazole‐κN²)copper(II)]‐μ‐oxido‐[tetrafluoridoniobium(V)]‐μ‐fluorido], [CuNbF₅O(C₆H₁₀N₂)₃]_n, (I), and its isostructural pentafluoridooxidotantalate(V) analogue, catena‐poly[[tris(3,4,5‐trimethyl‐1H‐pyrazole‐κN²)copper(II)]‐μ‐oxido‐[tetrafluoridotantalum(V)]‐μ‐fluorido], [CuTaF₅O(C₆H₁₀N₂)₃]_n, (II), are the first examples of the strict orientational order of [MOF₅]²⁻ (M = Nb and Ta) in one‐dimensional coordination chains. A primary factor for the exact discrimination of one orientation of the anion over the other is strong and shape‐selective multiple interactions of [MOF₅]²⁻ with the inherently acentric CuL₃²⁺ platform, with a set of two coordination and three N—H…F hydrogen bonds. In (I) and (II), the Cu²⁺ ions exhibit distorted square‐pyramidal fivefold coordination formed by three pyrazole N atoms and the oxide O atom, defining the equatorial plane, and the anionic bridging F atom (which is trans with respect to the M—O bond) residing in the apical position. The inorganic bridges connect CuL₃²⁺ moieties into polar zigzag chains; the bulk polarity of the structure is eliminated by an antiparallel alignment of the individual chains. These chains are further connected through C—H…F hydrogen bonding and very weak C—H…π interactions of the organic ligands.     

A theoretical approach to the influence of the macrocycle conformation on the molecular electronic structure in Mg-porphyrins

Nonplanar saddled (sad) ruffled (ruf) and domed (dom) conformations of the Mg-porphyrin (MgP) macrocycle in several degrees of deformation have been computed. These symmetrical distortion modes were induced in unsubstituted macrocycle using molecular definitions for calculations which permits us to achieve a systematical variation of the nonplanarity varying only a convenient geometrical parameter of the molecule. Series of nonplanar macrocycles like those synthesized in previous works employing peripheral substitutions are obtained. The procedure here used to induce deformations gives the possibility of investigating the modulator role of the out-of-plane distortions on the geometry and electronic properties of the porphyrin avoiding additional influences due to the substituents or the surrounding protein scaffolding.     

Eu0.5RE0.5Fe0.5Mn0.5O3的57Fe Msosbauer谱研究

利用固相反应合成了Eu0.5RE0.5Fe0.5Mn0.5O3(RE=La,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Y)等化合物。测量了其XRD谱及57FeMssbauer谱。实验发现,随着RE原子序数的增加,样品的晶胞体积减小,Fe在化合物中处于Fe3+的高自旋状态,57Fe的四极裂矩与样品的畸变参数D成线性关系。     

Eu_（0．5）RE_（0．5）Fe_（0．5）Mn_（0．5）O_3的~（57）Fe Msosbauer谱研究

利用固相反应合成了Ｅｕ_（０．５）ＲＥ_（０．５）Ｆｅ_（０．５）Ｍｎ_（０．５）Ｏ_３（ＲＥ＝Ｌａ，Ｐｒ，Ｎｄ，Ｓｍ，Ｅｕ，Ｇｄ，Ｔｂ，Ｄｙ，Ｈｏ，Ｅｒ，Ｔｍ，Ｙｂ，Ｙ）等化合物。测量了其ＸＲＤ谱及~（５７）ＦｅＭｓｓｂａｕｅｒ谱．实验发现，随着ＲＥ原子序数的增加，样品的晶胞体积减小，Ｆｅ在化合物中处于Ｆｅ~（３＋）的高自旋状态，~（５７）Ｆｅ的四极裂矩与样品的畸变参数Ｄ成线性关系。