石墨-六角氮化硼微晶混合物与水高压反应产物分析

 利用球磨法制备石墨-六角氮化硼微晶混合物，并在6.1 GPa、800~1 500 ℃条件下与水进行高压反应，以便研究用水作触媒合成B-C-N三元化合物的可能性。通过对反应产物的XRD、XPS谱分析发现：高压下随着温度的升高，反应产物中出现再结晶石墨，其晶化程度逐渐提高；但没有出现再结晶六角氮化硼，也未出现立方氮化硼。在球磨不充分条件下，石墨-六角氮化硼混合物的XRD谱没有完全弥散，它们与水高压反应时，能观察到石墨与立方氮化硼分别结晶的现象，但都没有形成B-C-N晶化结构。     

几种旱生植物水分生理特性的比较研究

本文对梭梭(Halorylon ammodendron)等几种典型荒漠旱生植物在干旱环境下体内含水量、相对合水量、水分饱和亏缺、自由水、束缚水、水势、离体枝叶吸水速率等的变化及其与植物抗旱的关系进行了比较研究。     

中高温工质在蒸发器中的换热模拟分析

本文采用分布参数的方法,建立了水源热泵中普遍采用的壳管式蒸发器稳态数学模型.通过中高温水源热泵试验台的实验数据同模拟计算结果的对比,验证了数学模型的准确性。应用此数学模型对中高温工质HTR01、HTR02及R134a在蒸发器典型制热运行工况,进行了模拟计算。得出了三种工质制冷剂侧换热系数沿管长的变化关系并对三种工质的换热性能进行了对比分析,为采用中高温工质的水源热泵换热器设计提供了参考依据.     

Bending-torsion vibration of a partially submerged cylinder with an arbitrary cross-section

An analytical method is presented to investigate the bending-torsion vibration characteristics of a cylinder with an arbitrary cross-section and partially submerged in water. The compressibility and the free surface waves of the water are considered simultaneously in the analysis. The exact solution of structure–water interaction is obtained mathematically. Firstly, the analytical expression of the velocity potential of the water is derived by using the method of separation of variables. The unknown coefficients in the velocity potential are determined by the longitudinal and circumferential Fourier expansions along the outer surface of the cylinder and are expressed in the form of integral equations including the unknown dynamic bending deflection and torsional angle of the cylinder. Secondly, the force and torque acting on the cylinder per unit length, provided by the water, are obtained by integrating the water dynamic pressure along the circumference of the cylinder. The general solution of bending-torsion vibration of the cylinder under the water dynamic pressure is derived analytically. The integral equations included in the velocity potential of the water can be solved exactly. Finally, the eigenfrequency equation of cylinder–water interaction is obtained by means of the boundary conditions of the cylinder. Some numerical examples for elliptical columns partially submerged in water are provided to show the application of the present method.     

A Scanning Electron Microscopy study of water in soil

Cold stage Scanning Electron Microscopy (SEM) with a rapid cooling technique makes it possible to investigate the water phase within unsaturated porous media. It is thought that this technique preserves the main features of the micromorphology of the water menisci as it exists in the liquid phase in soils. Saddle-shaped elements, as well as pendular rings of water, were observed with concave and convex curvatures of the water-air interface. The hydraulic conductivity of an unsaturated soil may be inferred from SEM photographs. Observations of isolated water menisci indicate the existence of an immobile water domain. The surface geometry of the water menisci was analyzed quantitatively and surface tension and capillary pressure were determined.     

Solubility of carbon dioxide in aqueous solutions of sodium chloride: Experimental results and correlation

The solubility of carbon dioxide in aqueous solutions of sodium chloride was measured in the temperature range from 40 to 160°C, up to 6 mol-kg salt solutions and total pressures up to 10 MPa. Pitzer's⁽¹⁾ equations as well as the Chen and Evans⁽²⁾ model were used to correlate the new data. Results are reported and compared to literature data and correlations.     

超声波在废橡胶再生中应用的最新进展

全世界每年产生大量废旧橡胶，它们需要很长时间才能降解，这既污染环境，又浪费资源，解决此问题的唯一方法是再生利用。在众多再生方法中，新近出现的超声波脱硫再生法，被认为是最有希望的方法，本文详细地介绍了这方面的最新进展情况。     

Unexpected end‐groups of poly(acrylic acid) prepared by RAFT polymerization

Low‐molecular‐weight poly(acrylic acid) (PAA) was synthesized by reversible addition fragmentation chain transfer polymerization with a trithiocarbonate as chain‐transfer agent (CTA). With a combination of NMR spectroscopy and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry, the PAA end‐groups of the polymer were analyzed before and after neutralization by sodium hydroxide. The polymer prior to neutralization is made up of the expected trithiocarbonate chain‐ends and of the H‐terminated chains issued from a reaction of transfer to solvent. After neutralization, the trithiocarbonates are transformed into thiols, disulfides, thiolactones, and additional H‐terminated chains. By quantifying the different end‐groups, it was possible to demonstrate that fragmentation is the rate limiting step in the transfer reaction. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5439–5462, 2004