垂向磁场变化量对高温超导块材悬浮力特性的影响

高温超导体因其无源自稳定的特性,受到许多学者的重视,具有广阔的应用前景.目前针对高温超导块材悬浮性能的研究主要集中于由永磁体产生的低磁场环境.本文基于超导磁体平台提供的强磁场环境,通过改变高温超导块材不同的场冷高度,实验研究了高温超导块材悬浮力与垂向磁场变化量的关系.研究结果表明随着垂向磁场变化量的增加,高温超导块材的悬浮力增长趋缓,并最终出现悬浮力饱和的现象.本文还对比了YBCO 和Gd-BCO 两种不同材料超导块材的悬浮性能,结果发现GdBCO 的悬浮力在强磁场环境中表现出更大的潜力.这为高温超导磁浮在强磁场中的应用奠定了基础,通过更加合理地调节磁场的分布,可以更好地发挥高温超导块材的悬浮性能潜力     

南四湖各生态功能湖区垂向沉积物的磷吸附特征

研究了南四湖各生态功能湖区(养殖区、禁渔区、航道及湖滨带)垂向不同深度沉积物对磷的吸附动力学及等温吸附曲线,并分析了沉积物各形态磷与磷吸附特征参数的相关关系.研究结果表明:①各层沉积物对磷的吸附在10h内基本达到平衡,最大吸附量Qmax随着沉积深度的增加而增大;②随着沉积深度的增加,吸附-解吸平衡浓度Cepc和本底吸附态磷ωNAP含量均逐渐减小,吸附效率m逐渐增大;③吸附-解吸平衡浓度Cepc与Ex-P、Fe-P含量显著正相关,最大吸附量Qmax与Ex-P、org-P和TP含量均呈显著负相关关系,本底吸附态磷ωNAP与Ex-P、De-P含量呈显著正相关关系,吸附效率m仅与org-P含量呈显著正相关关系.     

A Triptycene-Based 2D MOF with Vertically Extended Structure for Improving the Electrocatalytic Performance of CO2 to Methane

Two-dimensional conductive metal-organic frameworks (2D-c-MOFs) have attracted extensive attention owing to their unique structures and physical-chemical properties. However, the planarly extended structure of 2D-c-MOFs usually limited the accessibility of the active sites. Herein, we designed a triptycene-based 2D vertically conductive MOF (2D-vc-MOF) by coordinating 2,3,6,7,14,15-hexahydroxyltriptycene (HHTC) with Cu²⁺. The vertically extended 2D-vc-MOF(Cu) possesses a weak interlayer interaction, which leads to a facile exfoliation to the nanosheet. Compared with the classical 2D-c-MOFs with planarly extended 2D structures, 2D-vc-MOF(Cu) exhibits a 100 % increased catalytic activity in terms of turnover number and a two-fold increased selectivity. Density functional theory (DFT) calculations further revealed that higher activity originated from the lower energy barriers of the vertically extended 2D structures during the CO₂ reduction reaction process.     

双三角阵声靶测试系统研究

声靶容易构成较大的测试靶面,常用在大口径弹药的立靶密集度测试中。为了消除声波在空气中传播速度变化对声靶测试精度的影响,采用双三角阵声阵列模型使测量公式中不再引入声波速度。为了使测试系统紧凑、可靠,整个测试系统由双三角阵列、多通道数据采集仪、计算机系统构成。对测试系统进行了实弹射击实验,在2 m×2 m靶面内,弹着点测量误差为±10 mm。