呋喃基聚酯的结构与性能关系研究进展

呋喃基聚酯是指以2,5-呋喃二甲酸(FDCA)为主要单体合成的生物基或部分生物基高分子,其主链含有刚性的呋喃环,因而在结构、性能上与大规模使用的传统石油基芳香族聚酯(如PET、PBT)相似,有望在瓶、片、薄膜、化纤等领域部分替代后者。本文综述了呋喃基聚酯的分子结构、聚集态结构以及力学、气体阻隔、降解等性能方面的最新研究进展,讨论了结构与性能之间的关系。重点关注呋喃基聚酯突出的阻隔性能及其对应的影响因素,主要从分子结构(呋喃环的非对称性和极性)和聚集态结构(结晶等)两方面加以阐明。简介了呋喃基聚酯的发展现状及其在包装、纺织等领域的潜在应用,并展望其主要研究趋势。     

Gas chromatographic properties of two thermotropic Poly(L-glutamates) with long alkyl side chains

Summary Comparative gas chromatographic properties of two thermotropic Poly(L-glutamates) with long alkyl side chains (10 and 16 carbons called Poly 10 and Poly 16 respectively) are studied.Their thermal properties were established with differential scanning calorimetry (DSC) and gas chromatography. They present a cholesteric liquid crystal in a large temperature range.The chromatographic separation abilities of the two polymers in the liquid crystal state were studied using capillary glass columns. Interesting analytical performances were obtained in different fields: isomeric separation of alkanes, aromatics, polyaromatics, volatile aroma compounds and cis and trans isomers. Some differences were noticed in their behaviours; 2 and 3-methyloctane and xylene isomers are separated only on Poly 10 while limonene and eucalyptol are separated only on Poly 16.     

基于杂环羧酸配体的金属有机骨架化合物合成、表征及性质研究

以噻吩-2,5-二羧酸为主要配体,借助第二配体----4,4-联吡啶或者邻菲罗啉通过水热法合成了三种MOFs材料,分别是[Cd (tdc) (bpy)]n、[Zn (tdc) (bpy)]n、[Co (tdc) (phen)]n。利用X射线单晶衍射仪、红外光谱仪对三种MOFs材料进行了结构表征与分析,同时利用荧光光谱仪、热重分析仪和电化学工作站测定了三种MOFs材料的荧光性质、热稳定性和MOFs材料修饰玻碳电极的电化学行为,结果表明,三种MOFs材料比配体更好的荧光强度和热稳定性,制备的[Co (tdc) (phen)]n修饰玻碳电极,对铁氰化钾溶液和含1.0mmol/L NaNO2的pH = 5 PBS溶液,均比裸玻碳电极表现出更强的循环伏安响应,有望作为修饰剂应用于修饰玻碳电极中。     

自成核对等规聚丙烯结晶行为和性能的影响

结晶聚合物的结晶动力学影响其形态结构 ,而形态结构的变化对材料的性能有着重要的影响 [1] .成核剂能有效地降低聚合物的球晶尺寸 ,提高材料的性能 [2 ] ,因此被广泛地应用于工业生产中 .自成核 (self- seeding nucleation)是指聚合物自身的微小晶粒作为晶核而诱导结晶生长的一种成核方式 [3 ,4 ] ,它具有很高的成核效率 ,并能有效地降低球晶尺寸 .本文研究了等规聚丙烯的自成核过程、结晶行为、形态结构及其对材料性能的影响 .1　实验部分1 .1　样品的制备　等规聚丙烯 (i PP)为广东茂名石油化学工业公司产品 ,牌号为 T3 6 F.将 i PP粒…     

On some properties of a linguistic classifier

A general structure of a linguistic classifier wherein sub-subclassifiers are the building blocks is suggested. Some properties of these sub-subclassifiers are proposed and proved. The physical significances of these properties are explored and it is shown that a condensed measure of belongingness of patterns to any class can be obtained which can conveniently be used for forming classification rules.     

Motion of a vortex filament with axial flow in the half space

We consider a nonlinear third order dispersive equation which models the motion of a vortex filament immersed in an incompressible and inviscid fluid occupying the three dimensional half space. We prove the unique solvability of initial–boundary value problems as an attempt to analyze the motion of a tornado.     

Hydrodynamics of a particle impact on a wall

The problem of a particle impacting on a wall, a common phenomenon in particle-laden flows in the minerals and process industries, is investigated computationally using a spectral-element method with the grid adjusting to the movement of the particle towards the wall. Remeshing is required at regular intervals to avoid problems associated with mesh distortion and the constantly reducing maximum time-step associated with integration of the non-linear convective terms of the Navier–Stokes equations. Accurate interpolation between meshes is achieved using the same high-order interpolation employed by the spectral-element flow solver. This approach allows the full flow evolution to be followed from the initial approach, through impact and afterwards as the flow relaxes. The method is applied to the generic two-dimensional and three-dimensional bluff body geometries, the circular cylinder and the sphere. The principal case reported here is that of a particle colliding normally with a wall and sticking. For the circular cylinder, non-normal collisions are also considered. The impacts are studied for moderate Reynolds numbers up to approximately 1200. A cylindrical body impacting on a wall produces two vortices from its wake that convect away from the cylinder along the wall before stalling while lifting induced wall vorticity into the main flow. The situation for a sphere impact is similar, except in this case a vortex ring is formed from the wake vorticity. Again, secondary vorticity from the wall and particle plays a role. At higher Reynolds number, the secondary vorticity tends to form a semi-annular structure encircling the primary vortex core. At even higher Reynolds numbers, the secondary annular structure fragments into semi-discrete structures, which again encircle and orbit the primary core. Vorticity fields and passive tracer particles are used to characterize the interaction of the vortical structures. The evolution of the pressure and viscous drag coefficients during a collision are provided for a typical sphere impact. For a Reynolds number greater than approximately 1000 for a sphere and 400 for a cylinder, the primary vortex core produced by the impacting body undergoes a short-wavelength instability in the azimuthal/spanwise direction. Experimental visualisation using dye carried out in water is presented to validate the predictions.     

Ruin-based risk measures in discrete-time risk models

For an insurance company, effective risk management requires an appropriate measurement of the risk associated with an insurance portfolio. The objective of the present paper is to study properties of ruin-based risk measures defined within discrete-time risk models under a different perspective at the frontier of the theory of risk measures and ruin theory. Ruin theory is a convenient framework to assess the riskiness of an insurance business. We present and examine desirable properties of ruin-based risk measures. Applications within the classical discrete-time risk model and extensions allowing temporal dependence are investigated. The impact of the temporal dependence on ruin-based risk measures within those different risk models is also studied. We discuss capital allocation based on Euler’s principle for homogeneous and subadditive ruin-based risk measures.     

Large Eddy Simulation of the vortex end in reverse-flow centrifugal separators

The present work is a study of the gas-flow phenomenon known as the “end of the vortex” (EoV), which spontaneously occurs at the lower end, or under, reverse-flow centrifugal separators such as cyclones or swirl tubes. Different CFD models of swirl tubes have been built to study and analyse this phenomenon in detail. The present numerical work is based on—and compared with—previous experimental observations of this phenomenon. The numerical models were built in complete agreement with the geometrical configurations and operating conditions used in these earlier experimental studies [1]. Two different configurations of swirl tubes were analyzed. One configuration was an in principle long tube with variable length in which the dependence on the vessel length of the behaviour of the vortex core in a simple, well-defined geometry was studied. The other configuration was equipped with a wide “dust collection vessel” at the bottom, the depth of which was varied, to study the behaviour of the vortex core in a widely-used geometry. 3-D LES simulations were carried out using the commercial CFD package Star-CD. The bending of the vortex core to the wall of the vessel and its precessional motion, constituting the phenomenon of the EoV, was seen in both configurations, and the obtained results are in very good agreement, both qualitatively and to an extent quantitatively, with previous experimental results [1].