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101.
102.
103.
Pd80+x
Si20−x
(x = 0, 1, and 2) binary metallic glasses with the diameter ranging from 7 to 8 mm were prepared by a combination of fluxing
and water quenching or air cooling. Thermal analysis results show that with increasing Si content, the glass transition temperature
T
g, the initial crystallization temperature T
x and the onset crystallization temperature T
p of Pd-Si binary glassy alloys increase. Moreover, the supercooled liquid region reaches 61 K. It indicates that Pd-Si binary
alloys possess large glass forming ability, which can be greatly improved by fluxing treatment.
Supported by the National Basic Research Program of China (Grant No. 2007CB613905) and the National Natural Science Foundation
of China (Grant Nos. 50671050 and 50431030) 相似文献
104.
The thermodynamics structural relaxation of Fe73Cu1.5Nd3Si13.5B9 amorphous alloy from room temperature to 400°C has been investigated by measuring the structure factor with in situ X-ray diffraction. The structural information of the atomic configuration such as radial distribution function (RDF) and
neighbor atomic distance was gained by Fourier transformation. The research result shows that the amorphous structure remains
stable in the temperature range of 30 to 400°C but exhibits distinct changes in local atomic configuration with the increase
of temperature. The quantitative determination of the neighbor atomic distance suggests that the degree of short-range order
changes by the temperature altering the second nearest neighbor local atomic configuration of the amorphous when structural
relaxation occurs.
Supported by the Natural Science Foundation of Hebei Province of China (Grant No. A2007000296), the National Natural Science
Foundation of China (Grant No. 50731005), SKPBRC (Grant Nos. 2007CB616915 and 2006CB605201), and PCSIRT (Grant No. IRT0650) 相似文献
105.
106.
Agudelo A. C. Marco J. F. Gancedo J. R. Pérez-Alcázar G. A. 《Hyperfine Interactions》2002,139(1-4):141-152
The corrosion reaction of four Fe–Mn–Al alloys exposed to a cycling, dry–humid, SO2 (0.001% by volume) polluted atmosphere was studied. ICEMS, XPS, AES-SAM and transmission Mössbauer spectroscopy at different temperatures were employed to characterize the corrosion products. The analytical results indicate that (i) ferrihydrite is the main component of the rust; (ii) there is an abundant presence of Mn2+ and SO3
2–/SO4
2– on the top of the corrosion layer, the concentration of SO4
2– increasing with the number of cycles; and (iii) the magnetic hyperfine pattern exhibited by the series of low-temperature spectra of the rust is quite different from that observed in the rust formed under similar corrosive environments on iron and weathering steel. This latter finding is correlated with a slow rate of transformation of the Fe3+ species formed at the early stages of corrosion into -FeOOH, the usual final product of this type of corrosion processes. The sulphate anions, abundant inside the electrolyte during the wet periods, could be incorporated to the ferrihydrite structure being responsible for the Mössbauer spectral pattern recorded from the corrosion products at low temperatures. 相似文献
107.
Summary X-ray double-crystal rocking curves of Ga1−x
Al
x
As/GaAs heterostructures have been calculated using a dynamical diffraction model for the general case of Bragg reflection
geometry. Different experimental configurations have been considered and the possibility of studying both slightly mismatched
and relatively thin layers has been investigated. Experimental rocking curves have been measured using the CuKα
1 radiation, the 004 symmetric reflection and a perfect crystal as the monochromator. An excellent agreement between calculated
and experimental rocking curves has been found and this demonstrates the reliability of both the experimental procedure and
the theoretical approach. 相似文献
108.
M.J. Rozenberg 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(4):457-461
We propose a novel scenario for the electronic state in the manganese perovskites. We argue that, at low temperatures and
within the ferromagnetic state, the physics of these colossal magnetoresistance compounds may be characterized by a correlated
metallic state near a metal insulator transition where the orbital degrees of freedom play the main role. This follows from
the observation that a two-band degenerate Hubbard model under a strong magnetic field can be mapped onto a para-orbital single
band model. We solve the model numerically using the quantum Monte-Carlo technique within a dynamical mean field theory which
is exact in the limit of large lattice connectivity. We argue that the proposed scenario may allow for the qualitative interpretation
of a variety of experiments which were also observed in other (early) transition metal oxides.
Received: 3 October 1997 / Revised: 9 December 1997 / Accepted: 12 January 1998 相似文献
109.
The Ising model with competing interactions is studied in a mean field effective medium approach. The phase diagram of such
model alloys is studied. We conclude that for all ratios of the competing interaction moments, a spin glass phase always exists
at low temperatures for certain concentration regimes. 相似文献
110.
The establishment of atomic short-range order (SRO) has been investigated in CuMn alloys (5, 8,13,16,20 at. % Mn) by measurement of the electrical resistivity during isochronal and isothermal annealing. An increasing degree of SRO is accompanied by a reduction of resistivity; this effect increases with Mn concentration. For 8,13 and 16 at. % Mn SRO kinetics turn out to deviate significantly from single exponential behavior with a maximum at 13 at. % Mn, whereas at 5 and 20 at. % Mn SRO is adjusted in a single exponential process. For data analysis three methods are used: a sum of two and three exponentials as well as a log-normal spectrum of relaxation times. The strong interaction between second-nearest-neighbor atoms in CuMn seems to be essential for SRO kinetics but of minor importance for the value of SRO-induced resistivity change. 相似文献