全文获取类型
收费全文 | 15077篇 |
免费 | 1472篇 |
国内免费 | 1007篇 |
专业分类
化学 | 10294篇 |
晶体学 | 74篇 |
力学 | 487篇 |
综合类 | 204篇 |
数学 | 918篇 |
物理学 | 5579篇 |
出版年
2024年 | 35篇 |
2023年 | 322篇 |
2022年 | 496篇 |
2021年 | 634篇 |
2020年 | 541篇 |
2019年 | 452篇 |
2018年 | 372篇 |
2017年 | 600篇 |
2016年 | 634篇 |
2015年 | 643篇 |
2014年 | 906篇 |
2013年 | 956篇 |
2012年 | 931篇 |
2011年 | 932篇 |
2010年 | 792篇 |
2009年 | 1006篇 |
2008年 | 907篇 |
2007年 | 915篇 |
2006年 | 780篇 |
2005年 | 780篇 |
2004年 | 683篇 |
2003年 | 444篇 |
2002年 | 347篇 |
2001年 | 262篇 |
2000年 | 257篇 |
1999年 | 237篇 |
1998年 | 215篇 |
1997年 | 220篇 |
1996年 | 202篇 |
1995年 | 162篇 |
1994年 | 102篇 |
1993年 | 107篇 |
1992年 | 91篇 |
1991年 | 59篇 |
1990年 | 82篇 |
1989年 | 73篇 |
1988年 | 70篇 |
1987年 | 63篇 |
1986年 | 37篇 |
1985年 | 43篇 |
1984年 | 28篇 |
1983年 | 22篇 |
1982年 | 43篇 |
1981年 | 23篇 |
1980年 | 9篇 |
1979年 | 15篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1974年 | 3篇 |
1973年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
This study demonstrates the separation of active ingredients in acne formulations (salicylic acid, cloramphenicol and resorcinol in presence of azulene) by capillary zone electrophoresis. Factors affecting their separations were the buffer pH and concentration, applied voltage, sample preparation, and presence of additives. Optimun results were obtained with a 50 mM sodium tetraborate-50 mM sodium phosphate, pH 9.0. The carrier electrolyte gave baseline separation with good resolution, short migration times (<6 min), great reproducibility and accuracy. Calibration plots were linear over at least three orders of magnitude of analyte concentrations, the lower limits of detection being within the range 0.39-1.25 μg ml−1. The procedure was fast and reliable and commercial pharmaceuticals could be analysed without prior sample clean-up procedure. 相似文献
92.
In this paper an automatic technique for handling discontinuous IVPs when they are solved by means of adaptive Runge–Kutta codes is proposed. This technique detects, accurately locates and passes the discontinuities in the solution of IVPs by using the information generated by the code along the numerical integration together with a continuous interpolant of the discrete solution. A remarkable feature is that it does not require additional information on the location of the discontinuities. Some numerical experiments are presented to illustrate the reliability and efficiency of the proposed algorithms. 相似文献
93.
采用淋洗液发生器阴离子交换-抑制电导检测法,同时分离和检测阿思巴甜、甜蜜素、安赛蜜和糖精4种常见的甜味剂.由于采用了淋洗液发生器,使背景电导大大降低,可以实现甜味剂的高灵敏度检测和分离.该方法具有良好的重现性、线性关系和较低的检测限.阿思巴甜、甜蜜素、安赛蜜和糖精的检测限分别是:1.27、0.045、0.033、0.063 mg/L;样品测定的回收率分别为99.7%、102.8%、98.6%、103.5%. 相似文献
94.
Frank Rutz Martin Koch Shilpa Khare Martin Moneke Heike Richter Uwe Ewert 《International Journal of Infrared and Millimeter Waves》2006,27(4):547-556
We report on experiments that evaluate the potential of terahertz (THz) time-domain spectroscopy (TDS) for quality control
of polymeric compounds. We investigate specimens out of a polyethylene compound with silver-coated titanium dioxide nanospheres
and a glass-fiber reinforced epoxy composite. We further examine an industrial polymer product produced by injection molding.
Our data demonstrates that THz imaging is a powerful tool for contactless quality control in the polymer industry. 相似文献
95.
An enantioselective Michael addition of malonate to nitroalkenes is efficiently catalyzed by low loading demethylquinine salts in water; the yield range from 49% to 93% and the ee up to 90%. 相似文献
96.
通过建立GM(1,1)模型,结合宁波市2005年对非公有制经济领域人才资源的抽样调查数据,对2006~2010年期间宁波市非公有制经济领域人才需求量和人才质量进行动态分析和预测. 相似文献
97.
Kimio Asaka Yoshihito Hirano Kenji Tatsumi Kumio Kasahara Toru Tajime 《Optical Review》1998,5(5):310-314
We propose a new detection method for a pseudo-random frequency modulation continuous wave (RM-CW) coherent lidar. The feature of this method is modulation of local beam with a time delayed pseudo-random sequence. Heterodyne detection and correlation detection between the received beam and the local beam are simultaneously carried out in an optical field. In the RM-CW coherent lidar using the optical field correlation detection method, the received equipment is greatly simplified. We carried out preliminary experiments and demonstrated that the new method is effective for detection of a CW coherent lidar. 相似文献
98.
This paper examines joint storage considerations when both commodities and resources can be stored, e.g., grain and water for irrigation. Results suggest that when separate agencies control public resource and commodity storage, suboptimal storage rules occur unless (i) each agency is sensitive to the policies of the other, (ii) commodity inventories are adjusted in response to prices, and (iii) resource inventories are adjusted in response to both commodity demand and resource supply conditions. For example, the common case where water storage depends on weather and reservoir conditions alone is not sufficiently general. The results imply that water management agencies that tend to be dominated by engineers and hydrological considerations need to incorporate economic considerations into decision processes. 相似文献
99.
The three-dimensional structure of the calcite (104)-water interface has been determined with surface X-ray scattering. Nine crystal truncation rods (including specular and non-specular rods) were measured providing both vertical and lateral sensitivity to the interfacial structure. The results reveal that calcite is nearly ideally terminated with a single surface hydration layer that includes two inequivalent water molecules having distinct heights of 2.3 ± 0.1 and 3.5 ± 0.2 Å, each with a well-defined lateral registry with respect to the calcite surface. No additional layering of water is observed beyond this surface hydration layer. Small displacements in the outer two calcium carbonate layers were also observed. These results are compared with previous experimental and computational results. 相似文献
100.
Doubly tunable sum frequency generation (SFG) spectra demonstrate that the water molecules at gold/electrolyte interface change their orientation with applied potential. At negative potentials, water molecules in the double layer align with their oxygen atom pointing to the solution. As potential became positive to be close to the potential of zero charge (PZC), the SFG signal decreased, suggesting the OH groups of the water molecule are either in random orientation or parallel to the electrode. As potential became more positive than the PZC, the SFG signal increased again with the oxygen-up orientation as same as in the negative potential region, indicating that water molecules interact with the adsorbed sulfate anions. The peak position of the SFG spectra indicates a relatively disordered state of water molecules at the gold electrode surface, in contrast to the previously observed ice-like structure of water at electrolyte/oxide interfaces. 相似文献