光谱探针法确定Eu3+:ThO2的格位对称性及选择激发下样品的光致发光研究

测量和分析了不同温度下Eu³⁺:ThO₂的激发光谱、发射光谱和荧光 衰减曲线.Eu³⁺:ThO₂晶体是用熔融法生长的.通过12K下格位选择激 发下的发射光谱测量,利用晶场理论,确定了Eu³⁺在ThO₂占据Oh和C_3v两种格位.列表给出了两种格位Eu³⁺离子的晶场能 级和室温及12K下的荧光寿命.讨论了温度对能     

Theoretical study of potential energy surface and vibrational spectra of ArF2 system

An ab initio potential energy surface (PES) of ArF2 system has been obtained by using MP4 calculation with a large basis set including bond functions. There are two local minimums on the PES: one is T-shaped and the other is L-shaped. The L-shaped minimum is the global minimum with a well depth of -119.62 cm- 1 at R = 0.3883nm. The T-shaped minimum has a well depth of -85.93cm -1 at R = 0.3486 nm. A saddle point is found at R = 0.3486 and θ = 61° with the well depth of -61.53 cm-1. The vibrational energy levels have been calculated by using VSCF-CI method. The results show that this PES supports 27 vibrational bound states, and the ground states are two degenerate states assigned to the L-type vibration.     

Study of the Mo-Ba partition in 252Cf spontaneous fission

Measurements of fission fragment yields and neutron multiplicities have been carried out for the Mo-Ba fragment pairs in the spontaneous fission of ²⁵²Cf, using the γ-ray spectroscopy technique to analyze γ-γ-γ coincidence data. Prompt γ -ray multiplicities were also measured as a function of the number of neutrons emitted in the fission process leading to the Mo-Ba partition. We do not observe the enhancement in the yields of events with high neutron emission multiplicity (ν_n > 7) that has been associated to a second fission mode leading to the production of hyperdeformed Ba fragments, as reported in some earlier studies. The average γ-ray multiplicity is found to be rather weakly dependent on the number of neutrons emitted in the fission process. Received: 21 July 1999 / Revised version: 19 November 1999     

New insight in the level structure of <Superscript>153</Superscript>Er

The high-spin level structure of the ¹⁵³Er nucleus has been reinvestigated by in-beam γ-ray and electron spectroscopy with (¹⁴N,pxn) reaction. Excitation energies, spin and parity assignments are unambiguously established for the two lowest isomers T _1/2≃ 380 ns and T_1/2\simeq 10 ns. The characteristics of the third one (T _1/2≃ 250 ns) at 5.2 MeV are still questionable but its main decay modes are better known. An extension of the level scheme is proposed up to 8.4 MeV.Experimental results have been discussed in terms of shell model multiplets and compared with the other structures observed in N=85 neighbouring nuclei. Received: 8 November 1999 / Revised version: 13 December 1999     

The calculation of the chemisorption energy using the new diagram technique for the Anderson model

Using the perturbation expansion in the rebonding interaction near the surface molecule limit, the new diagram technique for the calculation of the chemisorption energy in the Anderson model is proposed. The new expression for the chemisorption energy in the ring diagram approximation is presented. The approximate expression for the contribution of the non- ring diagrams is suggested. The chemisorption energies are calculated and compared with the available exact results and others in the literature. A simple explanation of observable trends in hydrogen chemisorption energies along the transition metal series is given based on the rebonding surface molecule picture. Received 8 July 1999 and Received in final form 24 January 2000     

准Λ型四能级原子系统在弱场中的增益及电磁感应透明

利用数值模拟的方法讨论了稳态下准型四能级原子与两光场相互作用系统对探测场的增益以及与粒子数布居规律之间的关系。结果表明即使在场较弱的情况下,随着探测场和它所对应能级间跃迁频率失谐量的变化,系统在所有拉比频率相位为零时对探测光总会同时呈现三个增益峰和两个固定的产生电磁感应透明(EIT)现象的位置,并且当系统呈现电磁感应透明的同时,探测场所对应的高能级粒子数为零;而拉比频率相位的变化则会导致系统对探测光既有吸收也有增益,并且也呈现电磁感应透明现象,但仅仅相位的变化并不影响高能级的粒子数分布。值得注意的是该结果均在精确求解下所得。     

Detection and Risk Assessments of Multi-Pesticides in Traditional Chinese Medicine Chuanxiong Rhizoma by LC/MS-MS and GC/MS-MS

With the internationalization of traditional Chinese medicines (TCMs) and the increasing use of herbal medicines around the world, there are concerns over their safety. In recent years, there have been some sporadic reports of pesticide residues in Chuanxiong Rhizoma (CX), although the lack of systematic and comprehensive analyses of pesticide residues and evaluations of toxicological risks in human health has increased the uncertainty of the potential effects of pesticides exposure in humans. This study aimed to clarify the status of pesticide residues and to determine the health risks of pesticide residues in CX. The findings of this study revealed that 99 batches of CX samples contained pesticide residues ranging from 0.05 to 3013.17 μg/kg. Here, 6–22 kinds of pesticides were detected in each sample. Prometryn, carbendazim, dimethomorph, chlorpyrifos, chlorantraniliprole, pyraclostrobin, and paclobutrazol were the most frequently detected pesticides, with detection rates of 68.69–100%. Insecticides and fungicides accounted for 43.23% and 37.84% of the total pesticides detected, respectively. Here, 86.87% of the pesticide content levels were lower than 50 μg/kg, and a small number of samples contained carbofuran, dimethoate, and isofenphos-methyl exceeding the maximum residue levels (MRLs). A risk assessment based on the hazard quotient/hazard index (HQ/HI) approach revealed that the short-term, long-term, and cumulative risks of pesticide residues in CX are well below the levels that may pose a health risk. Worryingly, six banned pesticides (carbofuran, phorate sulfone, phorate-sulfoxide, isofenphos-methyl, terbufos-sulfone, and terbufoxon sulfoxide) were detected. This study has improved our understanding of the potential exposure risk of pesticide multi-residues in CX. The results of the study will have a positive impact on improving the quality and safety of CX and the development of MRLs for pesticide residues.     

Vibration of beams with general boundary conditions due to a moving random load

Summary  The transverse vibrations of elastic homogeneous isotropic beams with general boundary conditions due to a moving random force with constant mean value are analyzed. The boundary conditions considered are: pinned–pinned, fixed–fixed, pinned–fixed, and fixed–free. Based on the Bernoulli beam theory, the problem is described by means of a partial differential equation. Closed-form solutions for the variance and the coefficient of variation of the beam deflection are obtained and compared for three types of force motion: accelerated, decelerated and uniform. The effects of beam damping and speed of the moving force on the dynamic response of beams are studied in detail. Received 3 December 2001; accepted for publication 30 April 2002     

Transversal vibrations of double-plate systems

This paper presents an analytical and numerical analysis of free and forced transversal vibrations of an elastically connected double-plate system. Analytical solutions of a system of coupled partial differential equations, which describe corresponding dynamical free and forced processes, are obtained using Bernoulli’s particular integral and Lagrange’s method of variation constants. It is shown that one-mode vibrations correspond to two-frequency regime for free vibrations induced by initial conditions and to three-frequency regime for forced vibrations induced by one-frequency external excitation and corresponding initial conditions. The analytical solutions show that the elastic connection between plates leads to the appearance of two-frequency regime of time function, which corresponds to one eigenamplitude function of one mode, and also that the time functions of different vibration modes are uncoupled, for each shape of vibrations. It has been proven that for both elastically connected plates, for every pair of m and n, two possibilities for appearance of the resonance dynamical states, as well as for appearance of the dynamical absorption, are present. Using the MathCad program, the corresponding visualizations of the characteristic forms of the plate middle surfaces through time are presented.The English text was polished by Keren Wang.     

Identification of vibration loads on hydro generator by using hybrid genetic algorithm

Vibration dynamic characteristics have been a major issue in the modeling and mechanical analysis of large hydro generators. An algorithm is developed for identifying vibration dynamic characteristics by means of hybrid genetic algorithm. From the measured dynamic responses of a hydro generator, an appropriate estimation algorithm is needed to identify the loading parameters, including the main frequencies and amplitudes of vibrating forces. In order to identify parameters in an efficient and robust manner, an optimization method is proposed that combines genetic algorithm with simulated annealing and elitist strategy. The hybrid genetic algorithm is then used to tackle an ill-posed problem of parameter identification, in which the effectiveness of the proposed optimization method is confirmed by its comparison with actual observation data.The project supported by the National Natural Science Foundation of China (10472025). The English text was polished by Yunming Chen.